Multiscale Numerical Modeling for Prediction of Piezoresistive Effect for Polymer Composites with a Highly Segregated Structure
In this work, the piezoresistive effect for a polymer nanocomposite with a highly segregated distribution of conductive filler was investigated. As a base polymer for the investigated nanocomposites, ultrahigh-molecular-weight polyethylene, processed in a solid state (below melting point), was used....
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| Format: | Article |
| Language: | English |
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MDPI AG
2021-01-01
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| Series: | Nanomaterials |
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| Online Access: | https://www.mdpi.com/2079-4991/11/1/162 |
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| author | Oleg V. Lebedev Alexander N. Ozerin Sergey G. Abaimov |
| author_facet | Oleg V. Lebedev Alexander N. Ozerin Sergey G. Abaimov |
| author_sort | Oleg V. Lebedev |
| collection | DOAJ |
| description | In this work, the piezoresistive effect for a polymer nanocomposite with a highly segregated distribution of conductive filler was investigated. As a base polymer for the investigated nanocomposites, ultrahigh-molecular-weight polyethylene, processed in a solid state (below melting point), was used. Multiwalled carbon nanotubes (MWCNTs) were used as a nanofiller forming a highly segregated structure in between polymer particles. A numerical multiscale approach based on the finite element method was proposed to predict changes in the conductive structure composed of MWCNTs in response to uniaxial deformation of the material. At the nanoscale, numerical simulations were conducted for uniformly distributed MWCNTs providing confinement of the filler to a two-dimensional layer with a high volume fraction of the filler in between two polymer particles. At the microscale, the piezoresistive response to uniaxial deformation for the three-dimensional highly segregated structure reconstructed from experimental data was investigated numerically. The embedded element method was implemented to conduct a realistic and computationally efficient simulation of MWCNT behavior during deformation of the nanocomposite. The results of numerical simulations were compared with the experimental data to prove the correctness of assumptions used in the modeling. |
| first_indexed | 2024-03-09T05:19:58Z |
| format | Article |
| id | doaj.art-3337aa3de4114cab837410718f2e115d |
| institution | Directory Open Access Journal |
| issn | 2079-4991 |
| language | English |
| last_indexed | 2024-03-09T05:19:58Z |
| publishDate | 2021-01-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Nanomaterials |
| spelling | doaj.art-3337aa3de4114cab837410718f2e115d2023-12-03T12:41:36ZengMDPI AGNanomaterials2079-49912021-01-0111116210.3390/nano11010162Multiscale Numerical Modeling for Prediction of Piezoresistive Effect for Polymer Composites with a Highly Segregated StructureOleg V. Lebedev0Alexander N. Ozerin1Sergey G. Abaimov2Center for Design, Manufacturing and Materials, Skolkovo Institute of Science and Technology, 143026 Moscow, RussiaN.S. Enikolopov Institute of Synthetic Polymer Materials of RAS, Profsoyuznaya St. 70, 117393 Moscow, RussiaCenter for Design, Manufacturing and Materials, Skolkovo Institute of Science and Technology, 143026 Moscow, RussiaIn this work, the piezoresistive effect for a polymer nanocomposite with a highly segregated distribution of conductive filler was investigated. As a base polymer for the investigated nanocomposites, ultrahigh-molecular-weight polyethylene, processed in a solid state (below melting point), was used. Multiwalled carbon nanotubes (MWCNTs) were used as a nanofiller forming a highly segregated structure in between polymer particles. A numerical multiscale approach based on the finite element method was proposed to predict changes in the conductive structure composed of MWCNTs in response to uniaxial deformation of the material. At the nanoscale, numerical simulations were conducted for uniformly distributed MWCNTs providing confinement of the filler to a two-dimensional layer with a high volume fraction of the filler in between two polymer particles. At the microscale, the piezoresistive response to uniaxial deformation for the three-dimensional highly segregated structure reconstructed from experimental data was investigated numerically. The embedded element method was implemented to conduct a realistic and computationally efficient simulation of MWCNT behavior during deformation of the nanocomposite. The results of numerical simulations were compared with the experimental data to prove the correctness of assumptions used in the modeling.https://www.mdpi.com/2079-4991/11/1/162polymer compositescarbon nanoparticlespiezoresistive effectelectrical conductivityultrahigh-molecular-weight polyethylene |
| spellingShingle | Oleg V. Lebedev Alexander N. Ozerin Sergey G. Abaimov Multiscale Numerical Modeling for Prediction of Piezoresistive Effect for Polymer Composites with a Highly Segregated Structure Nanomaterials polymer composites carbon nanoparticles piezoresistive effect electrical conductivity ultrahigh-molecular-weight polyethylene |
| title | Multiscale Numerical Modeling for Prediction of Piezoresistive Effect for Polymer Composites with a Highly Segregated Structure |
| title_full | Multiscale Numerical Modeling for Prediction of Piezoresistive Effect for Polymer Composites with a Highly Segregated Structure |
| title_fullStr | Multiscale Numerical Modeling for Prediction of Piezoresistive Effect for Polymer Composites with a Highly Segregated Structure |
| title_full_unstemmed | Multiscale Numerical Modeling for Prediction of Piezoresistive Effect for Polymer Composites with a Highly Segregated Structure |
| title_short | Multiscale Numerical Modeling for Prediction of Piezoresistive Effect for Polymer Composites with a Highly Segregated Structure |
| title_sort | multiscale numerical modeling for prediction of piezoresistive effect for polymer composites with a highly segregated structure |
| topic | polymer composites carbon nanoparticles piezoresistive effect electrical conductivity ultrahigh-molecular-weight polyethylene |
| url | https://www.mdpi.com/2079-4991/11/1/162 |
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