Crystal structure of (Z)-3-allyl-5-(3-bromobenzylidene)-2-sulfanylidene-1,3-thiazolidin-4-one
In the title compound, C13H10BrNOS2, the rhodanine (systematic name: 2-sulfanylidene-1,3-thiazolidin-4-one) and the 3-bromobenzylidene ring systems are inclined slightly, forming a dihedral angle of 5.86 (12)°. The rhodanine moiety is linked to an allyl group at the N atom and to the 3-bromobenzylid...
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2015-12-01
|
| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989015022884 |
| _version_ | 1819107150390099968 |
|---|---|
| author | Rahhal El Ajlaoui El Mostapha Rakib Issam Forsal Mohamed Saadi Lahcen El Ammari |
| author_facet | Rahhal El Ajlaoui El Mostapha Rakib Issam Forsal Mohamed Saadi Lahcen El Ammari |
| author_sort | Rahhal El Ajlaoui |
| collection | DOAJ |
| description | In the title compound, C13H10BrNOS2, the rhodanine (systematic name: 2-sulfanylidene-1,3-thiazolidin-4-one) and the 3-bromobenzylidene ring systems are inclined slightly, forming a dihedral angle of 5.86 (12)°. The rhodanine moiety is linked to an allyl group at the N atom and to the 3-bromobenzylidene ring system. The allyl group, C=C—C, is nearly perpendicular to the mean plane through the rhodanine ring, maling a dihedral angle of 87.2 (5)°. In the crystal, molecules are linked by pairs of C—H...O hydrogen bonds, forming inversion dimers with an R22(10) ring motif. |
| first_indexed | 2024-12-22T02:49:28Z |
| format | Article |
| id | doaj.art-33452a6d3d3a46abb5b08d3469598ae1 |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-12-22T02:49:28Z |
| publishDate | 2015-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-33452a6d3d3a46abb5b08d3469598ae12022-12-21T18:41:25ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902015-12-017112o1010o101110.1107/S2056989015022884su5249Crystal structure of (Z)-3-allyl-5-(3-bromobenzylidene)-2-sulfanylidene-1,3-thiazolidin-4-oneRahhal El Ajlaoui0El Mostapha Rakib1Issam Forsal2Mohamed Saadi3Lahcen El Ammari4Laboratoire de Chimie Organique et Analytique, Université Sultan Moulay Slimane, Faculté des Sciences et Techniques, Béni-Mellal, BP 523, MoroccoLaboratoire de Chimie Organique et Analytique, Université Sultan Moulay Slimane, Faculté des Sciences et Techniques, Béni-Mellal, BP 523, MoroccoLaboratoire de Chimie Organique et Analytique, Université Sultan Moulay Slimane, Faculté des Sciences et Techniques, Béni-Mellal, BP 523, MoroccoLaboratoire de Chimie du Solide Appliquée, Faculté des Sciences, Université Mohammed V de Rabat, Avenue Ibn Battouta, BP. 1014, Rabat, MoroccoLaboratoire de Chimie du Solide Appliquée, Faculté des Sciences, Université Mohammed V de Rabat, Avenue Ibn Battouta, BP. 1014, Rabat, MoroccoIn the title compound, C13H10BrNOS2, the rhodanine (systematic name: 2-sulfanylidene-1,3-thiazolidin-4-one) and the 3-bromobenzylidene ring systems are inclined slightly, forming a dihedral angle of 5.86 (12)°. The rhodanine moiety is linked to an allyl group at the N atom and to the 3-bromobenzylidene ring system. The allyl group, C=C—C, is nearly perpendicular to the mean plane through the rhodanine ring, maling a dihedral angle of 87.2 (5)°. In the crystal, molecules are linked by pairs of C—H...O hydrogen bonds, forming inversion dimers with an R22(10) ring motif.http://scripts.iucr.org/cgi-bin/paper?S2056989015022884crystal structurerhodaninehydrogen bonding |
| spellingShingle | Rahhal El Ajlaoui El Mostapha Rakib Issam Forsal Mohamed Saadi Lahcen El Ammari Crystal structure of (Z)-3-allyl-5-(3-bromobenzylidene)-2-sulfanylidene-1,3-thiazolidin-4-one Acta Crystallographica Section E: Crystallographic Communications crystal structure rhodanine hydrogen bonding |
| title | Crystal structure of (Z)-3-allyl-5-(3-bromobenzylidene)-2-sulfanylidene-1,3-thiazolidin-4-one |
| title_full | Crystal structure of (Z)-3-allyl-5-(3-bromobenzylidene)-2-sulfanylidene-1,3-thiazolidin-4-one |
| title_fullStr | Crystal structure of (Z)-3-allyl-5-(3-bromobenzylidene)-2-sulfanylidene-1,3-thiazolidin-4-one |
| title_full_unstemmed | Crystal structure of (Z)-3-allyl-5-(3-bromobenzylidene)-2-sulfanylidene-1,3-thiazolidin-4-one |
| title_short | Crystal structure of (Z)-3-allyl-5-(3-bromobenzylidene)-2-sulfanylidene-1,3-thiazolidin-4-one |
| title_sort | crystal structure of z 3 allyl 5 3 bromobenzylidene 2 sulfanylidene 1 3 thiazolidin 4 one |
| topic | crystal structure rhodanine hydrogen bonding |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989015022884 |
| work_keys_str_mv | AT rahhalelajlaoui crystalstructureofz3allyl53bromobenzylidene2sulfanylidene13thiazolidin4one AT elmostapharakib crystalstructureofz3allyl53bromobenzylidene2sulfanylidene13thiazolidin4one AT issamforsal crystalstructureofz3allyl53bromobenzylidene2sulfanylidene13thiazolidin4one AT mohamedsaadi crystalstructureofz3allyl53bromobenzylidene2sulfanylidene13thiazolidin4one AT lahcenelammari crystalstructureofz3allyl53bromobenzylidene2sulfanylidene13thiazolidin4one |