2,2′-(Hexane-1,6-diyl)diisoquinolinium tetrachloridozincate(II)
The asymmetric unit of the title compound, (C24H26N2)[ZnCl4], consists of two 2,2′-(hexane-1,6-diyl)diisoquinolinium cations and two [ZnCl4]2− complex anions. The [ZnCl4]2− anions have a distorted tetrahedral geometry. The dihedral angles between the isoquin...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009-06-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809017693 |
| _version_ | 1818286194095554560 |
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| author | Pei-Hua Ma Zhi-Fang Fan Yun-Qian Zhang Xin Xiao Sai-Feng Xue |
| author_facet | Pei-Hua Ma Zhi-Fang Fan Yun-Qian Zhang Xin Xiao Sai-Feng Xue |
| author_sort | Pei-Hua Ma |
| collection | DOAJ |
| description | The asymmetric unit of the title compound, (C24H26N2)[ZnCl4], consists of two 2,2′-(hexane-1,6-diyl)diisoquinolinium cations and two [ZnCl4]2− complex anions. The [ZnCl4]2− anions have a distorted tetrahedral geometry. The dihedral angles between the isoquinoline rings of the two cations are nearly equal [16.1 (2) and 16.3 (2)°]. In the crystal structure, the ordered linear formation is aggregated by weak intermolecular π–π stacking interactions between neighboring isoquinoline pyridine rings with a centroid–centroid distance of 3.779 (4) Å. |
| first_indexed | 2024-12-13T01:20:43Z |
| format | Article |
| id | doaj.art-3347dfd440184b43abe6f052b9c5cd69 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T01:20:43Z |
| publishDate | 2009-06-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-3347dfd440184b43abe6f052b9c5cd692022-12-22T00:04:14ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-06-01656m655m65510.1107/S16005368090176932,2′-(Hexane-1,6-diyl)diisoquinolinium tetrachloridozincate(II)Pei-Hua MaZhi-Fang FanYun-Qian ZhangXin XiaoSai-Feng XueThe asymmetric unit of the title compound, (C24H26N2)[ZnCl4], consists of two 2,2′-(hexane-1,6-diyl)diisoquinolinium cations and two [ZnCl4]2− complex anions. The [ZnCl4]2− anions have a distorted tetrahedral geometry. The dihedral angles between the isoquinoline rings of the two cations are nearly equal [16.1 (2) and 16.3 (2)°]. In the crystal structure, the ordered linear formation is aggregated by weak intermolecular π–π stacking interactions between neighboring isoquinoline pyridine rings with a centroid–centroid distance of 3.779 (4) Å.http://scripts.iucr.org/cgi-bin/paper?S1600536809017693 |
| spellingShingle | Pei-Hua Ma Zhi-Fang Fan Yun-Qian Zhang Xin Xiao Sai-Feng Xue 2,2′-(Hexane-1,6-diyl)diisoquinolinium tetrachloridozincate(II) Acta Crystallographica Section E |
| title | 2,2′-(Hexane-1,6-diyl)diisoquinolinium tetrachloridozincate(II) |
| title_full | 2,2′-(Hexane-1,6-diyl)diisoquinolinium tetrachloridozincate(II) |
| title_fullStr | 2,2′-(Hexane-1,6-diyl)diisoquinolinium tetrachloridozincate(II) |
| title_full_unstemmed | 2,2′-(Hexane-1,6-diyl)diisoquinolinium tetrachloridozincate(II) |
| title_short | 2,2′-(Hexane-1,6-diyl)diisoquinolinium tetrachloridozincate(II) |
| title_sort | 2 2 amp 8242 hexane 1 6 diyl diisoquinolinium tetrachloridozincate ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809017693 |
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