New approaches to organocatalysis based on C–H and C–X bonding for electrophilic substrate activation
Hydrogen bond donor catalysis represents a rapidly growing subfield of organocatalysis. While traditional hydrogen bond donors containing N–H and O–H moieties have been effectively used for electrophile activation, activation based on other types of non-covalent interactions is less common. This min...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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Beilstein-Institut
2016-12-01
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| Series: | Beilstein Journal of Organic Chemistry |
| Subjects: | |
| Online Access: | https://doi.org/10.3762/bjoc.12.283 |
| _version_ | 1818412983578001408 |
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| author | Pavel Nagorny Zhankui Sun |
| author_facet | Pavel Nagorny Zhankui Sun |
| author_sort | Pavel Nagorny |
| collection | DOAJ |
| description | Hydrogen bond donor catalysis represents a rapidly growing subfield of organocatalysis. While traditional hydrogen bond donors containing N–H and O–H moieties have been effectively used for electrophile activation, activation based on other types of non-covalent interactions is less common. This mini review highlights recent progress in developing and exploring new organic catalysts for electrophile activation through the formation of C–H hydrogen bonds and C–X halogen bonds. |
| first_indexed | 2024-12-14T10:55:59Z |
| format | Article |
| id | doaj.art-334c033dd9bb44d4a480f81b222392c6 |
| institution | Directory Open Access Journal |
| issn | 1860-5397 |
| language | English |
| last_indexed | 2024-12-14T10:55:59Z |
| publishDate | 2016-12-01 |
| publisher | Beilstein-Institut |
| record_format | Article |
| series | Beilstein Journal of Organic Chemistry |
| spelling | doaj.art-334c033dd9bb44d4a480f81b222392c62022-12-21T23:04:55ZengBeilstein-InstitutBeilstein Journal of Organic Chemistry1860-53972016-12-011212834284810.3762/bjoc.12.2831860-5397-12-283New approaches to organocatalysis based on C–H and C–X bonding for electrophilic substrate activationPavel Nagorny0Zhankui Sun1Chemistry Department, University of Michigan, Ann Arbor, MI 48109, USASchool of Pharmacy, Shanghai Jiao Tong University, No. 800 Dongchuan Rd., Shanghai 200240, P. R. ChinaHydrogen bond donor catalysis represents a rapidly growing subfield of organocatalysis. While traditional hydrogen bond donors containing N–H and O–H moieties have been effectively used for electrophile activation, activation based on other types of non-covalent interactions is less common. This mini review highlights recent progress in developing and exploring new organic catalysts for electrophile activation through the formation of C–H hydrogen bonds and C–X halogen bonds.https://doi.org/10.3762/bjoc.12.283C–H hydrogen bondcounteranion activationelectrophile activationhalogen bond donorhydrogen bond donororganocatalysis |
| spellingShingle | Pavel Nagorny Zhankui Sun New approaches to organocatalysis based on C–H and C–X bonding for electrophilic substrate activation Beilstein Journal of Organic Chemistry C–H hydrogen bond counteranion activation electrophile activation halogen bond donor hydrogen bond donor organocatalysis |
| title | New approaches to organocatalysis based on C–H and C–X bonding for electrophilic substrate activation |
| title_full | New approaches to organocatalysis based on C–H and C–X bonding for electrophilic substrate activation |
| title_fullStr | New approaches to organocatalysis based on C–H and C–X bonding for electrophilic substrate activation |
| title_full_unstemmed | New approaches to organocatalysis based on C–H and C–X bonding for electrophilic substrate activation |
| title_short | New approaches to organocatalysis based on C–H and C–X bonding for electrophilic substrate activation |
| title_sort | new approaches to organocatalysis based on c h and c x bonding for electrophilic substrate activation |
| topic | C–H hydrogen bond counteranion activation electrophile activation halogen bond donor hydrogen bond donor organocatalysis |
| url | https://doi.org/10.3762/bjoc.12.283 |
| work_keys_str_mv | AT pavelnagorny newapproachestoorganocatalysisbasedonchandcxbondingforelectrophilicsubstrateactivation AT zhankuisun newapproachestoorganocatalysisbasedonchandcxbondingforelectrophilicsubstrateactivation |