Synthesis of Metal-Organic Frameworks Zinc (II) with Optimum Slow Pyrolysis Process for Conductivity Performance
Metal-organic frameworks are one of the materials that currently have the potential as an anode material to replace graphite. It also has the advantages of large specific surface area, storage space and high gas absorption with high pore volume and good conductivity. The purpose of this study was to...
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| Format: | Article |
| Language: | English |
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EDP Sciences
2024-01-01
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| Series: | E3S Web of Conferences |
| Online Access: | https://www.e3s-conferences.org/articles/e3sconf/pdf/2024/14/e3sconf_foitic2024_03003.pdf |
| _version_ | 1827352560231514112 |
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| author | Dyah Pita Rengga Wara Fitri Amelia Madnasri Sutikno Syahputra Fauzi |
| author_facet | Dyah Pita Rengga Wara Fitri Amelia Madnasri Sutikno Syahputra Fauzi |
| author_sort | Dyah Pita Rengga Wara |
| collection | DOAJ |
| description | Metal-organic frameworks are one of the materials that currently have the potential as an anode material to replace graphite. It also has the advantages of large specific surface area, storage space and high gas absorption with high pore volume and good conductivity. The purpose of this study was to determine the optimum temperature for the synthesis of Metal-Organic Frameworks to obtain conductivity performance. Zinc nitrate hexahydrate and acetic acid were mixed in N, N-Dimthylformamide solvent at various temperatures of 250-650°C for 4 hours with a slow pyrolysis process and proceeded with precipitation. Solid Metal-Organic Frameworks formed were characterized using Scanning Electron Microscopy, X-ray diffraction, Fourier Transform Infra-Red, and IV-Meter. The crystal form is nanocubes of a layered metal-organic framework of Zinc (II) that penetrates each other in a hexagonal shape. The crystal contains zinc oxide with hydroxyl and carboxylic functional groups. Metal-organic synthesis occurs at an optimum reaction temperature of 450°C, showing high conductivity, with the fastest current increase, reaching a current of 3.82E-08 A at a voltage of 0.05 V. |
| first_indexed | 2024-03-08T03:07:40Z |
| format | Article |
| id | doaj.art-334ed378e32c469f949b5c799d0615c8 |
| institution | Directory Open Access Journal |
| issn | 2267-1242 |
| language | English |
| last_indexed | 2024-03-08T03:07:40Z |
| publishDate | 2024-01-01 |
| publisher | EDP Sciences |
| record_format | Article |
| series | E3S Web of Conferences |
| spelling | doaj.art-334ed378e32c469f949b5c799d0615c82024-02-13T08:27:42ZengEDP SciencesE3S Web of Conferences2267-12422024-01-014840300310.1051/e3sconf/202448403003e3sconf_foitic2024_03003Synthesis of Metal-Organic Frameworks Zinc (II) with Optimum Slow Pyrolysis Process for Conductivity PerformanceDyah Pita Rengga Wara0Fitri Amelia1Madnasri Sutikno2Syahputra Fauzi3Chemical Engineering Department. Universitas Negeri SemarangChemical Engineering Department. Universitas Negeri SemarangChemical Engineering Department. Universitas Negeri SemarangChemical Engineering Department. Universitas Negeri SemarangMetal-organic frameworks are one of the materials that currently have the potential as an anode material to replace graphite. It also has the advantages of large specific surface area, storage space and high gas absorption with high pore volume and good conductivity. The purpose of this study was to determine the optimum temperature for the synthesis of Metal-Organic Frameworks to obtain conductivity performance. Zinc nitrate hexahydrate and acetic acid were mixed in N, N-Dimthylformamide solvent at various temperatures of 250-650°C for 4 hours with a slow pyrolysis process and proceeded with precipitation. Solid Metal-Organic Frameworks formed were characterized using Scanning Electron Microscopy, X-ray diffraction, Fourier Transform Infra-Red, and IV-Meter. The crystal form is nanocubes of a layered metal-organic framework of Zinc (II) that penetrates each other in a hexagonal shape. The crystal contains zinc oxide with hydroxyl and carboxylic functional groups. Metal-organic synthesis occurs at an optimum reaction temperature of 450°C, showing high conductivity, with the fastest current increase, reaching a current of 3.82E-08 A at a voltage of 0.05 V.https://www.e3s-conferences.org/articles/e3sconf/pdf/2024/14/e3sconf_foitic2024_03003.pdf |
| spellingShingle | Dyah Pita Rengga Wara Fitri Amelia Madnasri Sutikno Syahputra Fauzi Synthesis of Metal-Organic Frameworks Zinc (II) with Optimum Slow Pyrolysis Process for Conductivity Performance E3S Web of Conferences |
| title | Synthesis of Metal-Organic Frameworks Zinc (II) with Optimum Slow Pyrolysis Process for Conductivity Performance |
| title_full | Synthesis of Metal-Organic Frameworks Zinc (II) with Optimum Slow Pyrolysis Process for Conductivity Performance |
| title_fullStr | Synthesis of Metal-Organic Frameworks Zinc (II) with Optimum Slow Pyrolysis Process for Conductivity Performance |
| title_full_unstemmed | Synthesis of Metal-Organic Frameworks Zinc (II) with Optimum Slow Pyrolysis Process for Conductivity Performance |
| title_short | Synthesis of Metal-Organic Frameworks Zinc (II) with Optimum Slow Pyrolysis Process for Conductivity Performance |
| title_sort | synthesis of metal organic frameworks zinc ii with optimum slow pyrolysis process for conductivity performance |
| url | https://www.e3s-conferences.org/articles/e3sconf/pdf/2024/14/e3sconf_foitic2024_03003.pdf |
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