Anion Influence on Spin State in Two Novel Fe(III) Compounds: [Fe(5F-sal2333)]X

Structural and magnetic data on two iron (III) complexes with a hexadentate Schiff base chelating ligand and Cl− or BPh4− counterions are reported. In the solid state, the Cl− complex [Fe(5F-sal2333)]Cl, 1, is high spin between 5–300 K while the BPh4&minus...

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Bibliographic Details
Main Authors: Sriram Sundaresan, Irina A. Kühne, Conor T. Kelly, Andrew Barker, Daniel Salley, Helge Müller-Bunz, Annie K. Powell, Grace G. Morgan
Format: Article
Language:English
Published: MDPI AG 2018-12-01
Series:Crystals
Subjects:
Online Access:http://www.mdpi.com/2073-4352/9/1/19