CO2 Hydrogenation on Metal-Organic Frameworks-Based Catalysts: A Mini Review
Conversion of carbon dioxide (CO2) into value-added fuels and chemicals can not only reduce the emission amount of CO2 in the atmosphere and alleviate the greenhouse effect but also realize carbon recycling. Through hydrogenation with renewable hydrogen (H2), CO2 can be transformed into various hydr...
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| Format: | Article |
| Language: | English |
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Frontiers Media S.A.
2022-07-01
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| Series: | Frontiers in Chemistry |
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| Online Access: | https://www.frontiersin.org/articles/10.3389/fchem.2022.956223/full |
| _version_ | 1828790429336731648 |
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| author | Qian Zhang Qian Zhang Sen Wang Mei Dong Weibin Fan |
| author_facet | Qian Zhang Qian Zhang Sen Wang Mei Dong Weibin Fan |
| author_sort | Qian Zhang |
| collection | DOAJ |
| description | Conversion of carbon dioxide (CO2) into value-added fuels and chemicals can not only reduce the emission amount of CO2 in the atmosphere and alleviate the greenhouse effect but also realize carbon recycling. Through hydrogenation with renewable hydrogen (H2), CO2 can be transformed into various hydrocarbons and oxygenates, including methanol, ethanol, methane and light olefins, etc. Recently, metal-organic frameworks (MOFs) have attracted extensive attention in the fields of adsorption, gas separation, and catalysis due to their high surface area, abundant metal sites, and tunable metal-support interface interaction. In CO2 hydrogenation, MOFs are regarded as important supports or sacrificed precursors for the preparation of high-efficient catalysts, which can uniformly disperse metal nanoparticles (NPs) and enhance the interaction between metal and support to prevent sintering and aggregation of active metal species. This work summarizes the recent process on hydrogenation of CO2 to methanol, methane and other C2+ products over various MOFs-based catalysts, and it will provide some dues for the design of MOFs materials in energy-efficient conversion and utilization. |
| first_indexed | 2024-12-12T01:30:20Z |
| format | Article |
| id | doaj.art-3355264e879f437780d9b99b2ae2e636 |
| institution | Directory Open Access Journal |
| issn | 2296-2646 |
| language | English |
| last_indexed | 2024-12-12T01:30:20Z |
| publishDate | 2022-07-01 |
| publisher | Frontiers Media S.A. |
| record_format | Article |
| series | Frontiers in Chemistry |
| spelling | doaj.art-3355264e879f437780d9b99b2ae2e6362022-12-22T00:42:59ZengFrontiers Media S.A.Frontiers in Chemistry2296-26462022-07-011010.3389/fchem.2022.956223956223CO2 Hydrogenation on Metal-Organic Frameworks-Based Catalysts: A Mini ReviewQian Zhang0Qian Zhang1Sen Wang2Mei Dong3Weibin Fan4State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan, ChinaUniversity of the Chinese Academy of Sciences, Beijing, ChinaState Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan, ChinaState Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan, ChinaState Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan, ChinaConversion of carbon dioxide (CO2) into value-added fuels and chemicals can not only reduce the emission amount of CO2 in the atmosphere and alleviate the greenhouse effect but also realize carbon recycling. Through hydrogenation with renewable hydrogen (H2), CO2 can be transformed into various hydrocarbons and oxygenates, including methanol, ethanol, methane and light olefins, etc. Recently, metal-organic frameworks (MOFs) have attracted extensive attention in the fields of adsorption, gas separation, and catalysis due to their high surface area, abundant metal sites, and tunable metal-support interface interaction. In CO2 hydrogenation, MOFs are regarded as important supports or sacrificed precursors for the preparation of high-efficient catalysts, which can uniformly disperse metal nanoparticles (NPs) and enhance the interaction between metal and support to prevent sintering and aggregation of active metal species. This work summarizes the recent process on hydrogenation of CO2 to methanol, methane and other C2+ products over various MOFs-based catalysts, and it will provide some dues for the design of MOFs materials in energy-efficient conversion and utilization.https://www.frontiersin.org/articles/10.3389/fchem.2022.956223/fullMOFsCO2 hydrogenationmethanolmethaneC2+ Products |
| spellingShingle | Qian Zhang Qian Zhang Sen Wang Mei Dong Weibin Fan CO2 Hydrogenation on Metal-Organic Frameworks-Based Catalysts: A Mini Review Frontiers in Chemistry MOFs CO2 hydrogenation methanol methane C2+ Products |
| title | CO2 Hydrogenation on Metal-Organic Frameworks-Based Catalysts: A Mini Review |
| title_full | CO2 Hydrogenation on Metal-Organic Frameworks-Based Catalysts: A Mini Review |
| title_fullStr | CO2 Hydrogenation on Metal-Organic Frameworks-Based Catalysts: A Mini Review |
| title_full_unstemmed | CO2 Hydrogenation on Metal-Organic Frameworks-Based Catalysts: A Mini Review |
| title_short | CO2 Hydrogenation on Metal-Organic Frameworks-Based Catalysts: A Mini Review |
| title_sort | co2 hydrogenation on metal organic frameworks based catalysts a mini review |
| topic | MOFs CO2 hydrogenation methanol methane C2+ Products |
| url | https://www.frontiersin.org/articles/10.3389/fchem.2022.956223/full |
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