2-Methyl-3-phenylsulfinyl-1-benzofuran
The title compound, C15H12O2S, was prepared by the oxidation of 2-methyl-3-phenylsulfanyl-1-benzofuran with 3-chloroperoxybenzoic acid. The O atom and the phenyl group of the phenylsulfinyl substituent lie on opposite sides of the plane of the benzofuran system. The phenyl ring makes a dihedral angl...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808021107 |
| _version_ | 1818905323631542272 |
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| author | Hong Dae Choi Pil Ja Seo Byeng Wha Son Uk Lee |
| author_facet | Hong Dae Choi Pil Ja Seo Byeng Wha Son Uk Lee |
| author_sort | Hong Dae Choi |
| collection | DOAJ |
| description | The title compound, C15H12O2S, was prepared by the oxidation of 2-methyl-3-phenylsulfanyl-1-benzofuran with 3-chloroperoxybenzoic acid. The O atom and the phenyl group of the phenylsulfinyl substituent lie on opposite sides of the plane of the benzofuran system. The phenyl ring makes a dihedral angle of 78.76 (4)° with the benzofuran mean plane. The crystal structure is stabilized by π–π interactions between the furan and benzene rings of neighbouring molecules [centroid–centroid distance = 4.017 (3) Å]. In addition, the crystal structure exhibits intermolecular C—H...π and C—H...O interactions. |
| first_indexed | 2024-12-19T21:21:31Z |
| format | Article |
| id | doaj.art-33772b0081d2486db65f50605e4322c1 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-19T21:21:31Z |
| publishDate | 2008-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-33772b0081d2486db65f50605e4322c12022-12-21T20:05:13ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-08-01648o1477o147710.1107/S16005368080211072-Methyl-3-phenylsulfinyl-1-benzofuranHong Dae ChoiPil Ja SeoByeng Wha SonUk LeeThe title compound, C15H12O2S, was prepared by the oxidation of 2-methyl-3-phenylsulfanyl-1-benzofuran with 3-chloroperoxybenzoic acid. The O atom and the phenyl group of the phenylsulfinyl substituent lie on opposite sides of the plane of the benzofuran system. The phenyl ring makes a dihedral angle of 78.76 (4)° with the benzofuran mean plane. The crystal structure is stabilized by π–π interactions between the furan and benzene rings of neighbouring molecules [centroid–centroid distance = 4.017 (3) Å]. In addition, the crystal structure exhibits intermolecular C—H...π and C—H...O interactions.http://scripts.iucr.org/cgi-bin/paper?S1600536808021107 |
| spellingShingle | Hong Dae Choi Pil Ja Seo Byeng Wha Son Uk Lee 2-Methyl-3-phenylsulfinyl-1-benzofuran Acta Crystallographica Section E |
| title | 2-Methyl-3-phenylsulfinyl-1-benzofuran |
| title_full | 2-Methyl-3-phenylsulfinyl-1-benzofuran |
| title_fullStr | 2-Methyl-3-phenylsulfinyl-1-benzofuran |
| title_full_unstemmed | 2-Methyl-3-phenylsulfinyl-1-benzofuran |
| title_short | 2-Methyl-3-phenylsulfinyl-1-benzofuran |
| title_sort | 2 methyl 3 phenylsulfinyl 1 benzofuran |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808021107 |
| work_keys_str_mv | AT hongdaechoi 2methyl3phenylsulfinyl1benzofuran AT piljaseo 2methyl3phenylsulfinyl1benzofuran AT byengwhason 2methyl3phenylsulfinyl1benzofuran AT uklee 2methyl3phenylsulfinyl1benzofuran |