Influence of Zn Addition on the Aging Precipitate Behavior and Mechanical Properties of Al-Cu-Li Alloy

In the present work, the effect of Zn on the aging precipitates and mechanical properties of Al-Cu-Li alloys was investigated by Vickers hardness, tensile tests, transmission electron microscopy (TEM) and differential scanning calorimetry (DSC). The results indicated that the addition of Zn reduced...

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Main Authors: Meiqi Wang, Lizhen Yan, Xiwu Li, Yongan Zhang, Zhihui Li, Kai Wen, Hongwei Liu, Baiqing Xiong
Format: Article
Language:English
Published: MDPI AG 2024-03-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/17/7/1562
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author Meiqi Wang
Lizhen Yan
Xiwu Li
Yongan Zhang
Zhihui Li
Kai Wen
Hongwei Liu
Baiqing Xiong
author_facet Meiqi Wang
Lizhen Yan
Xiwu Li
Yongan Zhang
Zhihui Li
Kai Wen
Hongwei Liu
Baiqing Xiong
author_sort Meiqi Wang
collection DOAJ
description In the present work, the effect of Zn on the aging precipitates and mechanical properties of Al-Cu-Li alloys was investigated by Vickers hardness, tensile tests, transmission electron microscopy (TEM) and differential scanning calorimetry (DSC). The results indicated that the addition of Zn reduced the activation energy of the T<sub>1</sub> phase and makes it easier to precipitate. The activation energy of the T<sub>1</sub> phase, which was 107.02 ± 1.8 KJ/mol, 94.33 ± 1.7 KJ/mol, 90.33 ± 1.7 KJ/mol and 90.28 ± 1.6 KJ/mol for 0Zn, 0.4Zn, 0.8Zn and 1.2Zn alloy, respectively. The area number density of the T<sub>1</sub> precipitate ranged from 97.0 ± 4.4 pcs/μm<sup>2</sup> to 118.2 ± 2.8 pcs/μm<sup>2</sup> as the Zn content increased from 0 to 1.2 wt.%. Consequently, the addition of Zn promoted the precipitation of the T<sub>1</sub> phase. Therefore, the peak hardness and tensile strength of the alloy also increased with the increase in the Zn content, and the hardness of the alloy with Zn content of 1.2 wt.% increased by 16.5 ± 1.4 HV; meanwhile, the ultimate tensile strength increased by 46.5 ± 2.5 MPa. Therefore, the area number density of precipitates increased and improved the strength of the Zn-containing alloy.
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spelling doaj.art-337a46ff8c844cb79292adb1524276f72024-04-12T13:22:00ZengMDPI AGMaterials1996-19442024-03-01177156210.3390/ma17071562Influence of Zn Addition on the Aging Precipitate Behavior and Mechanical Properties of Al-Cu-Li AlloyMeiqi Wang0Lizhen Yan1Xiwu Li2Yongan Zhang3Zhihui Li4Kai Wen5Hongwei Liu6Baiqing Xiong7State Key Laboratory of Nonferrous Metals and Processes, China GRINM Group Co., Ltd., Beijing 100088, ChinaState Key Laboratory of Nonferrous Metals and Processes, China GRINM Group Co., Ltd., Beijing 100088, ChinaState Key Laboratory of Nonferrous Metals and Processes, China GRINM Group Co., Ltd., Beijing 100088, ChinaState Key Laboratory of Nonferrous Metals and Processes, China GRINM Group Co., Ltd., Beijing 100088, ChinaState Key Laboratory of Nonferrous Metals and Processes, China GRINM Group Co., Ltd., Beijing 100088, ChinaState Key Laboratory of Nonferrous Metals and Processes, China GRINM Group Co., Ltd., Beijing 100088, ChinaState Key Laboratory of Nonferrous Metals and Processes, China GRINM Group Co., Ltd., Beijing 100088, ChinaState Key Laboratory of Nonferrous Metals and Processes, China GRINM Group Co., Ltd., Beijing 100088, ChinaIn the present work, the effect of Zn on the aging precipitates and mechanical properties of Al-Cu-Li alloys was investigated by Vickers hardness, tensile tests, transmission electron microscopy (TEM) and differential scanning calorimetry (DSC). The results indicated that the addition of Zn reduced the activation energy of the T<sub>1</sub> phase and makes it easier to precipitate. The activation energy of the T<sub>1</sub> phase, which was 107.02 ± 1.8 KJ/mol, 94.33 ± 1.7 KJ/mol, 90.33 ± 1.7 KJ/mol and 90.28 ± 1.6 KJ/mol for 0Zn, 0.4Zn, 0.8Zn and 1.2Zn alloy, respectively. The area number density of the T<sub>1</sub> precipitate ranged from 97.0 ± 4.4 pcs/μm<sup>2</sup> to 118.2 ± 2.8 pcs/μm<sup>2</sup> as the Zn content increased from 0 to 1.2 wt.%. Consequently, the addition of Zn promoted the precipitation of the T<sub>1</sub> phase. Therefore, the peak hardness and tensile strength of the alloy also increased with the increase in the Zn content, and the hardness of the alloy with Zn content of 1.2 wt.% increased by 16.5 ± 1.4 HV; meanwhile, the ultimate tensile strength increased by 46.5 ± 2.5 MPa. Therefore, the area number density of precipitates increased and improved the strength of the Zn-containing alloy.https://www.mdpi.com/1996-1944/17/7/1562Al-Cu-Li alloyZn additionT<sub>1</sub> precipitatemechanical properties
spellingShingle Meiqi Wang
Lizhen Yan
Xiwu Li
Yongan Zhang
Zhihui Li
Kai Wen
Hongwei Liu
Baiqing Xiong
Influence of Zn Addition on the Aging Precipitate Behavior and Mechanical Properties of Al-Cu-Li Alloy
Materials
Al-Cu-Li alloy
Zn addition
T<sub>1</sub> precipitate
mechanical properties
title Influence of Zn Addition on the Aging Precipitate Behavior and Mechanical Properties of Al-Cu-Li Alloy
title_full Influence of Zn Addition on the Aging Precipitate Behavior and Mechanical Properties of Al-Cu-Li Alloy
title_fullStr Influence of Zn Addition on the Aging Precipitate Behavior and Mechanical Properties of Al-Cu-Li Alloy
title_full_unstemmed Influence of Zn Addition on the Aging Precipitate Behavior and Mechanical Properties of Al-Cu-Li Alloy
title_short Influence of Zn Addition on the Aging Precipitate Behavior and Mechanical Properties of Al-Cu-Li Alloy
title_sort influence of zn addition on the aging precipitate behavior and mechanical properties of al cu li alloy
topic Al-Cu-Li alloy
Zn addition
T<sub>1</sub> precipitate
mechanical properties
url https://www.mdpi.com/1996-1944/17/7/1562
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AT zhihuili influenceofznadditionontheagingprecipitatebehaviorandmechanicalpropertiesofalculialloy
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