Control of Properties through Hydrogen Bonding Interactions in Conjugated Polymers
Abstract Molecular design is crucial for endowing conjugated polymers (CPs) with unique properties and enhanced electronic performance. Introducing Hydrogen‐bonding (H‐bonding) into CPs has been a broadly exploited, yet still emerging strategy capable of tuning a range of properties encompassing sol...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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Wiley
2024-02-01
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| Series: | Advanced Science |
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| Online Access: | https://doi.org/10.1002/advs.202305356 |
| _version_ | 1827197122434301952 |
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| author | Qingpei Wan Barry C. Thompson |
| author_facet | Qingpei Wan Barry C. Thompson |
| author_sort | Qingpei Wan |
| collection | DOAJ |
| description | Abstract Molecular design is crucial for endowing conjugated polymers (CPs) with unique properties and enhanced electronic performance. Introducing Hydrogen‐bonding (H‐bonding) into CPs has been a broadly exploited, yet still emerging strategy capable of tuning a range of properties encompassing solubility, crystallinity, electronic properties, solid‐state morphology, and stability, as well as mechanical properties and self‐healing properties. Different H‐bonding groups can be utilized to tailor CPs properties based on the applications of interest. This review provides an overview of classes of H‐bonding CPs (assorted by the different H‐bond functional groups), the synthetic methods to introduce the corresponding H‐bond functional groups and the impact of H‐bonding in CPs on corresponding electronic and materials properties. Recent advances in addressing the trade‐off between electronic performance and mechanical durability are also highlighted. Furthermore, insights into future directions and prospects for H‐bonded CPs are discussed. |
| first_indexed | 2024-03-07T22:48:20Z |
| format | Article |
| id | doaj.art-33911f55d866457dbcf18ae60a669e5b |
| institution | Directory Open Access Journal |
| issn | 2198-3844 |
| language | English |
| last_indexed | 2025-03-21T09:56:06Z |
| publishDate | 2024-02-01 |
| publisher | Wiley |
| record_format | Article |
| series | Advanced Science |
| spelling | doaj.art-33911f55d866457dbcf18ae60a669e5b2024-07-05T09:51:16ZengWileyAdvanced Science2198-38442024-02-01118n/an/a10.1002/advs.202305356Control of Properties through Hydrogen Bonding Interactions in Conjugated PolymersQingpei Wan0Barry C. Thompson1Department of Chemistry and Loker Hydrocarbon Research Institute University of Southern California Los Angeles CA 90089‐1661 USADepartment of Chemistry and Loker Hydrocarbon Research Institute University of Southern California Los Angeles CA 90089‐1661 USAAbstract Molecular design is crucial for endowing conjugated polymers (CPs) with unique properties and enhanced electronic performance. Introducing Hydrogen‐bonding (H‐bonding) into CPs has been a broadly exploited, yet still emerging strategy capable of tuning a range of properties encompassing solubility, crystallinity, electronic properties, solid‐state morphology, and stability, as well as mechanical properties and self‐healing properties. Different H‐bonding groups can be utilized to tailor CPs properties based on the applications of interest. This review provides an overview of classes of H‐bonding CPs (assorted by the different H‐bond functional groups), the synthetic methods to introduce the corresponding H‐bond functional groups and the impact of H‐bonding in CPs on corresponding electronic and materials properties. Recent advances in addressing the trade‐off between electronic performance and mechanical durability are also highlighted. Furthermore, insights into future directions and prospects for H‐bonded CPs are discussed.https://doi.org/10.1002/advs.202305356conjugated polymershydrogen bondsorganic electronics |
| spellingShingle | Qingpei Wan Barry C. Thompson Control of Properties through Hydrogen Bonding Interactions in Conjugated Polymers Advanced Science conjugated polymers hydrogen bonds organic electronics |
| title | Control of Properties through Hydrogen Bonding Interactions in Conjugated Polymers |
| title_full | Control of Properties through Hydrogen Bonding Interactions in Conjugated Polymers |
| title_fullStr | Control of Properties through Hydrogen Bonding Interactions in Conjugated Polymers |
| title_full_unstemmed | Control of Properties through Hydrogen Bonding Interactions in Conjugated Polymers |
| title_short | Control of Properties through Hydrogen Bonding Interactions in Conjugated Polymers |
| title_sort | control of properties through hydrogen bonding interactions in conjugated polymers |
| topic | conjugated polymers hydrogen bonds organic electronics |
| url | https://doi.org/10.1002/advs.202305356 |
| work_keys_str_mv | AT qingpeiwan controlofpropertiesthroughhydrogenbondinginteractionsinconjugatedpolymers AT barrycthompson controlofpropertiesthroughhydrogenbondinginteractionsinconjugatedpolymers |