Study on the Application of Shell-Activated Carbon for the Adsorption of Dyes and Antibiotics

In this study, we prepared homemade fruit shell-activated carbon (SAC) with efficient adsorption of new pollutants and used it in the removal of methylene blue dye (MB) and ofloxacin antibiotic (OFL) in water. We fitted the experimental data for MB and OFL adsorption with isothermal and kinetic mode...

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Main Authors: Jinlong Wang, Rui Wang, Jingqian Ma, Yongjun Sun
Format: Article
Language:English
Published: MDPI AG 2022-11-01
Series:Water
Subjects:
Online Access:https://www.mdpi.com/2073-4441/14/22/3752
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author Jinlong Wang
Rui Wang
Jingqian Ma
Yongjun Sun
author_facet Jinlong Wang
Rui Wang
Jingqian Ma
Yongjun Sun
author_sort Jinlong Wang
collection DOAJ
description In this study, we prepared homemade fruit shell-activated carbon (SAC) with efficient adsorption of new pollutants and used it in the removal of methylene blue dye (MB) and ofloxacin antibiotic (OFL) in water. We fitted the experimental data for MB and OFL adsorption with isothermal and kinetic models and performed extensive characterization to study the properties of SAC. We also studied the effects of solution pH, dosage amount, initial concentration, and coexisting ions on the adsorption capacity. The results show that SAC has a rich pore structure, and electrostatic interactions are its main adsorption mechanism. Adjusting the solution pH by changing the SAC dosage and removing the K<sup>+</sup>, SO<sub>4</sub><sup>2−</sup>, and Cu<sup>2+</sup> could increase the removal of MB and OFL to 99.9% and 97.6%, respectively. In addition, the adsorption capacity of SAC for MB remained at more than 50% of the initial state after three iterations of adsorption regeneration, showing a good regeneration ability. These results show the potential of SAC in replacing conventional activated carbon to remove new pollutants.
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spelling doaj.art-33a05201150f4790b18a045ae0543be72023-11-24T10:22:26ZengMDPI AGWater2073-44412022-11-011422375210.3390/w14223752Study on the Application of Shell-Activated Carbon for the Adsorption of Dyes and AntibioticsJinlong Wang0Rui Wang1Jingqian Ma2Yongjun Sun3College of Environmental Science and Engineering, Nanjing Tech University, Nanjing 211816, ChinaCollege of Urban Construction, Nanjing Tech University, Nanjing 211800, ChinaCollege of Urban Construction, Nanjing Tech University, Nanjing 211800, ChinaCollege of Urban Construction, Nanjing Tech University, Nanjing 211800, ChinaIn this study, we prepared homemade fruit shell-activated carbon (SAC) with efficient adsorption of new pollutants and used it in the removal of methylene blue dye (MB) and ofloxacin antibiotic (OFL) in water. We fitted the experimental data for MB and OFL adsorption with isothermal and kinetic models and performed extensive characterization to study the properties of SAC. We also studied the effects of solution pH, dosage amount, initial concentration, and coexisting ions on the adsorption capacity. The results show that SAC has a rich pore structure, and electrostatic interactions are its main adsorption mechanism. Adjusting the solution pH by changing the SAC dosage and removing the K<sup>+</sup>, SO<sub>4</sub><sup>2−</sup>, and Cu<sup>2+</sup> could increase the removal of MB and OFL to 99.9% and 97.6%, respectively. In addition, the adsorption capacity of SAC for MB remained at more than 50% of the initial state after three iterations of adsorption regeneration, showing a good regeneration ability. These results show the potential of SAC in replacing conventional activated carbon to remove new pollutants.https://www.mdpi.com/2073-4441/14/22/3752shell activated carbonmethylene blueofloxacinadsorption
spellingShingle Jinlong Wang
Rui Wang
Jingqian Ma
Yongjun Sun
Study on the Application of Shell-Activated Carbon for the Adsorption of Dyes and Antibiotics
Water
shell activated carbon
methylene blue
ofloxacin
adsorption
title Study on the Application of Shell-Activated Carbon for the Adsorption of Dyes and Antibiotics
title_full Study on the Application of Shell-Activated Carbon for the Adsorption of Dyes and Antibiotics
title_fullStr Study on the Application of Shell-Activated Carbon for the Adsorption of Dyes and Antibiotics
title_full_unstemmed Study on the Application of Shell-Activated Carbon for the Adsorption of Dyes and Antibiotics
title_short Study on the Application of Shell-Activated Carbon for the Adsorption of Dyes and Antibiotics
title_sort study on the application of shell activated carbon for the adsorption of dyes and antibiotics
topic shell activated carbon
methylene blue
ofloxacin
adsorption
url https://www.mdpi.com/2073-4441/14/22/3752
work_keys_str_mv AT jinlongwang studyontheapplicationofshellactivatedcarbonfortheadsorptionofdyesandantibiotics
AT ruiwang studyontheapplicationofshellactivatedcarbonfortheadsorptionofdyesandantibiotics
AT jingqianma studyontheapplicationofshellactivatedcarbonfortheadsorptionofdyesandantibiotics
AT yongjunsun studyontheapplicationofshellactivatedcarbonfortheadsorptionofdyesandantibiotics