Effect of Operating Conditions on Sulfur and Metal Content of Basrah Crude Oil

In the present work, Basrah crude oil, atmospheric distillate of 305-623 K boiling range, vacuum distillate of 623-823 K boiling range, and wide petroleum distillate of boiling range 305-823 K are hydrotreated in trickle bed reactor using Cobalt- Molybdenum alumina as a catalyst. Hydrotreating tempe...

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Main Authors: Muzher M. Ibraheem, Abdulhaleem A. Mohammad, Ayser T. Jarullah
Format: Article
Language:English
Published: Tikrit University 2009-06-01
Series:Tikrit Journal of Engineering Sciences
Online Access:https://tj-es.com/ojs/index.php/tjes/article/view/599
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author Muzher M. Ibraheem
Abdulhaleem A. Mohammad
Ayser T. Jarullah
author_facet Muzher M. Ibraheem
Abdulhaleem A. Mohammad
Ayser T. Jarullah
author_sort Muzher M. Ibraheem
collection DOAJ
description In the present work, Basrah crude oil, atmospheric distillate of 305-623 K boiling range, vacuum distillate of 623-823 K boiling range, and wide petroleum distillate of boiling range 305-823 K are hydrotreated in trickle bed reactor using Cobalt- Molybdenum alumina as a catalyst. Hydrotreating temperatures are 598-648K, 598- 673K, 648-673K and 648K respectively while LHSV are 0.7-2 hr-1, 1 hr-1, 0.7-2 hr-1 respectively. The operating pressure and H2/Oil ratio for all experiments are kept constant at 3 Mpa and 300 liter/liter. The results show that Sulphur and metal content decreased with increasing temperature and decreasing LHSV. Vacuum residue of boiling range above 823K is mixed with hydrotreated atmospheric distillate, vacuum distillate and with the hydrotreated wide petroleum distillate. The temperature for hydrotreating the mixed sample is 648K and LHSV is 1 hr-1. It was found that hydrotreating crude oil is the best choice since it gives the highest removal of sulphur, vanadium and cobalt removal..
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spelling doaj.art-33dfffe72c864c4384b400e91633ddaa2023-07-12T12:55:54ZengTikrit UniversityTikrit Journal of Engineering Sciences1813-162X2312-75892009-06-0116210.25130/tjes.16.2.04Effect of Operating Conditions on Sulfur and Metal Content of Basrah Crude OilMuzher M. Ibraheem0Abdulhaleem A. Mohammad1Ayser T. Jarullah2Chemical Eng. Dept., Tikrit University, IraqChemical Eng. Dept., University of Baghdad, IraqChemical Eng. Dept., Tikrit University, IraqIn the present work, Basrah crude oil, atmospheric distillate of 305-623 K boiling range, vacuum distillate of 623-823 K boiling range, and wide petroleum distillate of boiling range 305-823 K are hydrotreated in trickle bed reactor using Cobalt- Molybdenum alumina as a catalyst. Hydrotreating temperatures are 598-648K, 598- 673K, 648-673K and 648K respectively while LHSV are 0.7-2 hr-1, 1 hr-1, 0.7-2 hr-1 respectively. The operating pressure and H2/Oil ratio for all experiments are kept constant at 3 Mpa and 300 liter/liter. The results show that Sulphur and metal content decreased with increasing temperature and decreasing LHSV. Vacuum residue of boiling range above 823K is mixed with hydrotreated atmospheric distillate, vacuum distillate and with the hydrotreated wide petroleum distillate. The temperature for hydrotreating the mixed sample is 648K and LHSV is 1 hr-1. It was found that hydrotreating crude oil is the best choice since it gives the highest removal of sulphur, vanadium and cobalt removal.. https://tj-es.com/ojs/index.php/tjes/article/view/599
spellingShingle Muzher M. Ibraheem
Abdulhaleem A. Mohammad
Ayser T. Jarullah
Effect of Operating Conditions on Sulfur and Metal Content of Basrah Crude Oil
Tikrit Journal of Engineering Sciences
title Effect of Operating Conditions on Sulfur and Metal Content of Basrah Crude Oil
title_full Effect of Operating Conditions on Sulfur and Metal Content of Basrah Crude Oil
title_fullStr Effect of Operating Conditions on Sulfur and Metal Content of Basrah Crude Oil
title_full_unstemmed Effect of Operating Conditions on Sulfur and Metal Content of Basrah Crude Oil
title_short Effect of Operating Conditions on Sulfur and Metal Content of Basrah Crude Oil
title_sort effect of operating conditions on sulfur and metal content of basrah crude oil
url https://tj-es.com/ojs/index.php/tjes/article/view/599
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