Heavy Metal Dispersion in a Hydrological Sub-Basin as Consequence of Mining Activity in Taxco, Guerrero (Southern Mexico)

The mining industry generates high concentrations of heavy metals (HMs) susceptible to being released into surface and ground water. The objective of this work was to determine the concentration and dispersion of HMs in surface water and ground water in a hydrological sub-basin located in southwest...

Full description

Bibliographic Details
Main Authors: Juan Carlos Ramírez-Javier, Alejandro Hermelindo Ramírez-Guzmán, Giovanni Hernández-Flores, Mario Alberto Hernández Hernández, Oscar Talavera-Mendoza, Sergio Adrián Salgado Souto, Alejandra Cortés-Silva
Format: Article
Language:English
Published: MDPI AG 2023-05-01
Series:Water
Subjects:
Online Access:https://www.mdpi.com/2073-4441/15/10/1950
_version_ 1797598002240552960
author Juan Carlos Ramírez-Javier
Alejandro Hermelindo Ramírez-Guzmán
Giovanni Hernández-Flores
Mario Alberto Hernández Hernández
Oscar Talavera-Mendoza
Sergio Adrián Salgado Souto
Alejandra Cortés-Silva
author_facet Juan Carlos Ramírez-Javier
Alejandro Hermelindo Ramírez-Guzmán
Giovanni Hernández-Flores
Mario Alberto Hernández Hernández
Oscar Talavera-Mendoza
Sergio Adrián Salgado Souto
Alejandra Cortés-Silva
author_sort Juan Carlos Ramírez-Javier
collection DOAJ
description The mining industry generates high concentrations of heavy metals (HMs) susceptible to being released into surface and ground water. The objective of this work was to determine the concentration and dispersion of HMs in surface water and ground water in a hydrological sub-basin located in southwest Mexico. The samples were collected as following: 24 samples from streams, rivers, and one lake, and 15 samples from springs, located along the Taxco-Cocula sub-basin. A total of 78 samples were collected in the dry and rainy seasons. Physicochemical parameters, major ions, and HMs were analyzed. The pH, Eh, electrical conductivity, and total dissolved solids were analyzed in situ, while the concentrations of anions, cations, and HMs were measured in the laboratory. The results were treated with multivariate analysis and PHREEQC simulation. The highest recorded values (in mg/L) were in surface water, where the HMs in the dry season were Al (28.63), As (0.60), Cd (1.78), Cu (1.10), Fe (68.27), Mn (21.47), Pb (0.02), and Zn (208.80). These high concentrations exceed the limits established by national and international regulations for drinking water. The ground water did not indicate pollutants associated to the mining industry. On the other hand, in the rainy season, the surface water showed a decrease in the concentrations of the measured heavy metals. The hypsometric gradient and the hydrogeological and meteorological characteristics of the Taxco-Cocula sub-basin are the factors that contribute to the dilution and dispersion of the HMs along the 60 km of its length.
first_indexed 2024-03-11T03:13:15Z
format Article
id doaj.art-340ba877a1e34b22ba8cb74f75c8997f
institution Directory Open Access Journal
issn 2073-4441
language English
last_indexed 2024-03-11T03:13:15Z
publishDate 2023-05-01
publisher MDPI AG
record_format Article
series Water
spelling doaj.art-340ba877a1e34b22ba8cb74f75c8997f2023-11-18T03:42:46ZengMDPI AGWater2073-44412023-05-011510195010.3390/w15101950Heavy Metal Dispersion in a Hydrological Sub-Basin as Consequence of Mining Activity in Taxco, Guerrero (Southern Mexico)Juan Carlos Ramírez-Javier0Alejandro Hermelindo Ramírez-Guzmán1Giovanni Hernández-Flores2Mario Alberto Hernández Hernández3Oscar Talavera-Mendoza4Sergio Adrián Salgado Souto5Alejandra Cortés-Silva6Facultad de Ecología Marina, Universidad Autónoma de Guerrero, Av. Gran Vía Tropical No. 20, Fracc. Las Playas, Acapulco 39390, MexicoEscuela Superior de Ciencias de la Tierra, Universidad Autónoma de Guerrero, Ex hacienda de San Juan Bautista s/n, Taxco de Alarcón 40323, MexicoCONACYT-Escuela Superior de Ciencias de la Tierra, Universidad Autónoma de Guerrero, Ex Hacienda San Juan Bautista s/n, Taxco de Alarcón 40323, MexicoCONACYT-Instituto de Geofísica, Universidad Nacional Autónoma de México, Ciudad Universitaria, Delegación Coyoacán, Ciudad de México 04510, MexicoEscuela Superior de Ciencias de la Tierra, Universidad Autónoma de Guerrero, Ex hacienda de San Juan Bautista s/n, Taxco de Alarcón 40323, MexicoEscuela Superior de Ciencias de la Tierra, Universidad Autónoma de Guerrero, Ex hacienda de San Juan Bautista s/n, Taxco de Alarcón 40323, MexicoInstituto de Geofísica, Universidad Nacional Autónoma de México, Ciudad Universitaria, Delegación Coyoacán, Ciudad de México 04510, MexicoThe mining industry generates high concentrations of heavy metals (HMs) susceptible to being released into surface and ground water. The objective of this work was to determine the concentration and dispersion of HMs in surface water and ground water in a hydrological sub-basin located in southwest Mexico. The samples were collected as following: 24 samples from streams, rivers, and one lake, and 15 samples from springs, located along the Taxco-Cocula sub-basin. A total of 78 samples were collected in the dry and rainy seasons. Physicochemical parameters, major ions, and HMs were analyzed. The pH, Eh, electrical conductivity, and total dissolved solids were analyzed in situ, while the concentrations of anions, cations, and HMs were measured in the laboratory. The results were treated with multivariate analysis and PHREEQC simulation. The highest recorded values (in mg/L) were in surface water, where the HMs in the dry season were Al (28.63), As (0.60), Cd (1.78), Cu (1.10), Fe (68.27), Mn (21.47), Pb (0.02), and Zn (208.80). These high concentrations exceed the limits established by national and international regulations for drinking water. The ground water did not indicate pollutants associated to the mining industry. On the other hand, in the rainy season, the surface water showed a decrease in the concentrations of the measured heavy metals. The hypsometric gradient and the hydrogeological and meteorological characteristics of the Taxco-Cocula sub-basin are the factors that contribute to the dilution and dispersion of the HMs along the 60 km of its length.https://www.mdpi.com/2073-4441/15/10/1950ground waterhydrogeochemistrymining wastesurface waterTaxco mining districtwater quality
spellingShingle Juan Carlos Ramírez-Javier
Alejandro Hermelindo Ramírez-Guzmán
Giovanni Hernández-Flores
Mario Alberto Hernández Hernández
Oscar Talavera-Mendoza
Sergio Adrián Salgado Souto
Alejandra Cortés-Silva
Heavy Metal Dispersion in a Hydrological Sub-Basin as Consequence of Mining Activity in Taxco, Guerrero (Southern Mexico)
Water
ground water
hydrogeochemistry
mining waste
surface water
Taxco mining district
water quality
title Heavy Metal Dispersion in a Hydrological Sub-Basin as Consequence of Mining Activity in Taxco, Guerrero (Southern Mexico)
title_full Heavy Metal Dispersion in a Hydrological Sub-Basin as Consequence of Mining Activity in Taxco, Guerrero (Southern Mexico)
title_fullStr Heavy Metal Dispersion in a Hydrological Sub-Basin as Consequence of Mining Activity in Taxco, Guerrero (Southern Mexico)
title_full_unstemmed Heavy Metal Dispersion in a Hydrological Sub-Basin as Consequence of Mining Activity in Taxco, Guerrero (Southern Mexico)
title_short Heavy Metal Dispersion in a Hydrological Sub-Basin as Consequence of Mining Activity in Taxco, Guerrero (Southern Mexico)
title_sort heavy metal dispersion in a hydrological sub basin as consequence of mining activity in taxco guerrero southern mexico
topic ground water
hydrogeochemistry
mining waste
surface water
Taxco mining district
water quality
url https://www.mdpi.com/2073-4441/15/10/1950
work_keys_str_mv AT juancarlosramirezjavier heavymetaldispersioninahydrologicalsubbasinasconsequenceofminingactivityintaxcoguerrerosouthernmexico
AT alejandrohermelindoramirezguzman heavymetaldispersioninahydrologicalsubbasinasconsequenceofminingactivityintaxcoguerrerosouthernmexico
AT giovannihernandezflores heavymetaldispersioninahydrologicalsubbasinasconsequenceofminingactivityintaxcoguerrerosouthernmexico
AT marioalbertohernandezhernandez heavymetaldispersioninahydrologicalsubbasinasconsequenceofminingactivityintaxcoguerrerosouthernmexico
AT oscartalaveramendoza heavymetaldispersioninahydrologicalsubbasinasconsequenceofminingactivityintaxcoguerrerosouthernmexico
AT sergioadriansalgadosouto heavymetaldispersioninahydrologicalsubbasinasconsequenceofminingactivityintaxcoguerrerosouthernmexico
AT alejandracortessilva heavymetaldispersioninahydrologicalsubbasinasconsequenceofminingactivityintaxcoguerrerosouthernmexico