Bis[2-(2-oxoindolin-3-ylidene)-N-phenylhydrazinecarbothioamidato-κ3O,N2,S]nickel(II) dimethylformamide monosolvate
The asymmetric unit of the title compound, [Ni(C15H11N4OS)2]·C3H7NO, contains one NiII complex molecule and one disordered dimethylformamide solvent molecule. The NiII ion is six-coordinated in a distorted octahedral geometry by two N, two O and two S atoms. An intramolecular C&...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-05-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812012834 |
| _version_ | 1819291345892671488 |
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| author | Amna Qasem Ali Abdussalam Salhin Hoong-Kun Fun Siang Guan Teoh Naser Eltaher Eltayeb |
| author_facet | Amna Qasem Ali Abdussalam Salhin Hoong-Kun Fun Siang Guan Teoh Naser Eltaher Eltayeb |
| author_sort | Amna Qasem Ali |
| collection | DOAJ |
| description | The asymmetric unit of the title compound, [Ni(C15H11N4OS)2]·C3H7NO, contains one NiII complex molecule and one disordered dimethylformamide solvent molecule. The NiII ion is six-coordinated in a distorted octahedral geometry by two N, two O and two S atoms. An intramolecular C—H...S hydrogen bond generates an S(6) ring motif. In the crystal, molecules are linked through intermolecular N—H...S, N—H...O, C—H...N, C—H...O and C—H...S hydrogen bonds into infinite two-dimensional network parallel to the ab plane. The structure is further stablized by weak C—H...π interactions. The dimethylformamide solvent molecule is disordered over two sets of sites in a 0.514 (15):0.486 (15) ratio. |
| first_indexed | 2024-12-24T03:37:10Z |
| format | Article |
| id | doaj.art-3416a88012f1462f91994c5d3031d998 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T03:37:10Z |
| publishDate | 2012-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-3416a88012f1462f91994c5d3031d9982022-12-21T17:17:01ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-05-01685m538m53910.1107/S1600536812012834Bis[2-(2-oxoindolin-3-ylidene)-N-phenylhydrazinecarbothioamidato-κ3O,N2,S]nickel(II) dimethylformamide monosolvateAmna Qasem AliAbdussalam SalhinHoong-Kun FunSiang Guan TeohNaser Eltaher EltayebThe asymmetric unit of the title compound, [Ni(C15H11N4OS)2]·C3H7NO, contains one NiII complex molecule and one disordered dimethylformamide solvent molecule. The NiII ion is six-coordinated in a distorted octahedral geometry by two N, two O and two S atoms. An intramolecular C—H...S hydrogen bond generates an S(6) ring motif. In the crystal, molecules are linked through intermolecular N—H...S, N—H...O, C—H...N, C—H...O and C—H...S hydrogen bonds into infinite two-dimensional network parallel to the ab plane. The structure is further stablized by weak C—H...π interactions. The dimethylformamide solvent molecule is disordered over two sets of sites in a 0.514 (15):0.486 (15) ratio.http://scripts.iucr.org/cgi-bin/paper?S1600536812012834 |
| spellingShingle | Amna Qasem Ali Abdussalam Salhin Hoong-Kun Fun Siang Guan Teoh Naser Eltaher Eltayeb Bis[2-(2-oxoindolin-3-ylidene)-N-phenylhydrazinecarbothioamidato-κ3O,N2,S]nickel(II) dimethylformamide monosolvate Acta Crystallographica Section E |
| title | Bis[2-(2-oxoindolin-3-ylidene)-N-phenylhydrazinecarbothioamidato-κ3O,N2,S]nickel(II) dimethylformamide monosolvate |
| title_full | Bis[2-(2-oxoindolin-3-ylidene)-N-phenylhydrazinecarbothioamidato-κ3O,N2,S]nickel(II) dimethylformamide monosolvate |
| title_fullStr | Bis[2-(2-oxoindolin-3-ylidene)-N-phenylhydrazinecarbothioamidato-κ3O,N2,S]nickel(II) dimethylformamide monosolvate |
| title_full_unstemmed | Bis[2-(2-oxoindolin-3-ylidene)-N-phenylhydrazinecarbothioamidato-κ3O,N2,S]nickel(II) dimethylformamide monosolvate |
| title_short | Bis[2-(2-oxoindolin-3-ylidene)-N-phenylhydrazinecarbothioamidato-κ3O,N2,S]nickel(II) dimethylformamide monosolvate |
| title_sort | bis 2 2 oxoindolin 3 ylidene n phenylhydrazinecarbothioamidato amp 954 3o n2 s nickel ii dimethylformamide monosolvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812012834 |
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