Dimethyl 9-Octadecenedioate and 9-Oktadecene from Methyl Oleate Via a Ruthenium-Catalyzed Homo Olefin Metathesis Reaction
Oleic acid, one of the major components of palm oil, has attracted much interest in modern oleochemistry. The internal olefin group in oleic acid is a useful functional group in the transformation of a fatty acid to other functional chemicals and materials. In this paper, we discuss the application...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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Universitas Indonesia
2017-12-01
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| Series: | International Journal of Technology |
| Subjects: | |
| Online Access: | http://ijtech.eng.ui.ac.id/article/view/772 |
| _version_ | 1797964965661900800 |
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| author | Robby Roswanda Ilham Putra Didin Mujahidin |
| author_facet | Robby Roswanda Ilham Putra Didin Mujahidin |
| author_sort | Robby Roswanda |
| collection | DOAJ |
| description | Oleic acid, one of the major components of palm oil, has attracted much interest in modern oleochemistry. The internal olefin group in oleic acid is a useful functional group in the transformation of a fatty acid to other functional chemicals and materials. In this paper, we discuss the application of the olefin metathesis reaction by preparing a long-chain dicarboxylic acid and alkene from the ester of oleic acid. The internal olefin metathesis reaction of methyl oleate produced dimethyl 9-oktadecendioate and 9-octadecene in the presence of a ruthenium Grubbs II (second generation) catalyst with a 51% yield. We also found that there was a higher amount of the E isomer products than the Z isomer products. |
| first_indexed | 2024-04-11T01:51:47Z |
| format | Article |
| id | doaj.art-34528a64fc6a4087bae93249147d5f05 |
| institution | Directory Open Access Journal |
| issn | 2086-9614 2087-2100 |
| language | English |
| last_indexed | 2024-04-11T01:51:47Z |
| publishDate | 2017-12-01 |
| publisher | Universitas Indonesia |
| record_format | Article |
| series | International Journal of Technology |
| spelling | doaj.art-34528a64fc6a4087bae93249147d5f052023-01-03T06:05:04ZengUniversitas IndonesiaInternational Journal of Technology2086-96142087-21002017-12-01881422142810.14716/ijtech.v8i8.772772Dimethyl 9-Octadecenedioate and 9-Oktadecene from Methyl Oleate Via a Ruthenium-Catalyzed Homo Olefin Metathesis ReactionRobby Roswanda0Ilham Putra1Didin Mujahidin2Institut Teknologi Bandung- Chemistry, ITB, Bandung and Indonesia<br/>-Inttitut Teknologi BandungOleic acid, one of the major components of palm oil, has attracted much interest in modern oleochemistry. The internal olefin group in oleic acid is a useful functional group in the transformation of a fatty acid to other functional chemicals and materials. In this paper, we discuss the application of the olefin metathesis reaction by preparing a long-chain dicarboxylic acid and alkene from the ester of oleic acid. The internal olefin metathesis reaction of methyl oleate produced dimethyl 9-oktadecendioate and 9-octadecene in the presence of a ruthenium Grubbs II (second generation) catalyst with a 51% yield. We also found that there was a higher amount of the E isomer products than the Z isomer products.http://ijtech.eng.ui.ac.id/article/view/772Dimethyl 9-oktadecenedioateMethyl oleateOlefin metathesis9-oktadecene |
| spellingShingle | Robby Roswanda Ilham Putra Didin Mujahidin Dimethyl 9-Octadecenedioate and 9-Oktadecene from Methyl Oleate Via a Ruthenium-Catalyzed Homo Olefin Metathesis Reaction International Journal of Technology Dimethyl 9-oktadecenedioate Methyl oleate Olefin metathesis 9-oktadecene |
| title | Dimethyl 9-Octadecenedioate and 9-Oktadecene from Methyl Oleate Via a Ruthenium-Catalyzed Homo Olefin Metathesis Reaction |
| title_full | Dimethyl 9-Octadecenedioate and 9-Oktadecene from Methyl Oleate Via a Ruthenium-Catalyzed Homo Olefin Metathesis Reaction |
| title_fullStr | Dimethyl 9-Octadecenedioate and 9-Oktadecene from Methyl Oleate Via a Ruthenium-Catalyzed Homo Olefin Metathesis Reaction |
| title_full_unstemmed | Dimethyl 9-Octadecenedioate and 9-Oktadecene from Methyl Oleate Via a Ruthenium-Catalyzed Homo Olefin Metathesis Reaction |
| title_short | Dimethyl 9-Octadecenedioate and 9-Oktadecene from Methyl Oleate Via a Ruthenium-Catalyzed Homo Olefin Metathesis Reaction |
| title_sort | dimethyl 9 octadecenedioate and 9 oktadecene from methyl oleate via a ruthenium catalyzed homo olefin metathesis reaction |
| topic | Dimethyl 9-oktadecenedioate Methyl oleate Olefin metathesis 9-oktadecene |
| url | http://ijtech.eng.ui.ac.id/article/view/772 |
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