Properties of Barium Cerate Thin Films Formed Using E-Beam Deposition

This article focuses on the properties of the BaCeO<sub>3</sub> thin films formed by electron-beam vapor deposition and investigates the formation of barium cerates on supports with different thermal expansion coefficients (Stainless Steel, Invar, Glass Sealing, and Inconel substrates) a...

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Main Authors: Monica Susana Campos Covarrubias, Mantas Sriubas, Kristina Bockute, Piotr Winiarz, Tadeusz Miruszewski, Wojciech Skubida, Daniel Jaworski, Michał Bartmański, Marek Szkodo, Maria Gazda, Giedrius Laukaitis
Format: Article
Language:English
Published: MDPI AG 2020-12-01
Series:Crystals
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Online Access:https://www.mdpi.com/2073-4352/10/12/1152
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author Monica Susana Campos Covarrubias
Mantas Sriubas
Kristina Bockute
Piotr Winiarz
Tadeusz Miruszewski
Wojciech Skubida
Daniel Jaworski
Michał Bartmański
Marek Szkodo
Maria Gazda
Giedrius Laukaitis
author_facet Monica Susana Campos Covarrubias
Mantas Sriubas
Kristina Bockute
Piotr Winiarz
Tadeusz Miruszewski
Wojciech Skubida
Daniel Jaworski
Michał Bartmański
Marek Szkodo
Maria Gazda
Giedrius Laukaitis
author_sort Monica Susana Campos Covarrubias
collection DOAJ
description This article focuses on the properties of the BaCeO<sub>3</sub> thin films formed by electron-beam vapor deposition and investigates the formation of barium cerates on supports with different thermal expansion coefficients (Stainless Steel, Invar, Glass Sealing, and Inconel substrates) and the influence of the technological parameters on the properties of the formed thin films with an emphasis on the stability of the films. Morphology and phase composition and mechanical and electrical properties were investigated. It was found that the main factors influencing the phase composition and morphology of the films are the temperature of the support and the deposition rate. However, the mechanical properties of the films are mostly influenced by strains introduced to thin films by using different supports. Two interesting features of the electrical properties of the studied strained films were noticed: the film with the highest in-plane tensile strain showed the lowest activation energy of total conductivity, whereas the film with the lowest strain showed the highest value of total conductivity.
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spelling doaj.art-3473825f3bd44f0e9ecae24a676ebe082023-11-21T01:25:13ZengMDPI AGCrystals2073-43522020-12-011012115210.3390/cryst10121152Properties of Barium Cerate Thin Films Formed Using E-Beam DepositionMonica Susana Campos Covarrubias0Mantas Sriubas1Kristina Bockute2Piotr Winiarz3Tadeusz Miruszewski4Wojciech Skubida5Daniel Jaworski6Michał Bartmański7Marek Szkodo8Maria Gazda9Giedrius Laukaitis10Physics Department, Kaunas University of Technology, LT-51368 Kaunas, LithuaniaPhysics Department, Kaunas University of Technology, LT-51368 Kaunas, LithuaniaPhysics Department, Kaunas University of Technology, LT-51368 Kaunas, LithuaniaInstitute of Nanotechnology and Materials Engineering, Faculty of Applied Physics and Mathematics and Advanced Materials Centre, Gdańsk University of Technology, 80-233 Gdańsk, PolandInstitute of Nanotechnology and Materials Engineering, Faculty of Applied Physics and Mathematics and Advanced Materials Centre, Gdańsk University of Technology, 80-233 Gdańsk, PolandInstitute of Nanotechnology and Materials Engineering, Faculty of Applied Physics and Mathematics and Advanced Materials Centre, Gdańsk University of Technology, 80-233 Gdańsk, PolandInstitute of Nanotechnology and Materials Engineering, Faculty of Applied Physics and Mathematics and Advanced Materials Centre, Gdańsk University of Technology, 80-233 Gdańsk, PolandDepartment of Materials Engineering and Bonding, Faculty of Mechanical Engineering, Gdańsk University of Technology, 80-233 Gdańsk, PolandDepartment of Materials Engineering and Bonding, Faculty of Mechanical Engineering, Gdańsk University of Technology, 80-233 Gdańsk, PolandInstitute of Nanotechnology and Materials Engineering, Faculty of Applied Physics and Mathematics and Advanced Materials Centre, Gdańsk University of Technology, 80-233 Gdańsk, PolandPhysics Department, Kaunas University of Technology, LT-51368 Kaunas, LithuaniaThis article focuses on the properties of the BaCeO<sub>3</sub> thin films formed by electron-beam vapor deposition and investigates the formation of barium cerates on supports with different thermal expansion coefficients (Stainless Steel, Invar, Glass Sealing, and Inconel substrates) and the influence of the technological parameters on the properties of the formed thin films with an emphasis on the stability of the films. Morphology and phase composition and mechanical and electrical properties were investigated. It was found that the main factors influencing the phase composition and morphology of the films are the temperature of the support and the deposition rate. However, the mechanical properties of the films are mostly influenced by strains introduced to thin films by using different supports. Two interesting features of the electrical properties of the studied strained films were noticed: the film with the highest in-plane tensile strain showed the lowest activation energy of total conductivity, whereas the film with the lowest strain showed the highest value of total conductivity.https://www.mdpi.com/2073-4352/10/12/1152BaCeO<sub>3</sub>thin filmse-beam physical vapor depositionmechanical propertiesstrainselectrical properties
spellingShingle Monica Susana Campos Covarrubias
Mantas Sriubas
Kristina Bockute
Piotr Winiarz
Tadeusz Miruszewski
Wojciech Skubida
Daniel Jaworski
Michał Bartmański
Marek Szkodo
Maria Gazda
Giedrius Laukaitis
Properties of Barium Cerate Thin Films Formed Using E-Beam Deposition
Crystals
BaCeO<sub>3</sub>
thin films
e-beam physical vapor deposition
mechanical properties
strains
electrical properties
title Properties of Barium Cerate Thin Films Formed Using E-Beam Deposition
title_full Properties of Barium Cerate Thin Films Formed Using E-Beam Deposition
title_fullStr Properties of Barium Cerate Thin Films Formed Using E-Beam Deposition
title_full_unstemmed Properties of Barium Cerate Thin Films Formed Using E-Beam Deposition
title_short Properties of Barium Cerate Thin Films Formed Using E-Beam Deposition
title_sort properties of barium cerate thin films formed using e beam deposition
topic BaCeO<sub>3</sub>
thin films
e-beam physical vapor deposition
mechanical properties
strains
electrical properties
url https://www.mdpi.com/2073-4352/10/12/1152
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