2′,7′-Dibromospiro[cyclopropane-1,9′-fluorene]
In the title compound, C15H10Br2, each molecule is situated on special postion mm, so the asymmetric unit contains one-quater of a molecule. The 2,7-dibromo-9H-fluorene fragment and three spirocyclopropane C atoms lie on different planes, which are perpendicular to each other. In the crystal, π–π in...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2014-07-01
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| Series: | Acta Crystallographica Section E |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536814014585 |
| _version_ | 1798017091200090112 |
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| author | Yue-yuan Xue Yong-qi Qin |
| author_facet | Yue-yuan Xue Yong-qi Qin |
| author_sort | Yue-yuan Xue |
| collection | DOAJ |
| description | In the title compound, C15H10Br2, each molecule is situated on special postion mm, so the asymmetric unit contains one-quater of a molecule. The 2,7-dibromo-9H-fluorene fragment and three spirocyclopropane C atoms lie on different planes, which are perpendicular to each other. In the crystal, π–π interactions between aromatic rings [intercentroid distance = 3.699 (3) Å] pack the molecules into stacks extending in [001]. |
| first_indexed | 2024-04-11T16:01:11Z |
| format | Article |
| id | doaj.art-347bb19b56df453baf51b9efee7a7386 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T16:01:11Z |
| publishDate | 2014-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-347bb19b56df453baf51b9efee7a73862022-12-22T04:14:58ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-07-01707o821o82110.1107/S1600536814014585cv54632′,7′-Dibromospiro[cyclopropane-1,9′-fluorene]Yue-yuan Xue0Yong-qi Qin1Department of Chemistry and Chemical Engineering, Lvliang University, Lvliang, Shanxi 033001, People's Republic of ChinaLaboratory of Medicinal Chemistry, Lvliang University, Lvliang, Shanxi 033001, People's Republic of ChinaIn the title compound, C15H10Br2, each molecule is situated on special postion mm, so the asymmetric unit contains one-quater of a molecule. The 2,7-dibromo-9H-fluorene fragment and three spirocyclopropane C atoms lie on different planes, which are perpendicular to each other. In the crystal, π–π interactions between aromatic rings [intercentroid distance = 3.699 (3) Å] pack the molecules into stacks extending in [001].http://scripts.iucr.org/cgi-bin/paper?S1600536814014585crystal structure |
| spellingShingle | Yue-yuan Xue Yong-qi Qin 2′,7′-Dibromospiro[cyclopropane-1,9′-fluorene] Acta Crystallographica Section E crystal structure |
| title | 2′,7′-Dibromospiro[cyclopropane-1,9′-fluorene] |
| title_full | 2′,7′-Dibromospiro[cyclopropane-1,9′-fluorene] |
| title_fullStr | 2′,7′-Dibromospiro[cyclopropane-1,9′-fluorene] |
| title_full_unstemmed | 2′,7′-Dibromospiro[cyclopropane-1,9′-fluorene] |
| title_short | 2′,7′-Dibromospiro[cyclopropane-1,9′-fluorene] |
| title_sort | 2 7 dibromospiro cyclopropane 1 9 fluorene |
| topic | crystal structure |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536814014585 |
| work_keys_str_mv | AT yueyuanxue 27dibromospirocyclopropane19fluorene AT yongqiqin 27dibromospirocyclopropane19fluorene |