Connecting Large Amplitude Oscillatory Shear Rheology to Steady Simple Shear Rheology and Application to Biomass Slurries
Large amplitude oscillatory shear (LAOS) rheology is often performed in order to complement steady simple shear (SSS) rheology, i.e., probe rheological properties of materials that cannot be not observed with SSS alone. However, it is difficult to measure the SSS rheology of some problematic materia...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
De Gruyter
2014-10-01
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| Series: | Applied Rheology |
| Subjects: | |
| Online Access: | https://doi.org/10.3933/applrheol-24-53075 |
| _version_ | 1819020182020947968 |
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| author | Stickel Jonathan J. Knutsen Jeffrey S. Liberatore Matthew W. |
| author_facet | Stickel Jonathan J. Knutsen Jeffrey S. Liberatore Matthew W. |
| author_sort | Stickel Jonathan J. |
| collection | DOAJ |
| description | Large amplitude oscillatory shear (LAOS) rheology is often performed in order to complement steady simple shear (SSS) rheology, i.e., probe rheological properties of materials that cannot be not observed with SSS alone. However, it is difficult to measure the SSS rheology of some problematic materials due to fracture and ejection, and LAOS may alleviate these issues, at least partially. Therefore, it is of interest to obtain SSS rheology information from LAOS measurements. We show that a constitutive modeling approach may be used to unify the analysis of LAOS data obtained from different viscometric geometries and modes of control and that the LAOS data may be used to predict SSS profiles. A model elastoviscoplastic material, a Carbopol solution, was used to validate the approach experimentally. LAOS rheometry of problematic biomass slurries was also performed, and the SSS profiles for the slurries were predicted with more confidence than could be obtained from SSS measurements directly. |
| first_indexed | 2024-12-21T03:47:08Z |
| format | Article |
| id | doaj.art-34841ebf31164963b7fd947094170545 |
| institution | Directory Open Access Journal |
| issn | 1617-8106 |
| language | English |
| last_indexed | 2024-12-21T03:47:08Z |
| publishDate | 2014-10-01 |
| publisher | De Gruyter |
| record_format | Article |
| series | Applied Rheology |
| spelling | doaj.art-34841ebf31164963b7fd9470941705452022-12-21T19:17:03ZengDe GruyterApplied Rheology1617-81062014-10-01245243310.3933/applrheol-24-53075Connecting Large Amplitude Oscillatory Shear Rheology to Steady Simple Shear Rheology and Application to Biomass SlurriesStickel Jonathan J.0Knutsen Jeffrey S.1Liberatore Matthew W.2National Bioenergy Center, National Renewable Energy Laboratory, 15013 Denver West Parkway,Golden, CO 80401, USANational Bioenergy Center, National Renewable Energy Laboratory, 15013 Denver West Parkway,Golden, CO 80401, USADepartment of Chemical and Biological Engineering, Colorado School of Mines, 1500 Illinois Street,Golden, CO 80401, USALarge amplitude oscillatory shear (LAOS) rheology is often performed in order to complement steady simple shear (SSS) rheology, i.e., probe rheological properties of materials that cannot be not observed with SSS alone. However, it is difficult to measure the SSS rheology of some problematic materials due to fracture and ejection, and LAOS may alleviate these issues, at least partially. Therefore, it is of interest to obtain SSS rheology information from LAOS measurements. We show that a constitutive modeling approach may be used to unify the analysis of LAOS data obtained from different viscometric geometries and modes of control and that the LAOS data may be used to predict SSS profiles. A model elastoviscoplastic material, a Carbopol solution, was used to validate the approach experimentally. LAOS rheometry of problematic biomass slurries was also performed, and the SSS profiles for the slurries were predicted with more confidence than could be obtained from SSS measurements directly.https://doi.org/10.3933/applrheol-24-53075laoselastoviscoplasticyield stresscarbopolbiomass slurry |
| spellingShingle | Stickel Jonathan J. Knutsen Jeffrey S. Liberatore Matthew W. Connecting Large Amplitude Oscillatory Shear Rheology to Steady Simple Shear Rheology and Application to Biomass Slurries Applied Rheology laos elastoviscoplastic yield stress carbopol biomass slurry |
| title | Connecting Large Amplitude Oscillatory Shear Rheology to Steady Simple Shear Rheology and Application to Biomass Slurries |
| title_full | Connecting Large Amplitude Oscillatory Shear Rheology to Steady Simple Shear Rheology and Application to Biomass Slurries |
| title_fullStr | Connecting Large Amplitude Oscillatory Shear Rheology to Steady Simple Shear Rheology and Application to Biomass Slurries |
| title_full_unstemmed | Connecting Large Amplitude Oscillatory Shear Rheology to Steady Simple Shear Rheology and Application to Biomass Slurries |
| title_short | Connecting Large Amplitude Oscillatory Shear Rheology to Steady Simple Shear Rheology and Application to Biomass Slurries |
| title_sort | connecting large amplitude oscillatory shear rheology to steady simple shear rheology and application to biomass slurries |
| topic | laos elastoviscoplastic yield stress carbopol biomass slurry |
| url | https://doi.org/10.3933/applrheol-24-53075 |
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