Crystal structure of (2E,3E)-N2,N3-bis(3-ethyl-[1,1′-biphenyl]-4-yl)butane-2,3-diimine
In the title compound, C32H32N2, synthesized by the condensation reaction of 2-ethyl-4-phenylaniline and 2,3-butanedione, the conformation about the C=N bonds is E and the substituted biphenyl units are trans to one another. In the two biphenyl ring systems, the planes of the two rings are inclined...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2015-04-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989015005071 |
| _version_ | 1818321540581687296 |
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| author | Yan Zhao Jianchao Yuan Jie Zhao Shenglan Zhao |
| author_facet | Yan Zhao Jianchao Yuan Jie Zhao Shenglan Zhao |
| author_sort | Yan Zhao |
| collection | DOAJ |
| description | In the title compound, C32H32N2, synthesized by the condensation reaction of 2-ethyl-4-phenylaniline and 2,3-butanedione, the conformation about the C=N bonds is E and the substituted biphenyl units are trans to one another. In the two biphenyl ring systems, the planes of the two rings are inclined to one another by 25.25 (19) and 28.01 (19)°. The planes of the ethyl-substituted benzene rings are inclined to one another by 20.23 (19)° and to the mean plane of the butane-2,3-diimine unit [maximum deviation = 0.014 (4) Å] by 83.19 (19) and 63.38 (19)°. In the crystal, molecules are linked by C—H...π interactions, forming sheets lying parallel to (101). |
| first_indexed | 2024-12-13T10:42:32Z |
| format | Article |
| id | doaj.art-34a2491903d64296a9985e11f7d4bbee |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-12-13T10:42:32Z |
| publishDate | 2015-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-34a2491903d64296a9985e11f7d4bbee2022-12-21T23:50:24ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902015-04-01714o251o25210.1107/S2056989015005071su5091Crystal structure of (2E,3E)-N2,N3-bis(3-ethyl-[1,1′-biphenyl]-4-yl)butane-2,3-diimineYan Zhao0Jianchao Yuan1Jie Zhao2Shenglan Zhao3Key Laboratory of Eco-Environment-Related Polymer Materials of Ministry of Education, Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry & Chemical Engineering, Northwest Normal University, Lanzhou 730070, People's Republic of ChinaKey Laboratory of Eco-Environment-Related Polymer Materials of Ministry of Education, Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry & Chemical Engineering, Northwest Normal University, Lanzhou 730070, People's Republic of ChinaKey Laboratory of Eco-Environment-Related Polymer Materials of Ministry of Education, Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry & Chemical Engineering, Northwest Normal University, Lanzhou 730070, People's Republic of ChinaKey Laboratory of Eco-Environment-Related Polymer Materials of Ministry of Education, Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry & Chemical Engineering, Northwest Normal University, Lanzhou 730070, People's Republic of ChinaIn the title compound, C32H32N2, synthesized by the condensation reaction of 2-ethyl-4-phenylaniline and 2,3-butanedione, the conformation about the C=N bonds is E and the substituted biphenyl units are trans to one another. In the two biphenyl ring systems, the planes of the two rings are inclined to one another by 25.25 (19) and 28.01 (19)°. The planes of the ethyl-substituted benzene rings are inclined to one another by 20.23 (19)° and to the mean plane of the butane-2,3-diimine unit [maximum deviation = 0.014 (4) Å] by 83.19 (19) and 63.38 (19)°. In the crystal, molecules are linked by C—H...π interactions, forming sheets lying parallel to (101).http://scripts.iucr.org/cgi-bin/paper?S2056989015005071crystal structureα-diiminecatalystC—H...π interactions |
| spellingShingle | Yan Zhao Jianchao Yuan Jie Zhao Shenglan Zhao Crystal structure of (2E,3E)-N2,N3-bis(3-ethyl-[1,1′-biphenyl]-4-yl)butane-2,3-diimine Acta Crystallographica Section E: Crystallographic Communications crystal structure α-diimine catalyst C—H...π interactions |
| title | Crystal structure of (2E,3E)-N2,N3-bis(3-ethyl-[1,1′-biphenyl]-4-yl)butane-2,3-diimine |
| title_full | Crystal structure of (2E,3E)-N2,N3-bis(3-ethyl-[1,1′-biphenyl]-4-yl)butane-2,3-diimine |
| title_fullStr | Crystal structure of (2E,3E)-N2,N3-bis(3-ethyl-[1,1′-biphenyl]-4-yl)butane-2,3-diimine |
| title_full_unstemmed | Crystal structure of (2E,3E)-N2,N3-bis(3-ethyl-[1,1′-biphenyl]-4-yl)butane-2,3-diimine |
| title_short | Crystal structure of (2E,3E)-N2,N3-bis(3-ethyl-[1,1′-biphenyl]-4-yl)butane-2,3-diimine |
| title_sort | crystal structure of 2e 3e n2 n3 bis 3 ethyl 1 1 biphenyl 4 yl butane 2 3 diimine |
| topic | crystal structure α-diimine catalyst C—H...π interactions |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989015005071 |
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