Selective hydrogenation of citral synthesis menthols over Nl-Cu/SiO2 catalysts in ionic liquids(离子液体中柠檬醛选择性催化加氢合成薄荷醇的研究)
研究制备了Ni-Cu/SiO2双功能催化剂，并在离子液体和有机溶剂介质中研究柠檬醛催化加氢合成薄荷醇反应.结果表明：离子液体中催化剂对柠檬醛分子中的2位C=C双键加氢更容易，提高了催化剂选择性，反应条件更为温和；特别是可调节酸度的[bmim][AlmCln]离子液体，在竞争性加氢中促进了柠檬醛向生成薄荷醇的方向转化；在2 MPa，80 ℃的反应条件下，柠檬醛转化率为100%，对薄荷醇的选择性为88.6%.而且，催化剂和离子液体可回收和重复使用....
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| Format: | Article |
| Language: | zho |
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Zhejiang University Press
2007-09-01
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| Series: | Zhejiang Daxue xuebao. Lixue ban |
| Subjects: | |
| Online Access: | https://doi.org/zjup/1008-9497.2007.34.5.556-559 |
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| author | NIANBao-yi(念保义) XUgang(徐刚) WUJian-ping(吴坚平) YANGLi-rong(杨立荣) |
| author_facet | NIANBao-yi(念保义) XUgang(徐刚) WUJian-ping(吴坚平) YANGLi-rong(杨立荣) |
| author_sort | NIANBao-yi(念保义) |
| collection | DOAJ |
| description | 研究制备了Ni-Cu/SiO2双功能催化剂，并在离子液体和有机溶剂介质中研究柠檬醛催化加氢合成薄荷醇反应.结果表明：离子液体中催化剂对柠檬醛分子中的2位C=C双键加氢更容易，提高了催化剂选择性，反应条件更为温和；特别是可调节酸度的[bmim][AlmCln]离子液体，在竞争性加氢中促进了柠檬醛向生成薄荷醇的方向转化；在2 MPa，80 ℃的反应条件下，柠檬醛转化率为100%，对薄荷醇的选择性为88.6%.而且，催化剂和离子液体可回收和重复使用. |
| first_indexed | 2024-04-24T17:00:19Z |
| format | Article |
| id | doaj.art-34a26d5fe8794a4ebcc58f47c79b236f |
| institution | Directory Open Access Journal |
| issn | 1008-9497 |
| language | zho |
| last_indexed | 2024-04-24T17:00:19Z |
| publishDate | 2007-09-01 |
| publisher | Zhejiang University Press |
| record_format | Article |
| series | Zhejiang Daxue xuebao. Lixue ban |
| spelling | doaj.art-34a26d5fe8794a4ebcc58f47c79b236f2024-03-29T01:58:25ZzhoZhejiang University PressZhejiang Daxue xuebao. Lixue ban1008-94972007-09-01345556559zjup/1008-9497.2007.34.5.556-559Selective hydrogenation of citral synthesis menthols over Nl-Cu/SiO2 catalysts in ionic liquids(离子液体中柠檬醛选择性催化加氢合成薄荷醇的研究)NIANBao-yi(念保义)0XUgang(徐刚)1WUJian-ping(吴坚平)2YANGLi-rong(杨立荣)3 1.Department of Chemistry and Biology Engineering, Sanming College, Sanming 365004, China( 1.三明学院化学与生物工程系，福建 三明 365004) 2.College of Material Science and Chemical Engineering, Zhejiang University, Hangzhou 310027, China( 2.浙江大学材料科学与化工学院生物工程研究所，浙江 杭州 310027) 2.College of Material Science and Chemical Engineering, Zhejiang University, Hangzhou 310027, China( 2.浙江大学材料科学与化工学院生物工程研究所，浙江 杭州 310027) 2.College of Material Science and Chemical Engineering, Zhejiang University, Hangzhou 310027, China( 2.浙江大学材料科学与化工学院生物工程研究所，浙江 杭州 310027)研究制备了Ni-Cu/SiO2双功能催化剂，并在离子液体和有机溶剂介质中研究柠檬醛催化加氢合成薄荷醇反应.结果表明：离子液体中催化剂对柠檬醛分子中的2位C=C双键加氢更容易，提高了催化剂选择性，反应条件更为温和；特别是可调节酸度的[bmim][AlmCln]离子液体，在竞争性加氢中促进了柠檬醛向生成薄荷醇的方向转化；在2 MPa，80 ℃的反应条件下，柠檬醛转化率为100%，对薄荷醇的选择性为88.6%.而且，催化剂和离子液体可回收和重复使用.https://doi.org/zjup/1008-9497.2007.34.5.556-559柠檬醛选择性加氢薄荷醇离子液体 |
| spellingShingle | NIANBao-yi(念保义) XUgang(徐刚) WUJian-ping(吴坚平) YANGLi-rong(杨立荣) Selective hydrogenation of citral synthesis menthols over Nl-Cu/SiO2 catalysts in ionic liquids(离子液体中柠檬醛选择性催化加氢合成薄荷醇的研究) Zhejiang Daxue xuebao. Lixue ban 柠檬醛 选择性加氢 薄荷醇 离子液体 |
| title | Selective hydrogenation of citral synthesis menthols over Nl-Cu/SiO2 catalysts in ionic liquids(离子液体中柠檬醛选择性催化加氢合成薄荷醇的研究) |
| title_full | Selective hydrogenation of citral synthesis menthols over Nl-Cu/SiO2 catalysts in ionic liquids(离子液体中柠檬醛选择性催化加氢合成薄荷醇的研究) |
| title_fullStr | Selective hydrogenation of citral synthesis menthols over Nl-Cu/SiO2 catalysts in ionic liquids(离子液体中柠檬醛选择性催化加氢合成薄荷醇的研究) |
| title_full_unstemmed | Selective hydrogenation of citral synthesis menthols over Nl-Cu/SiO2 catalysts in ionic liquids(离子液体中柠檬醛选择性催化加氢合成薄荷醇的研究) |
| title_short | Selective hydrogenation of citral synthesis menthols over Nl-Cu/SiO2 catalysts in ionic liquids(离子液体中柠檬醛选择性催化加氢合成薄荷醇的研究) |
| title_sort | selective hydrogenation of citral synthesis menthols over nl cu sio2 catalysts in ionic liquids 离子液体中柠檬醛选择性催化加氢合成薄荷醇的研究 |
| topic | 柠檬醛 选择性加氢 薄荷醇 离子液体 |
| url | https://doi.org/zjup/1008-9497.2007.34.5.556-559 |
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