Characterization of the Morphological and Chemical Profile of Different Families of Microplastics in Samples of Breathable Air

Microplastic (MP) contamination has become a problem of great interest to the community at large. The detection of these particles in different ecosystems and foods has been the subject of study. However, the focus of these investigations has been on the identification and quantification of PM by DS...

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Main Authors: Joaquín Hernández-Fernández, Esneyder Puello-Polo, John R. Castro-Suarez
Format: Article
Language:English
Published: MDPI AG 2023-01-01
Series:Molecules
Subjects:
Online Access:https://www.mdpi.com/1420-3049/28/3/1042
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author Joaquín Hernández-Fernández
Esneyder Puello-Polo
John R. Castro-Suarez
author_facet Joaquín Hernández-Fernández
Esneyder Puello-Polo
John R. Castro-Suarez
author_sort Joaquín Hernández-Fernández
collection DOAJ
description Microplastic (MP) contamination has become a problem of great interest to the community at large. The detection of these particles in different ecosystems and foods has been the subject of study. However, the focus of these investigations has been on the identification and quantification of PM by DSC and Pyr-GC/MS and not on how they are transported to reach the air we breathe. In this study, the values of morphological parameters for plastic particles in a range between 1 and 2000 µm, present in the breathable air of 20 neighborhoods in the city of Cartagena, Colombia, were obtained to determine the characteristics that make these particles airborne. The values of parameters were obtained, such as roundness, sphericity, curvature, and the convexity of the particle, as well as its compactness and size, which influence its transport through the air and its ability to be ingested and inhaled. The data obtained in this study allows for simulations and the analysis of the behavior of microplastics once in the environment to predict future settlements. The DSC showed us the melting temperatures of PP, PE, PET, and PS, the Pyr-GC/MS showed the fragmentation patterns, and the presence of these MPs in the samples was confirmed.
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spelling doaj.art-34ee9a797f8c420d9faf00b29b9baa492023-11-16T17:26:49ZengMDPI AGMolecules1420-30492023-01-01283104210.3390/molecules28031042Characterization of the Morphological and Chemical Profile of Different Families of Microplastics in Samples of Breathable AirJoaquín Hernández-Fernández0Esneyder Puello-Polo1John R. Castro-Suarez2Chemistry Program, Department of Natural and Exact Sciences, San Pablo Campus, University of Cartgena, Cartagena 130015, ColombiaGrupo de Investigación en Oxi, Hidrotratamiento Catalítico y Nuevos Materiales, Programa de Química-Ciencias Básicas, Universidad del Atlántico, Puerto Colombia 081001, ColombiaÁrea Básicas Exactas, Universidad del Sinú, Seccional Cartagena, Cartagena 130001, ColombiaMicroplastic (MP) contamination has become a problem of great interest to the community at large. The detection of these particles in different ecosystems and foods has been the subject of study. However, the focus of these investigations has been on the identification and quantification of PM by DSC and Pyr-GC/MS and not on how they are transported to reach the air we breathe. In this study, the values of morphological parameters for plastic particles in a range between 1 and 2000 µm, present in the breathable air of 20 neighborhoods in the city of Cartagena, Colombia, were obtained to determine the characteristics that make these particles airborne. The values of parameters were obtained, such as roundness, sphericity, curvature, and the convexity of the particle, as well as its compactness and size, which influence its transport through the air and its ability to be ingested and inhaled. The data obtained in this study allows for simulations and the analysis of the behavior of microplastics once in the environment to predict future settlements. The DSC showed us the melting temperatures of PP, PE, PET, and PS, the Pyr-GC/MS showed the fragmentation patterns, and the presence of these MPs in the samples was confirmed.https://www.mdpi.com/1420-3049/28/3/1042microplasticsrespirable airmorphological profilepollutionDSCPyr-GC/MS
spellingShingle Joaquín Hernández-Fernández
Esneyder Puello-Polo
John R. Castro-Suarez
Characterization of the Morphological and Chemical Profile of Different Families of Microplastics in Samples of Breathable Air
Molecules
microplastics
respirable air
morphological profile
pollution
DSC
Pyr-GC/MS
title Characterization of the Morphological and Chemical Profile of Different Families of Microplastics in Samples of Breathable Air
title_full Characterization of the Morphological and Chemical Profile of Different Families of Microplastics in Samples of Breathable Air
title_fullStr Characterization of the Morphological and Chemical Profile of Different Families of Microplastics in Samples of Breathable Air
title_full_unstemmed Characterization of the Morphological and Chemical Profile of Different Families of Microplastics in Samples of Breathable Air
title_short Characterization of the Morphological and Chemical Profile of Different Families of Microplastics in Samples of Breathable Air
title_sort characterization of the morphological and chemical profile of different families of microplastics in samples of breathable air
topic microplastics
respirable air
morphological profile
pollution
DSC
Pyr-GC/MS
url https://www.mdpi.com/1420-3049/28/3/1042
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