An Efficient Approach to Address Issues of Graphene Nanoplatelets (GNPs) Incorporation in Aluminium Powders and Their Compaction Behaviour
The exceptional potential of the graphene has not been yet fully translated into the Al matrix to achieve high-performance Al nanocomposite. This is due to some critical issues faced by graphene during its processing such as the dispersion uniformity, structure damage, compatibility/wettability, and...
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2018-01-01
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author | Zeeshan Baig Othman Mamat Mazli Mustapha Asad Mumtaz Mansoor Sarfraz Sajjad Haider |
author_facet | Zeeshan Baig Othman Mamat Mazli Mustapha Asad Mumtaz Mansoor Sarfraz Sajjad Haider |
author_sort | Zeeshan Baig |
collection | DOAJ |
description | The exceptional potential of the graphene has not been yet fully translated into the Al matrix to achieve high-performance Al nanocomposite. This is due to some critical issues faced by graphene during its processing such as the dispersion uniformity, structure damage, compatibility/wettability, and low graphene embedding content in Al matrix. In the present work, a new integrative method was adopted and named as “solvent dispersion and ball milling” (SDBM) to address the issues above efficiently in a single approach. This strategy involves effective graphene nanoplatelets (GNPs) solvent dispersion via surfactant decoration and solution ball milling employed to polyvinyl alcohol (PVA) coated Al with various GNPs content (0.5, 1 and 1.5 wt. %). Flaky Al powder morphology attained by optimizing ball milling parameters and used for further processing with GNPs. Detailed powders characterizations were conducted to investigate morphology, graphene dispersion, group functionalities by FTIR (Fourier transform infrared spectroscopy) spectroscopy and crystallinity by powder XRD (X-ray diffraction)analysis. Compaction behaviour and spring back effect of the GNPs/Al powders was also investigated at different compaction pressure (300 to 600 Mpa) and varying GNPs fractions. In response, green and sintered relative density (%) along with effect on the hardness of the nanocomposites samples were examined. Conclusively, in comparison with the unreinforced Al, GNP/Al nanocomposite with 1.5 wt. % GNPs exhibited the highest hardness gives 62% maximum increase than pure Al validates the effectiveness of the approach produces high fraction uniformly dispersed GNPs in Al matrix. |
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spelling | doaj.art-34fb02be5ae5452e9946ef4e069907fe2022-12-22T03:45:38ZengMDPI AGMetals2075-47012018-01-01829010.3390/met8020090met8020090An Efficient Approach to Address Issues of Graphene Nanoplatelets (GNPs) Incorporation in Aluminium Powders and Their Compaction BehaviourZeeshan Baig0Othman Mamat1Mazli Mustapha2Asad Mumtaz3Mansoor Sarfraz4Sajjad Haider5Department of Mechanical Engineering, Universiti Teknologi PETRONAS, 32610 Bandar Seri Iskandar, Perak, MalaysiaDepartment of Mechanical Engineering, Universiti Teknologi PETRONAS, 32610 Bandar Seri Iskandar, Perak, MalaysiaDepartment of Mechanical Engineering, Universiti Teknologi PETRONAS, 32610 Bandar Seri Iskandar, Perak, MalaysiaDepartment of Fundamental and Applied Sciences, Universiti Teknologi PETRONAS, 32610 Bandar Seri Iskandar, Perak, MalaysiaSustainable Energy Technologies Center, College of Engineering, King Saud University, Riyadh 11421, Saudi ArabiaDepartment of Chemical Engineering, College of Engineering, King Saud University, Riyadh 11421, Saudi ArabiaThe exceptional potential of the graphene has not been yet fully translated into the Al matrix to achieve high-performance Al nanocomposite. This is due to some critical issues faced by graphene during its processing such as the dispersion uniformity, structure damage, compatibility/wettability, and low graphene embedding content in Al matrix. In the present work, a new integrative method was adopted and named as “solvent dispersion and ball milling” (SDBM) to address the issues above efficiently in a single approach. This strategy involves effective graphene nanoplatelets (GNPs) solvent dispersion via surfactant decoration and solution ball milling employed to polyvinyl alcohol (PVA) coated Al with various GNPs content (0.5, 1 and 1.5 wt. %). Flaky Al powder morphology attained by optimizing ball milling parameters and used for further processing with GNPs. Detailed powders characterizations were conducted to investigate morphology, graphene dispersion, group functionalities by FTIR (Fourier transform infrared spectroscopy) spectroscopy and crystallinity by powder XRD (X-ray diffraction)analysis. Compaction behaviour and spring back effect of the GNPs/Al powders was also investigated at different compaction pressure (300 to 600 Mpa) and varying GNPs fractions. In response, green and sintered relative density (%) along with effect on the hardness of the nanocomposites samples were examined. Conclusively, in comparison with the unreinforced Al, GNP/Al nanocomposite with 1.5 wt. % GNPs exhibited the highest hardness gives 62% maximum increase than pure Al validates the effectiveness of the approach produces high fraction uniformly dispersed GNPs in Al matrix.http://www.mdpi.com/2075-4701/8/2/90graphenedispersionpowder processingball millingaluminium nanocomposite |
spellingShingle | Zeeshan Baig Othman Mamat Mazli Mustapha Asad Mumtaz Mansoor Sarfraz Sajjad Haider An Efficient Approach to Address Issues of Graphene Nanoplatelets (GNPs) Incorporation in Aluminium Powders and Their Compaction Behaviour Metals graphene dispersion powder processing ball milling aluminium nanocomposite |
title | An Efficient Approach to Address Issues of Graphene Nanoplatelets (GNPs) Incorporation in Aluminium Powders and Their Compaction Behaviour |
title_full | An Efficient Approach to Address Issues of Graphene Nanoplatelets (GNPs) Incorporation in Aluminium Powders and Their Compaction Behaviour |
title_fullStr | An Efficient Approach to Address Issues of Graphene Nanoplatelets (GNPs) Incorporation in Aluminium Powders and Their Compaction Behaviour |
title_full_unstemmed | An Efficient Approach to Address Issues of Graphene Nanoplatelets (GNPs) Incorporation in Aluminium Powders and Their Compaction Behaviour |
title_short | An Efficient Approach to Address Issues of Graphene Nanoplatelets (GNPs) Incorporation in Aluminium Powders and Their Compaction Behaviour |
title_sort | efficient approach to address issues of graphene nanoplatelets gnps incorporation in aluminium powders and their compaction behaviour |
topic | graphene dispersion powder processing ball milling aluminium nanocomposite |
url | http://www.mdpi.com/2075-4701/8/2/90 |
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