9,10-Bis{2-[1-(2-pyridylmethyl)imidazolium-3-yl]ethoxy}anthracene bis(hexafluoridophosphate)
The cation of the title compound, C36H34N6O22+·2PF6−, lies across a crystallographic inversion centre. The imidazole and pyridine rings form dihedral angles of 82.28 (5)° and 11.87 (7)°, respectively, with the anthracene ring system. The cryst...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008-01-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536807063842 |
| _version_ | 1798017763154853888 |
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| author | Li-Hui Guo Da-Bin Qin Shao-Jin Gu Gui-Yu Wang Jie-Wei Luo |
| author_facet | Li-Hui Guo Da-Bin Qin Shao-Jin Gu Gui-Yu Wang Jie-Wei Luo |
| author_sort | Li-Hui Guo |
| collection | DOAJ |
| description | The cation of the title compound, C36H34N6O22+·2PF6−, lies across a crystallographic inversion centre. The imidazole and pyridine rings form dihedral angles of 82.28 (5)° and 11.87 (7)°, respectively, with the anthracene ring system. The crystal packing is stabilized by π–π interactions between the pyridine ring and the central ring of anthracene, with a ring centroid–centroid distance of 3.684 (3) Å. The PF6− anion is disordered over three different positions with occupancies of 0.284 (6), 0.354 (8) and 0.362 (9). |
| first_indexed | 2024-04-11T16:12:59Z |
| format | Article |
| id | doaj.art-350861293bef4e19a7f6448c3e450088 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T16:12:59Z |
| publishDate | 2008-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-350861293bef4e19a7f6448c3e4500882022-12-22T04:14:37ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-01-01641o189o18910.1107/S16005368070638429,10-Bis{2-[1-(2-pyridylmethyl)imidazolium-3-yl]ethoxy}anthracene bis(hexafluoridophosphate)Li-Hui GuoDa-Bin QinShao-Jin GuGui-Yu WangJie-Wei LuoThe cation of the title compound, C36H34N6O22+·2PF6−, lies across a crystallographic inversion centre. The imidazole and pyridine rings form dihedral angles of 82.28 (5)° and 11.87 (7)°, respectively, with the anthracene ring system. The crystal packing is stabilized by π–π interactions between the pyridine ring and the central ring of anthracene, with a ring centroid–centroid distance of 3.684 (3) Å. The PF6− anion is disordered over three different positions with occupancies of 0.284 (6), 0.354 (8) and 0.362 (9).http://scripts.iucr.org/cgi-bin/paper?S1600536807063842 |
| spellingShingle | Li-Hui Guo Da-Bin Qin Shao-Jin Gu Gui-Yu Wang Jie-Wei Luo 9,10-Bis{2-[1-(2-pyridylmethyl)imidazolium-3-yl]ethoxy}anthracene bis(hexafluoridophosphate) Acta Crystallographica Section E |
| title | 9,10-Bis{2-[1-(2-pyridylmethyl)imidazolium-3-yl]ethoxy}anthracene bis(hexafluoridophosphate) |
| title_full | 9,10-Bis{2-[1-(2-pyridylmethyl)imidazolium-3-yl]ethoxy}anthracene bis(hexafluoridophosphate) |
| title_fullStr | 9,10-Bis{2-[1-(2-pyridylmethyl)imidazolium-3-yl]ethoxy}anthracene bis(hexafluoridophosphate) |
| title_full_unstemmed | 9,10-Bis{2-[1-(2-pyridylmethyl)imidazolium-3-yl]ethoxy}anthracene bis(hexafluoridophosphate) |
| title_short | 9,10-Bis{2-[1-(2-pyridylmethyl)imidazolium-3-yl]ethoxy}anthracene bis(hexafluoridophosphate) |
| title_sort | 9 10 bis 2 1 2 pyridylmethyl imidazolium 3 yl ethoxy anthracene bis hexafluoridophosphate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536807063842 |
| work_keys_str_mv | AT lihuiguo 910bis212pyridylmethylimidazolium3ylethoxyanthracenebishexafluoridophosphate AT dabinqin 910bis212pyridylmethylimidazolium3ylethoxyanthracenebishexafluoridophosphate AT shaojingu 910bis212pyridylmethylimidazolium3ylethoxyanthracenebishexafluoridophosphate AT guiyuwang 910bis212pyridylmethylimidazolium3ylethoxyanthracenebishexafluoridophosphate AT jieweiluo 910bis212pyridylmethylimidazolium3ylethoxyanthracenebishexafluoridophosphate |