Recent Advances and Perspectives on Supported Catalysts for Heterogeneous Hydrogen Production from Ammonia Borane
Abstract Ammonia borane (AB), a liquid hydrogen storage material, has attracted increasing attention for hydrogen utilization because of its high hydrogen content. However, the slow kinetics of AB hydrolysis and the indefinite catalytic mechanism remain significant problems for its large‐scale pract...
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| Format: | Article |
| Language: | English |
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Wiley
2023-07-01
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| Series: | Advanced Science |
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| Online Access: | https://doi.org/10.1002/advs.202300726 |
| _version_ | 1797770726552371200 |
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| author | Shuyan Guan Yanyan Liu Huanhuan Zhang Ruofan Shen Hao Wen Naixin Kang Jingjing Zhou Baozhong Liu Yanping Fan Jianchun Jiang Baojun Li |
| author_facet | Shuyan Guan Yanyan Liu Huanhuan Zhang Ruofan Shen Hao Wen Naixin Kang Jingjing Zhou Baozhong Liu Yanping Fan Jianchun Jiang Baojun Li |
| author_sort | Shuyan Guan |
| collection | DOAJ |
| description | Abstract Ammonia borane (AB), a liquid hydrogen storage material, has attracted increasing attention for hydrogen utilization because of its high hydrogen content. However, the slow kinetics of AB hydrolysis and the indefinite catalytic mechanism remain significant problems for its large‐scale practical application. Thus, the development of efficient AB hydrolysis catalysts and the determination of their catalytic mechanisms are significant and urgent. A summary of the preparation process and structural characteristics of various supported catalysts is presented in this paper, including graphite, metal‐organic frameworks (MOFs), metal oxides, carbon nitride (CN), molybdenum carbide (MoC), carbon nanotubes (CNTs), boron nitride (h‐BN), zeolites, carbon dots (CDs), and metal carbide and nitride (MXene). In addition, the relationship between the electronic structure and catalytic performance is discussed to ascertain the actual active sites in the catalytic process. The mechanism of AB hydrolysis catalysis is systematically discussed, and possible catalytic paths are summarized to provide theoretical considerations for the designing of efficient AB hydrolysis catalysts. Furthermore, three methods for stimulating AB from dehydrogenation by‐products and the design of possible hydrogen product‐regeneration systems are summarized. Finally, the remaining challenges and future research directions for the effective development of AB catalysts are discussed. |
| first_indexed | 2024-03-12T21:26:21Z |
| format | Article |
| id | doaj.art-352148a6e0d241a197979715c9b41122 |
| institution | Directory Open Access Journal |
| issn | 2198-3844 |
| language | English |
| last_indexed | 2024-03-12T21:26:21Z |
| publishDate | 2023-07-01 |
| publisher | Wiley |
| record_format | Article |
| series | Advanced Science |
| spelling | doaj.art-352148a6e0d241a197979715c9b411222023-07-28T06:53:00ZengWileyAdvanced Science2198-38442023-07-011021n/an/a10.1002/advs.202300726Recent Advances and Perspectives on Supported Catalysts for Heterogeneous Hydrogen Production from Ammonia BoraneShuyan Guan0Yanyan Liu1Huanhuan Zhang2Ruofan Shen3Hao Wen4Naixin Kang5Jingjing Zhou6Baozhong Liu7Yanping Fan8Jianchun Jiang9Baojun Li10College of Science Henan Agricultural University 95 Wenhua Road Zhengzhou 450002 P. R. ChinaCollege of Science Henan Agricultural University 95 Wenhua Road Zhengzhou 450002 P. R. ChinaResearch Center of Green Catalysis College of Chemistry School of Physics and Microelectronics Zhengzhou University 100 Science Road Zhengzhou 450001 P. R. ChinaResearch Center of Green Catalysis College of Chemistry School of Physics and Microelectronics Zhengzhou University 100 Science Road Zhengzhou 450001 P. R. ChinaResearch Center of Green Catalysis College of Chemistry School of Physics and Microelectronics Zhengzhou University 100 Science Road Zhengzhou 450001 P. R. ChinaISM UMR CNRS N° 5255 Univ. Bordeaux Talence Cedex 33405 FranceCollege of Science Henan Agricultural University 95 Wenhua Road Zhengzhou 450002 P. R. ChinaCollege of Chemistry and Chemical Engineering Henan Key Laboratory of Coal Green Conversion Henan Polytechnic University 2001 Century Avenue Jiaozuo 454000 P. R. ChinaCollege of Chemistry and Chemical Engineering Henan Key Laboratory of Coal Green Conversion Henan Polytechnic University 2001 Century Avenue Jiaozuo 454000 P. R. ChinaInstitute of Chemical Industry of Forest Products CAF National Engineering Lab for Biomass Chemical Utilization Key and Open Lab on Forest Chemical Engineering SFA 16 Suojinwucun Nanjing 210042 P. R. ChinaCollege of Science Henan Agricultural University 95 Wenhua Road Zhengzhou 450002 P. R. ChinaAbstract Ammonia borane (AB), a liquid hydrogen storage material, has attracted increasing attention for hydrogen utilization because of its high hydrogen content. However, the slow kinetics of AB hydrolysis and the indefinite catalytic mechanism remain significant problems for its large‐scale practical application. Thus, the development of efficient AB hydrolysis catalysts and the determination of their catalytic mechanisms are significant and urgent. A summary of the preparation process and structural characteristics of various supported catalysts is presented in this paper, including graphite, metal‐organic frameworks (MOFs), metal oxides, carbon nitride (CN), molybdenum carbide (MoC), carbon nanotubes (CNTs), boron nitride (h‐BN), zeolites, carbon dots (CDs), and metal carbide and nitride (MXene). In addition, the relationship between the electronic structure and catalytic performance is discussed to ascertain the actual active sites in the catalytic process. The mechanism of AB hydrolysis catalysis is systematically discussed, and possible catalytic paths are summarized to provide theoretical considerations for the designing of efficient AB hydrolysis catalysts. Furthermore, three methods for stimulating AB from dehydrogenation by‐products and the design of possible hydrogen product‐regeneration systems are summarized. Finally, the remaining challenges and future research directions for the effective development of AB catalysts are discussed.https://doi.org/10.1002/advs.202300726ammonia boranecatalyst mechanismregenerationstandardizationsupported catalysts |
| spellingShingle | Shuyan Guan Yanyan Liu Huanhuan Zhang Ruofan Shen Hao Wen Naixin Kang Jingjing Zhou Baozhong Liu Yanping Fan Jianchun Jiang Baojun Li Recent Advances and Perspectives on Supported Catalysts for Heterogeneous Hydrogen Production from Ammonia Borane Advanced Science ammonia borane catalyst mechanism regeneration standardization supported catalysts |
| title | Recent Advances and Perspectives on Supported Catalysts for Heterogeneous Hydrogen Production from Ammonia Borane |
| title_full | Recent Advances and Perspectives on Supported Catalysts for Heterogeneous Hydrogen Production from Ammonia Borane |
| title_fullStr | Recent Advances and Perspectives on Supported Catalysts for Heterogeneous Hydrogen Production from Ammonia Borane |
| title_full_unstemmed | Recent Advances and Perspectives on Supported Catalysts for Heterogeneous Hydrogen Production from Ammonia Borane |
| title_short | Recent Advances and Perspectives on Supported Catalysts for Heterogeneous Hydrogen Production from Ammonia Borane |
| title_sort | recent advances and perspectives on supported catalysts for heterogeneous hydrogen production from ammonia borane |
| topic | ammonia borane catalyst mechanism regeneration standardization supported catalysts |
| url | https://doi.org/10.1002/advs.202300726 |
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