A Review on Shape Memory Alloys with Martensitic Transition at Cryogenic Temperatures

Shape memory alloys (SMA) are functional materials known for their shape memory and pseudoelastic properties, which originated from a thermoelastic phase transition between two solid phases: austenite and martensite. The ranges of temperature at which austenite and martensite are stable depend prima...

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Main Authors: Adelaide Nespoli, Davide Ninarello, Carlo Fanciulli
Format: Article
Language:English
Published: MDPI AG 2023-07-01
Series:Metals
Subjects:
Online Access:https://www.mdpi.com/2075-4701/13/7/1311
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author Adelaide Nespoli
Davide Ninarello
Carlo Fanciulli
author_facet Adelaide Nespoli
Davide Ninarello
Carlo Fanciulli
author_sort Adelaide Nespoli
collection DOAJ
description Shape memory alloys (SMA) are functional materials known for their shape memory and pseudoelastic properties, which originated from a thermoelastic phase transition between two solid phases: austenite and martensite. The ranges of temperature at which austenite and martensite are stable depend primarily on the chemical composition and the thermomechanical history of the alloy. This work presents a broad overview of shape memory alloys presenting the thermoelastic phase transition at cryogenic temperatures—that is, at temperatures below the freezing point of water. Currently, this class of SMA is not very well explored due to the difficulties in conducting both structural and functional experimentations at very low temperatures. However, these materials are of great importance for extreme environments such as space. In this work, the different classes of cryogenic SMA will first be presented as a function of their phase transformation temperatures. Hints of their mechanical performance will also be reported. Cu-based systems have been identified as cryogenic SMA presenting the lowest phase transformation temperatures. The lowest measured M<sub>s</sub> (45 K) was found for the Cu-8.8Al-13.1Mn (wt.%) alloy.
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spelling doaj.art-352c6060862947b78239058ef0a3010a2023-11-18T20:30:55ZengMDPI AGMetals2075-47012023-07-01137131110.3390/met13071311A Review on Shape Memory Alloys with Martensitic Transition at Cryogenic TemperaturesAdelaide Nespoli0Davide Ninarello1Carlo Fanciulli2Consiglio Nazionale delle Ricerche—Istituto di Chimica della Materia Condensata e di Tecnologie per l’Energia (CNR-ICMATE), via G. Previati 1/e, 23900 Lecco, ItalyConsiglio Nazionale delle Ricerche—Istituto di Chimica della Materia Condensata e di Tecnologie per l’Energia (CNR-ICMATE), via G. Previati 1/e, 23900 Lecco, ItalyConsiglio Nazionale delle Ricerche—Istituto di Chimica della Materia Condensata e di Tecnologie per l’Energia (CNR-ICMATE), via G. Previati 1/e, 23900 Lecco, ItalyShape memory alloys (SMA) are functional materials known for their shape memory and pseudoelastic properties, which originated from a thermoelastic phase transition between two solid phases: austenite and martensite. The ranges of temperature at which austenite and martensite are stable depend primarily on the chemical composition and the thermomechanical history of the alloy. This work presents a broad overview of shape memory alloys presenting the thermoelastic phase transition at cryogenic temperatures—that is, at temperatures below the freezing point of water. Currently, this class of SMA is not very well explored due to the difficulties in conducting both structural and functional experimentations at very low temperatures. However, these materials are of great importance for extreme environments such as space. In this work, the different classes of cryogenic SMA will first be presented as a function of their phase transformation temperatures. Hints of their mechanical performance will also be reported. Cu-based systems have been identified as cryogenic SMA presenting the lowest phase transformation temperatures. The lowest measured M<sub>s</sub> (45 K) was found for the Cu-8.8Al-13.1Mn (wt.%) alloy.https://www.mdpi.com/2075-4701/13/7/1311shape memory alloyscryogenic environmentphase transformation temperaturemartensitic transition
spellingShingle Adelaide Nespoli
Davide Ninarello
Carlo Fanciulli
A Review on Shape Memory Alloys with Martensitic Transition at Cryogenic Temperatures
Metals
shape memory alloys
cryogenic environment
phase transformation temperature
martensitic transition
title A Review on Shape Memory Alloys with Martensitic Transition at Cryogenic Temperatures
title_full A Review on Shape Memory Alloys with Martensitic Transition at Cryogenic Temperatures
title_fullStr A Review on Shape Memory Alloys with Martensitic Transition at Cryogenic Temperatures
title_full_unstemmed A Review on Shape Memory Alloys with Martensitic Transition at Cryogenic Temperatures
title_short A Review on Shape Memory Alloys with Martensitic Transition at Cryogenic Temperatures
title_sort review on shape memory alloys with martensitic transition at cryogenic temperatures
topic shape memory alloys
cryogenic environment
phase transformation temperature
martensitic transition
url https://www.mdpi.com/2075-4701/13/7/1311
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