Synthesis and Properties of a Bay-Annulated-Indigo Tetramer Based on Low-Cost Spiro[Fluorene-9,9′-Xanthene] Core
A three-dimensional bay-annulated-indigo (BAI) tetramer has been prepared by appending BAI units onto a low-cost spiro[fluorene-9,9′-xanthene] (SFX) core. The target compound 4BAI-SFX exhibits strong and broad absorption in the visible region covering the range of 450~700 nm. The electroch...
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| Format: | Article |
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MDPI AG
2019-10-01
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| Series: | Molecules |
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| Online Access: | https://www.mdpi.com/1420-3049/24/19/3623 |
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| author | Bao-Yi Ren Yan-Mei Tan Chang-Liang Sun Yong-Gang Sheng |
| author_facet | Bao-Yi Ren Yan-Mei Tan Chang-Liang Sun Yong-Gang Sheng |
| author_sort | Bao-Yi Ren |
| collection | DOAJ |
| description | A three-dimensional bay-annulated-indigo (BAI) tetramer has been prepared by appending BAI units onto a low-cost spiro[fluorene-9,9′-xanthene] (SFX) core. The target compound 4BAI-SFX exhibits strong and broad absorption in the visible region covering the range of 450~700 nm. The electrochemical measurement illuminates the characteristics of a deep lowest unoccupied molecular orbital (LUMO) level and multiple redox states of 4BAI-SFX. These results suggest that 4BAI-SFX should be a selectable electron-transporting material for eco-friendly organic semiconductors. |
| first_indexed | 2024-12-11T09:46:44Z |
| format | Article |
| id | doaj.art-353746fe7c5b4ee2991ee092b6d0b1a4 |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-12-11T09:46:44Z |
| publishDate | 2019-10-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-353746fe7c5b4ee2991ee092b6d0b1a42022-12-22T01:12:32ZengMDPI AGMolecules1420-30492019-10-012419362310.3390/molecules24193623molecules24193623Synthesis and Properties of a Bay-Annulated-Indigo Tetramer Based on Low-Cost Spiro[Fluorene-9,9′-Xanthene] CoreBao-Yi Ren0Yan-Mei Tan1Chang-Liang Sun2Yong-Gang Sheng3College of Applied Chemistry, Shenyang University of Chemical Technology, Shenyang 110142, ChinaCollege of Applied Chemistry, Shenyang University of Chemical Technology, Shenyang 110142, ChinaCollege of Applied Chemistry, Shenyang University of Chemical Technology, Shenyang 110142, ChinaCollege of Applied Chemistry, Shenyang University of Chemical Technology, Shenyang 110142, ChinaA three-dimensional bay-annulated-indigo (BAI) tetramer has been prepared by appending BAI units onto a low-cost spiro[fluorene-9,9′-xanthene] (SFX) core. The target compound 4BAI-SFX exhibits strong and broad absorption in the visible region covering the range of 450~700 nm. The electrochemical measurement illuminates the characteristics of a deep lowest unoccupied molecular orbital (LUMO) level and multiple redox states of 4BAI-SFX. These results suggest that 4BAI-SFX should be a selectable electron-transporting material for eco-friendly organic semiconductors.https://www.mdpi.com/1420-3049/24/19/3623bay-annulated indigospiro[fluorene-9,9′-xanthene]synthesisproperties |
| spellingShingle | Bao-Yi Ren Yan-Mei Tan Chang-Liang Sun Yong-Gang Sheng Synthesis and Properties of a Bay-Annulated-Indigo Tetramer Based on Low-Cost Spiro[Fluorene-9,9′-Xanthene] Core Molecules bay-annulated indigo spiro[fluorene-9,9′-xanthene] synthesis properties |
| title | Synthesis and Properties of a Bay-Annulated-Indigo Tetramer Based on Low-Cost Spiro[Fluorene-9,9′-Xanthene] Core |
| title_full | Synthesis and Properties of a Bay-Annulated-Indigo Tetramer Based on Low-Cost Spiro[Fluorene-9,9′-Xanthene] Core |
| title_fullStr | Synthesis and Properties of a Bay-Annulated-Indigo Tetramer Based on Low-Cost Spiro[Fluorene-9,9′-Xanthene] Core |
| title_full_unstemmed | Synthesis and Properties of a Bay-Annulated-Indigo Tetramer Based on Low-Cost Spiro[Fluorene-9,9′-Xanthene] Core |
| title_short | Synthesis and Properties of a Bay-Annulated-Indigo Tetramer Based on Low-Cost Spiro[Fluorene-9,9′-Xanthene] Core |
| title_sort | synthesis and properties of a bay annulated indigo tetramer based on low cost spiro fluorene 9 9 xanthene core |
| topic | bay-annulated indigo spiro[fluorene-9,9′-xanthene] synthesis properties |
| url | https://www.mdpi.com/1420-3049/24/19/3623 |
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