Investigation of the Impact of Biochar Application on Foaming Slags with Varied Compositions in Electric Arc Furnace-Based Steel Production

This paper investigates the influence of biochar, either as an individual component or in combination with high-temperature coke, on the slag foaming behavior. High-temperature coke serves as a reference. Three scenarios were considered to study the slag foaming behavior, each characterized by diffe...

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Main Authors: Lina Kieush, Johannes Schenk
Format: Article
Language:English
Published: MDPI AG 2023-08-01
Series:Energies
Subjects:
Online Access:https://www.mdpi.com/1996-1073/16/17/6325
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author Lina Kieush
Johannes Schenk
author_facet Lina Kieush
Johannes Schenk
author_sort Lina Kieush
collection DOAJ
description This paper investigates the influence of biochar, either as an individual component or in combination with high-temperature coke, on the slag foaming behavior. High-temperature coke serves as a reference. Three scenarios were considered to study the slag foaming behavior, each characterized by different slag chemical compositions. The results indicate that biochar can promote steady foaming for specific slags when the basicity (CaO/SiO<sub>2</sub>) falls within a range of 1.2 to 3.4. Experimental findings also reveal that stable foaming can be achieved when a mixture containing biochar and coke with a ratio of 1:1 is employed, with a minimum slag basicity of 1.0 and FeO content of 25 wt.%. The foaming range obtained using different FeO contents (15 wt.% to 40 wt.%) in the mixture surpasses the range observed with the individual application of coke or biochar. The X-ray diffraction (XRD) analysis showed that unrelated to the carbon source applied, the general pattern was that the phases larnite (Ca<sub>2</sub>SiO<sub>4</sub>) or dicalcium silicate were detected for slag foams with high basicity. Monticellite (CaMgSiO<sub>4</sub>) and magnesium iron oxide (Fe<sub>2</sub>MgO<sub>4</sub>) were predominant in slag foam samples, with the highest MgO content. The presence of monticellite and merwinite (Ca<sub>3</sub>MgSi<sub>2</sub>O<sub>8</sub>) occurred in samples with the lowest basicity. Eventually, the application of the mixture of coke and biochar showed the potential to obtain stable foaming across a wide range of slag compositions.
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spelling doaj.art-35504da0173f49d2bc80229fb5b9594f2023-11-19T08:06:21ZengMDPI AGEnergies1996-10732023-08-011617632510.3390/en16176325Investigation of the Impact of Biochar Application on Foaming Slags with Varied Compositions in Electric Arc Furnace-Based Steel ProductionLina Kieush0Johannes Schenk1Chair of Ferrous Metallurgy, Montanuniversitaet Leoben, 8700 Leoben, AustriaChair of Ferrous Metallurgy, Montanuniversitaet Leoben, 8700 Leoben, AustriaThis paper investigates the influence of biochar, either as an individual component or in combination with high-temperature coke, on the slag foaming behavior. High-temperature coke serves as a reference. Three scenarios were considered to study the slag foaming behavior, each characterized by different slag chemical compositions. The results indicate that biochar can promote steady foaming for specific slags when the basicity (CaO/SiO<sub>2</sub>) falls within a range of 1.2 to 3.4. Experimental findings also reveal that stable foaming can be achieved when a mixture containing biochar and coke with a ratio of 1:1 is employed, with a minimum slag basicity of 1.0 and FeO content of 25 wt.%. The foaming range obtained using different FeO contents (15 wt.% to 40 wt.%) in the mixture surpasses the range observed with the individual application of coke or biochar. The X-ray diffraction (XRD) analysis showed that unrelated to the carbon source applied, the general pattern was that the phases larnite (Ca<sub>2</sub>SiO<sub>4</sub>) or dicalcium silicate were detected for slag foams with high basicity. Monticellite (CaMgSiO<sub>4</sub>) and magnesium iron oxide (Fe<sub>2</sub>MgO<sub>4</sub>) were predominant in slag foam samples, with the highest MgO content. The presence of monticellite and merwinite (Ca<sub>3</sub>MgSi<sub>2</sub>O<sub>8</sub>) occurred in samples with the lowest basicity. Eventually, the application of the mixture of coke and biochar showed the potential to obtain stable foaming across a wide range of slag compositions.https://www.mdpi.com/1996-1073/16/17/6325biocharcokeslag foamingelectric arc furnaceX-ray diffraction analysis
spellingShingle Lina Kieush
Johannes Schenk
Investigation of the Impact of Biochar Application on Foaming Slags with Varied Compositions in Electric Arc Furnace-Based Steel Production
Energies
biochar
coke
slag foaming
electric arc furnace
X-ray diffraction analysis
title Investigation of the Impact of Biochar Application on Foaming Slags with Varied Compositions in Electric Arc Furnace-Based Steel Production
title_full Investigation of the Impact of Biochar Application on Foaming Slags with Varied Compositions in Electric Arc Furnace-Based Steel Production
title_fullStr Investigation of the Impact of Biochar Application on Foaming Slags with Varied Compositions in Electric Arc Furnace-Based Steel Production
title_full_unstemmed Investigation of the Impact of Biochar Application on Foaming Slags with Varied Compositions in Electric Arc Furnace-Based Steel Production
title_short Investigation of the Impact of Biochar Application on Foaming Slags with Varied Compositions in Electric Arc Furnace-Based Steel Production
title_sort investigation of the impact of biochar application on foaming slags with varied compositions in electric arc furnace based steel production
topic biochar
coke
slag foaming
electric arc furnace
X-ray diffraction analysis
url https://www.mdpi.com/1996-1073/16/17/6325
work_keys_str_mv AT linakieush investigationoftheimpactofbiocharapplicationonfoamingslagswithvariedcompositionsinelectricarcfurnacebasedsteelproduction
AT johannesschenk investigationoftheimpactofbiocharapplicationonfoamingslagswithvariedcompositionsinelectricarcfurnacebasedsteelproduction