Synthesis and Crystal Structure of a Zn(II)-Based MOF Bearing Neutral N-Donor Linker and SiF62− Anion
A novel three-dimensional two-fold interpenetrated bi-porous metal-organic framework IPM-325 (IPM: IISER Pune Materials) having pcu topology was synthesized at room temperature. Single crystal X-ray diffraction (SC-XRD) study revealed that the compound crystallizes in monoclinic lattice with molecul...
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MDPI AG
2018-01-01
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| Series: | Crystals |
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| Online Access: | http://www.mdpi.com/2073-4352/8/1/37 |
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| author | Biplab Manna Shivani Sharma Sujit K. Ghosh |
| author_facet | Biplab Manna Shivani Sharma Sujit K. Ghosh |
| author_sort | Biplab Manna |
| collection | DOAJ |
| description | A novel three-dimensional two-fold interpenetrated bi-porous metal-organic framework IPM-325 (IPM: IISER Pune Materials) having pcu topology was synthesized at room temperature. Single crystal X-ray diffraction (SC-XRD) study revealed that the compound crystallizes in monoclinic lattice with molecular formula {[Zn(L)2 (SiF6)] (CH2Cl2) xG}n where G = Guests). All metal centers were found to have octahedral geometry. From single crystal analysis it can be inferred that SiF62− anion play a vital role in extending the dimensionality of the framework by bridging between two metal centers. Interestingly, IPM-325 exhibited two-step structural transformation maintaining the crystallinity of the framework as characterized by powder X-ray diffraction (PXRD). |
| first_indexed | 2024-04-11T13:21:10Z |
| format | Article |
| id | doaj.art-35568ce7836e4427a9890389cc3118b7 |
| institution | Directory Open Access Journal |
| issn | 2073-4352 |
| language | English |
| last_indexed | 2024-04-11T13:21:10Z |
| publishDate | 2018-01-01 |
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| series | Crystals |
| spelling | doaj.art-35568ce7836e4427a9890389cc3118b72022-12-22T04:22:12ZengMDPI AGCrystals2073-43522018-01-01813710.3390/cryst8010037cryst8010037Synthesis and Crystal Structure of a Zn(II)-Based MOF Bearing Neutral N-Donor Linker and SiF62− AnionBiplab Manna0Shivani Sharma1Sujit K. Ghosh2Department of Chemistry, Indian Institute of Science Education and Research (IISER Pune), Dr. Homi Bhabha Road, Pashan, Pune 411008, IndiaDepartment of Chemistry, Indian Institute of Science Education and Research (IISER Pune), Dr. Homi Bhabha Road, Pashan, Pune 411008, IndiaDepartment of Chemistry, Indian Institute of Science Education and Research (IISER Pune), Dr. Homi Bhabha Road, Pashan, Pune 411008, IndiaA novel three-dimensional two-fold interpenetrated bi-porous metal-organic framework IPM-325 (IPM: IISER Pune Materials) having pcu topology was synthesized at room temperature. Single crystal X-ray diffraction (SC-XRD) study revealed that the compound crystallizes in monoclinic lattice with molecular formula {[Zn(L)2 (SiF6)] (CH2Cl2) xG}n where G = Guests). All metal centers were found to have octahedral geometry. From single crystal analysis it can be inferred that SiF62− anion play a vital role in extending the dimensionality of the framework by bridging between two metal centers. Interestingly, IPM-325 exhibited two-step structural transformation maintaining the crystallinity of the framework as characterized by powder X-ray diffraction (PXRD).http://www.mdpi.com/2073-4352/8/1/37metal-organic frameworkneutral N-donor frameworkstructural transformations |
| spellingShingle | Biplab Manna Shivani Sharma Sujit K. Ghosh Synthesis and Crystal Structure of a Zn(II)-Based MOF Bearing Neutral N-Donor Linker and SiF62− Anion Crystals metal-organic framework neutral N-donor framework structural transformations |
| title | Synthesis and Crystal Structure of a Zn(II)-Based MOF Bearing Neutral N-Donor Linker and SiF62− Anion |
| title_full | Synthesis and Crystal Structure of a Zn(II)-Based MOF Bearing Neutral N-Donor Linker and SiF62− Anion |
| title_fullStr | Synthesis and Crystal Structure of a Zn(II)-Based MOF Bearing Neutral N-Donor Linker and SiF62− Anion |
| title_full_unstemmed | Synthesis and Crystal Structure of a Zn(II)-Based MOF Bearing Neutral N-Donor Linker and SiF62− Anion |
| title_short | Synthesis and Crystal Structure of a Zn(II)-Based MOF Bearing Neutral N-Donor Linker and SiF62− Anion |
| title_sort | synthesis and crystal structure of a zn ii based mof bearing neutral n donor linker and sif62 anion |
| topic | metal-organic framework neutral N-donor framework structural transformations |
| url | http://www.mdpi.com/2073-4352/8/1/37 |
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