Accounting for surface waves improves gas flux estimation at high wind speed in a large lake

<p>The gas transfer velocity (<span class="inline-formula"><i>k</i></span>) is a major source of uncertainty when assessing the magnitude of lake gas exchange with the atmosphere. For the diversity of existing empirical and process-based <span class="i...

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Bibliographic Details
Main Authors: P. Perolo, B. Fernández Castro, N. Escoffier, T. Lambert, D. Bouffard, M.-E. Perga
Format: Article
Language:English
Published: Copernicus Publications 2021-11-01
Series:Earth System Dynamics
Online Access:https://esd.copernicus.org/articles/12/1169/2021/esd-12-1169-2021.pdf
Description
Summary:<p>The gas transfer velocity (<span class="inline-formula"><i>k</i></span>) is a major source of uncertainty when assessing the magnitude of lake gas exchange with the atmosphere. For the diversity of existing empirical and process-based <span class="inline-formula"><i>k</i></span> models, the transfer velocity increases with the level of turbulence near the air–water interface. However, predictions for <span class="inline-formula"><i>k</i></span> can vary by a factor of 2 among different models. Near-surface turbulence results from the action of wind shear, surface waves, and buoyancy-driven convection. Wind shear has long been identified as a key driver, but recent lake studies have shifted the focus towards the role of convection, particularly in small lakes. In large lakes, wind fetch can, however, be long enough to generate surface waves and contribute to enhance gas transfer, as widely recognised in oceanographic studies. Here, field values for gas transfer velocity were computed in a large hard-water lake, Lake Geneva, from <span class="inline-formula">CO<sub>2</sub></span> fluxes measured with an automated (forced diffusion) flux chamber and <span class="inline-formula">CO<sub>2</sub></span> partial pressure measured with high-frequency sensors. <span class="inline-formula"><i>k</i></span> estimates were compared to a set of reference limnological and oceanic <span class="inline-formula"><i>k</i></span> models. Our analysis reveals that accounting for surface waves generated during windy events significantly improves the accuracy of <span class="inline-formula"><i>k</i></span> estimates in this large lake. The improved <span class="inline-formula"><i>k</i></span> model is then used to compute <span class="inline-formula"><i>k</i></span> over a 1-year time period. Results show that episodic extreme events with surface waves (6 % occurrence, significant wave height <span class="inline-formula">&gt;</span> 0.4 <span class="inline-formula">m</span>) can generate more than 20 % of annual cumulative <span class="inline-formula"><i>k</i></span> and more than 25 % of annual net <span class="inline-formula">CO<sub>2</sub></span> fluxes in Lake Geneva. We conclude that for lakes whose fetch can exceed 15 <span class="inline-formula">km</span>, <span class="inline-formula"><i>k</i></span> models need to integrate the effect of surface waves.</p>
ISSN:2190-4979
2190-4987