The Phase Relations of the Co-Ni-In Ternary System at 673 K and 873 K and Magnetic Properties of Their Compounds
The phase relationships of the ternary Co-Ni-In system at 673 K and 873 K were investigated by means of powder X-ray diffraction, scanning electron microscopy equipped with energy dispersive spectroscopy, and optical microscopy. Though CoIn<sub>2</sub> does not exist at 873 K, the ternar...
| Main Authors: | , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2020-09-01
|
| Series: | Materials |
| Subjects: | |
| Online Access: | https://www.mdpi.com/1996-1944/13/18/3990 |
| _version_ | 1797554192519266304 |
|---|---|
| author | Tonghan Yang Wei He Guojian Chen Weijing Zeng Jinzhi Wang Lingmin Zeng Jianlie Liang |
| author_facet | Tonghan Yang Wei He Guojian Chen Weijing Zeng Jinzhi Wang Lingmin Zeng Jianlie Liang |
| author_sort | Tonghan Yang |
| collection | DOAJ |
| description | The phase relationships of the ternary Co-Ni-In system at 673 K and 873 K were investigated by means of powder X-ray diffraction, scanning electron microscopy equipped with energy dispersive spectroscopy, and optical microscopy. Though CoIn<sub>2</sub> does not exist at 873 K, the ternary solid solution Co<sub>1−x</sub>Ni<sub>x</sub>In<sub>2</sub> exists at both 673 K and 873 K with different composition ranges. The Rietveld refinements were carried out to investigate the crystal structure of Co<sub>1−x</sub>Ni<sub>x</sub>In<sub>2</sub> (x = 0.540, and 0.580) and Ni<sub>2−x</sub>Co<sub>x</sub>In<sub>3</sub> (x = 0.200). The magnetization dependence of temperature (MT) curves of Ni<sub>2−x</sub>Co<sub>x</sub>In<sub>3</sub> (x = 0.200) and Co<sub>1−x</sub>Ni<sub>x</sub>In<sub>2</sub> (x = 0.540) are similar to those of the ferromagnetic shape memory alloys Ni-Mn-A (A = Ga, Sn, and In), but do not undergo martensitic transformation. The maximum magnetic entropy changes in Ni<sub>2−x</sub>Co<sub>x</sub>In<sub>3</sub> (x = 0.200) and Co<sub>1−x</sub>Ni<sub>x</sub>In<sub>2</sub> (x = 0.540) under 3T are 1.25 and 1.475 J kg<sup>−1</sup>K<sup>−1</sup>, respectively. |
| first_indexed | 2024-03-10T16:27:13Z |
| format | Article |
| id | doaj.art-357b1be32d8247378303e5ae0778c8c3 |
| institution | Directory Open Access Journal |
| issn | 1996-1944 |
| language | English |
| last_indexed | 2024-03-10T16:27:13Z |
| publishDate | 2020-09-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Materials |
| spelling | doaj.art-357b1be32d8247378303e5ae0778c8c32023-11-20T13:04:53ZengMDPI AGMaterials1996-19442020-09-011318399010.3390/ma13183990The Phase Relations of the Co-Ni-In Ternary System at 673 K and 873 K and Magnetic Properties of Their CompoundsTonghan Yang0Wei He1Guojian Chen2Weijing Zeng3Jinzhi Wang4Lingmin Zeng5Jianlie Liang6College of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, ChinaCollege of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, ChinaSchool of Resources, Environment and Materials and Guangxi Key Laboratory of Processing for Non-ferrous Metallic and Featured Materials, Guangxi University, Nanning 530004, ChinaSchool of Resources, Environment and Materials and Guangxi Key Laboratory of Processing for Non-ferrous Metallic and Featured Materials, Guangxi University, Nanning 530004, ChinaSchool of Materials and Chemical Engineering, Ningbo University of Technology, Ningbo 315211, ChinaSchool of Resources, Environment and Materials and Guangxi Key Laboratory of Processing for Non-ferrous Metallic and Featured Materials, Guangxi University, Nanning 530004, ChinaSchool of Science, Guangxi University of Nationalities, Nanning 530006, ChinaThe phase relationships of the ternary Co-Ni-In system at 673 K and 873 K were investigated by means of powder X-ray diffraction, scanning electron microscopy equipped with energy dispersive spectroscopy, and optical microscopy. Though CoIn<sub>2</sub> does not exist at 873 K, the ternary solid solution Co<sub>1−x</sub>Ni<sub>x</sub>In<sub>2</sub> exists at both 673 K and 873 K with different composition ranges. The Rietveld refinements were carried out to investigate the crystal structure of Co<sub>1−x</sub>Ni<sub>x</sub>In<sub>2</sub> (x = 0.540, and 0.580) and Ni<sub>2−x</sub>Co<sub>x</sub>In<sub>3</sub> (x = 0.200). The magnetization dependence of temperature (MT) curves of Ni<sub>2−x</sub>Co<sub>x</sub>In<sub>3</sub> (x = 0.200) and Co<sub>1−x</sub>Ni<sub>x</sub>In<sub>2</sub> (x = 0.540) are similar to those of the ferromagnetic shape memory alloys Ni-Mn-A (A = Ga, Sn, and In), but do not undergo martensitic transformation. The maximum magnetic entropy changes in Ni<sub>2−x</sub>Co<sub>x</sub>In<sub>3</sub> (x = 0.200) and Co<sub>1−x</sub>Ni<sub>x</sub>In<sub>2</sub> (x = 0.540) under 3T are 1.25 and 1.475 J kg<sup>−1</sup>K<sup>−1</sup>, respectively.https://www.mdpi.com/1996-1944/13/18/3990Co-Ni-Inphase diagramX-ray diffractionmagnetic properties |
| spellingShingle | Tonghan Yang Wei He Guojian Chen Weijing Zeng Jinzhi Wang Lingmin Zeng Jianlie Liang The Phase Relations of the Co-Ni-In Ternary System at 673 K and 873 K and Magnetic Properties of Their Compounds Materials Co-Ni-In phase diagram X-ray diffraction magnetic properties |
| title | The Phase Relations of the Co-Ni-In Ternary System at 673 K and 873 K and Magnetic Properties of Their Compounds |
| title_full | The Phase Relations of the Co-Ni-In Ternary System at 673 K and 873 K and Magnetic Properties of Their Compounds |
| title_fullStr | The Phase Relations of the Co-Ni-In Ternary System at 673 K and 873 K and Magnetic Properties of Their Compounds |
| title_full_unstemmed | The Phase Relations of the Co-Ni-In Ternary System at 673 K and 873 K and Magnetic Properties of Their Compounds |
| title_short | The Phase Relations of the Co-Ni-In Ternary System at 673 K and 873 K and Magnetic Properties of Their Compounds |
| title_sort | phase relations of the co ni in ternary system at 673 k and 873 k and magnetic properties of their compounds |
| topic | Co-Ni-In phase diagram X-ray diffraction magnetic properties |
| url | https://www.mdpi.com/1996-1944/13/18/3990 |
| work_keys_str_mv | AT tonghanyang thephaserelationsoftheconiinternarysystemat673kand873kandmagneticpropertiesoftheircompounds AT weihe thephaserelationsoftheconiinternarysystemat673kand873kandmagneticpropertiesoftheircompounds AT guojianchen thephaserelationsoftheconiinternarysystemat673kand873kandmagneticpropertiesoftheircompounds AT weijingzeng thephaserelationsoftheconiinternarysystemat673kand873kandmagneticpropertiesoftheircompounds AT jinzhiwang thephaserelationsoftheconiinternarysystemat673kand873kandmagneticpropertiesoftheircompounds AT lingminzeng thephaserelationsoftheconiinternarysystemat673kand873kandmagneticpropertiesoftheircompounds AT jianlieliang thephaserelationsoftheconiinternarysystemat673kand873kandmagneticpropertiesoftheircompounds AT tonghanyang phaserelationsoftheconiinternarysystemat673kand873kandmagneticpropertiesoftheircompounds AT weihe phaserelationsoftheconiinternarysystemat673kand873kandmagneticpropertiesoftheircompounds AT guojianchen phaserelationsoftheconiinternarysystemat673kand873kandmagneticpropertiesoftheircompounds AT weijingzeng phaserelationsoftheconiinternarysystemat673kand873kandmagneticpropertiesoftheircompounds AT jinzhiwang phaserelationsoftheconiinternarysystemat673kand873kandmagneticpropertiesoftheircompounds AT lingminzeng phaserelationsoftheconiinternarysystemat673kand873kandmagneticpropertiesoftheircompounds AT jianlieliang phaserelationsoftheconiinternarysystemat673kand873kandmagneticpropertiesoftheircompounds |