Effect of recycled ceramic waste particles on kinetic of curing and thermal degradation of unsaturated polyester resin

In this study, the effect of recycled ceramic waste particles on the curing reaction and thermal degradation of unsaturated polyester resin has been studied kinetically. Methyl ethyl ketone peroxide and cobalt octoate were used as initiator and promotor, respectively. The porcelain powder obtained f...

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Main Authors: Mohamed Farsane, Abdellah Anouar, Souad Chah, Miloudi Bouzziri
Format: Article
Language:English
Published: Faculté Polydisciplinaire de Khouribga 2020-12-01
Series:Journal of Applied Surfaces and Interfaces
Subjects:
Online Access:https://revues.imist.ma/index.php/jasi/article/view/20296/13042
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author Mohamed Farsane
Abdellah Anouar
Souad Chah
Miloudi Bouzziri
author_facet Mohamed Farsane
Abdellah Anouar
Souad Chah
Miloudi Bouzziri
author_sort Mohamed Farsane
collection DOAJ
description In this study, the effect of recycled ceramic waste particles on the curing reaction and thermal degradation of unsaturated polyester resin has been studied kinetically. Methyl ethyl ketone peroxide and cobalt octoate were used as initiator and promotor, respectively. The porcelain powder obtained from ceramic waste was used as filler. The effect of methyl ethyl ketone peroxide and porcelain powder were investigated by measuring the gel time and exotherm behavior. Also, thermal properties have been carried out using TGA at different heating rates in an argon atmosphere, and the results were analyzed by the Friedman method. The results indicate that the curing process is affected by the incorporation of ceramic particles in two ways. Therefore, the use of ceramic particles increases the induction time and decreases the exotherm properties of unsaturated polyester resin. In addition, the results obtained by Friedman method demonstrates that the incorporation of ceramic particles in the resin increases the activation energy, and consequently improves the thermal stability of unsaturated polyester resin.
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spelling doaj.art-3590bd6d9dc94a7987e44ce751f5df392022-12-21T17:43:47ZengFaculté Polydisciplinaire de KhouribgaJournal of Applied Surfaces and Interfaces2550-48002550-48002020-12-0181-31521https://doi.org/10.48442/IMIST.PRSM/jasi-v8i1-3.20296Effect of recycled ceramic waste particles on kinetic of curing and thermal degradation of unsaturated polyester resinMohamed Farsane 0Abdellah Anouar 1Souad Chah 2Miloudi Bouzziri 3Laboratory of Physico-Chemistry of Processes and Materials (PCPM). Faculty of Science and Technology of Settat, University Hassan 1, BP 577, Settat 26000, MoroccoLaboratory of Applied Chemistry and Environment, Faculty of Science and Technology of Settat, University Hassan 1, BP 577, Settat 26000, Morocco.Laboratory of Physico-Chemistry of Processes and Materials (PCPM). Faculty of Science and Technology of Settat, University Hassan 1, BP 577, Settat 26000, MoroccoLaboratory of Physico-Chemistry of Processes and Materials (PCPM). Faculty of Science and Technology of Settat, University Hassan 1, BP 577, Settat 26000, MoroccoIn this study, the effect of recycled ceramic waste particles on the curing reaction and thermal degradation of unsaturated polyester resin has been studied kinetically. Methyl ethyl ketone peroxide and cobalt octoate were used as initiator and promotor, respectively. The porcelain powder obtained from ceramic waste was used as filler. The effect of methyl ethyl ketone peroxide and porcelain powder were investigated by measuring the gel time and exotherm behavior. Also, thermal properties have been carried out using TGA at different heating rates in an argon atmosphere, and the results were analyzed by the Friedman method. The results indicate that the curing process is affected by the incorporation of ceramic particles in two ways. Therefore, the use of ceramic particles increases the induction time and decreases the exotherm properties of unsaturated polyester resin. In addition, the results obtained by Friedman method demonstrates that the incorporation of ceramic particles in the resin increases the activation energy, and consequently improves the thermal stability of unsaturated polyester resin.https://revues.imist.ma/index.php/jasi/article/view/20296/13042unsaturated polyester resinceramic particlesgel timecuring exothermfriedman methodactivation energy
spellingShingle Mohamed Farsane
Abdellah Anouar
Souad Chah
Miloudi Bouzziri
Effect of recycled ceramic waste particles on kinetic of curing and thermal degradation of unsaturated polyester resin
Journal of Applied Surfaces and Interfaces
unsaturated polyester resin
ceramic particles
gel time
curing exotherm
friedman method
activation energy
title Effect of recycled ceramic waste particles on kinetic of curing and thermal degradation of unsaturated polyester resin
title_full Effect of recycled ceramic waste particles on kinetic of curing and thermal degradation of unsaturated polyester resin
title_fullStr Effect of recycled ceramic waste particles on kinetic of curing and thermal degradation of unsaturated polyester resin
title_full_unstemmed Effect of recycled ceramic waste particles on kinetic of curing and thermal degradation of unsaturated polyester resin
title_short Effect of recycled ceramic waste particles on kinetic of curing and thermal degradation of unsaturated polyester resin
title_sort effect of recycled ceramic waste particles on kinetic of curing and thermal degradation of unsaturated polyester resin
topic unsaturated polyester resin
ceramic particles
gel time
curing exotherm
friedman method
activation energy
url https://revues.imist.ma/index.php/jasi/article/view/20296/13042
work_keys_str_mv AT mohamedfarsane effectofrecycledceramicwasteparticlesonkineticofcuringandthermaldegradationofunsaturatedpolyesterresin
AT abdellahanouar effectofrecycledceramicwasteparticlesonkineticofcuringandthermaldegradationofunsaturatedpolyesterresin
AT souadchah effectofrecycledceramicwasteparticlesonkineticofcuringandthermaldegradationofunsaturatedpolyesterresin
AT miloudibouzziri effectofrecycledceramicwasteparticlesonkineticofcuringandthermaldegradationofunsaturatedpolyesterresin