Carbon Nanotubes Enabled Laser 3D Printing of High-Performance Titanium with Highly Concentrated Reinforcement

Summary: Zero- to two-dimensional nanomaterials have been incorporated into metal-matrices to improve the strength of metals, but challengingly, high-volume-fraction nanomaterials are difficult to disperse uniformly in metal matrices, severely degrading the ductility of conventionally processed meta...

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Main Authors: Dongdong Gu, Hongyu Chen, Donghua Dai, Chenglong Ma, Han Zhang, Kaijie Lin, Lixia Xi, Tong Zhao, Chen Hong, Andres Gasser, Reinhart Poprawe
Format: Article
Language:English
Published: Elsevier 2020-09-01
Series:iScience
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2589004220306908
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author Dongdong Gu
Hongyu Chen
Donghua Dai
Chenglong Ma
Han Zhang
Kaijie Lin
Lixia Xi
Tong Zhao
Chen Hong
Andres Gasser
Reinhart Poprawe
author_facet Dongdong Gu
Hongyu Chen
Donghua Dai
Chenglong Ma
Han Zhang
Kaijie Lin
Lixia Xi
Tong Zhao
Chen Hong
Andres Gasser
Reinhart Poprawe
author_sort Dongdong Gu
collection DOAJ
description Summary: Zero- to two-dimensional nanomaterials have been incorporated into metal-matrices to improve the strength of metals, but challengingly, high-volume-fraction nanomaterials are difficult to disperse uniformly in metal matrices, severely degrading the ductility of conventionally processed metals. Here, a considerably dense uniform dispersion of in situ formed nanoscale lamellar TiC reinforcement (16.1 wt %) in Ti matrix is achieved through laser-tailored 3D printing and complete reaction of Ti powder with a small amount (1.0 wt %) of carbon nanotubes (CNTs). An enhanced tensile strength of 912 MPa and an outstanding fracture elongation of 16% are simultaneously achieved for laser-printed components, showing a maximum 350% improvement in “product of strength and elongation” compared with conventional Ti. In situ nanoscale TiC reinforcement favors the formation of ultrafine equiaxed Ti grains and metallurgically coherent interface with minimal lattice misfit between TiC lamellae and Ti matrix. Our approach hopefully provides a feasible way to broaden structural applications of CNTs in load-bearing Ti-based engineering components via laser-tailored reorganization with Ti.
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spelling doaj.art-3591afe27f4547ec96dc54e786aca6f32022-12-21T23:20:25ZengElsevieriScience2589-00422020-09-01239101498Carbon Nanotubes Enabled Laser 3D Printing of High-Performance Titanium with Highly Concentrated ReinforcementDongdong Gu0Hongyu Chen1Donghua Dai2Chenglong Ma3Han Zhang4Kaijie Lin5Lixia Xi6Tong Zhao7Chen Hong8Andres Gasser9Reinhart Poprawe10College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Yudao Street 29, Nanjing 210016, PR China; Jiangsu Provincial Engineering Laboratory for Laser Additive Manufacturing of High-Performance Metallic Components, Nanjing University of Aeronautics and Astronautics, Yudao Street 29, Nanjing 210016, PR China; Corresponding authorCollege of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Yudao Street 29, Nanjing 210016, PR China; Jiangsu Provincial Engineering Laboratory for Laser Additive Manufacturing of High-Performance Metallic Components, Nanjing University of Aeronautics and Astronautics, Yudao Street 29, Nanjing 210016, PR ChinaCollege of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Yudao Street 29, Nanjing 210016, PR China; Jiangsu Provincial Engineering Laboratory for Laser Additive Manufacturing of High-Performance Metallic Components, Nanjing University of Aeronautics and Astronautics, Yudao Street 29, Nanjing 210016, PR ChinaCollege of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Yudao Street 29, Nanjing 210016, PR China; Jiangsu Provincial Engineering Laboratory for Laser Additive Manufacturing of High-Performance Metallic Components, Nanjing University of Aeronautics and Astronautics, Yudao Street 29, Nanjing 210016, PR ChinaCollege of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Yudao Street 29, Nanjing 210016, PR China; Jiangsu Provincial Engineering Laboratory for Laser Additive Manufacturing of High-Performance Metallic Components, Nanjing University of Aeronautics and Astronautics, Yudao Street 29, Nanjing 210016, PR ChinaCollege of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Yudao Street 29, Nanjing 210016, PR China; Jiangsu Provincial Engineering Laboratory for Laser Additive Manufacturing of High-Performance Metallic Components, Nanjing University of Aeronautics and Astronautics, Yudao Street 29, Nanjing 210016, PR ChinaCollege of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Yudao Street 29, Nanjing 210016, PR China; Jiangsu Provincial Engineering Laboratory for Laser Additive Manufacturing of High-Performance Metallic Components, Nanjing University of Aeronautics and Astronautics, Yudao Street 29, Nanjing 210016, PR ChinaFraunhofer Institute for Laser Technology ILT, Steinbachstraße 15, Aachen 52074, Germany; Chair for Laser Technology LLT, RWTH Aachen University, Steinbachstraße 15, Aachen 52074, GermanyFraunhofer Institute for Laser Technology ILT, Steinbachstraße 15, Aachen 52074, Germany; Chair for Laser Technology LLT, RWTH Aachen University, Steinbachstraße 15, Aachen 52074, GermanyFraunhofer Institute for Laser Technology ILT, Steinbachstraße 15, Aachen 52074, Germany; Chair for Laser Technology LLT, RWTH Aachen University, Steinbachstraße 15, Aachen 52074, GermanyFraunhofer Institute for Laser Technology ILT, Steinbachstraße 15, Aachen 52074, Germany; Chair for Laser Technology LLT, RWTH Aachen University, Steinbachstraße 15, Aachen 52074, GermanySummary: Zero- to two-dimensional nanomaterials have been incorporated into metal-matrices to improve the strength of metals, but challengingly, high-volume-fraction nanomaterials are difficult to disperse uniformly in metal matrices, severely degrading the ductility of conventionally processed metals. Here, a considerably dense uniform dispersion of in situ formed nanoscale lamellar TiC reinforcement (16.1 wt %) in Ti matrix is achieved through laser-tailored 3D printing and complete reaction of Ti powder with a small amount (1.0 wt %) of carbon nanotubes (CNTs). An enhanced tensile strength of 912 MPa and an outstanding fracture elongation of 16% are simultaneously achieved for laser-printed components, showing a maximum 350% improvement in “product of strength and elongation” compared with conventional Ti. In situ nanoscale TiC reinforcement favors the formation of ultrafine equiaxed Ti grains and metallurgically coherent interface with minimal lattice misfit between TiC lamellae and Ti matrix. Our approach hopefully provides a feasible way to broaden structural applications of CNTs in load-bearing Ti-based engineering components via laser-tailored reorganization with Ti.http://www.sciencedirect.com/science/article/pii/S2589004220306908Materials ProcessingMechanical PropertyNanomaterials
spellingShingle Dongdong Gu
Hongyu Chen
Donghua Dai
Chenglong Ma
Han Zhang
Kaijie Lin
Lixia Xi
Tong Zhao
Chen Hong
Andres Gasser
Reinhart Poprawe
Carbon Nanotubes Enabled Laser 3D Printing of High-Performance Titanium with Highly Concentrated Reinforcement
iScience
Materials Processing
Mechanical Property
Nanomaterials
title Carbon Nanotubes Enabled Laser 3D Printing of High-Performance Titanium with Highly Concentrated Reinforcement
title_full Carbon Nanotubes Enabled Laser 3D Printing of High-Performance Titanium with Highly Concentrated Reinforcement
title_fullStr Carbon Nanotubes Enabled Laser 3D Printing of High-Performance Titanium with Highly Concentrated Reinforcement
title_full_unstemmed Carbon Nanotubes Enabled Laser 3D Printing of High-Performance Titanium with Highly Concentrated Reinforcement
title_short Carbon Nanotubes Enabled Laser 3D Printing of High-Performance Titanium with Highly Concentrated Reinforcement
title_sort carbon nanotubes enabled laser 3d printing of high performance titanium with highly concentrated reinforcement
topic Materials Processing
Mechanical Property
Nanomaterials
url http://www.sciencedirect.com/science/article/pii/S2589004220306908
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