2,3-Diruthenocenylcyclopropenone
In the title compound, [Ru2(C5H5)2(C13H8O)], the Ru—C bond lengths in the two ruthenocenyl moieties are in the range of 2.155 (4)–2.196 (3) Å. Both cyclopentadienyl (Cp) rings are planar and parallel with staggered (18.6 °) and eclipsed (3.1°) conformations between the mutual orientations of rings i...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2017-09-01
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| Series: | IUCrData |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S241431461701358X |
| _version_ | 1818540834833825792 |
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| author | Jessica J. Sánchez García Marcos Flores-Alamo Elena I. Klimova |
| author_facet | Jessica J. Sánchez García Marcos Flores-Alamo Elena I. Klimova |
| author_sort | Jessica J. Sánchez García |
| collection | DOAJ |
| description | In the title compound, [Ru2(C5H5)2(C13H8O)], the Ru—C bond lengths in the two ruthenocenyl moieties are in the range of 2.155 (4)–2.196 (3) Å. Both cyclopentadienyl (Cp) rings are planar and parallel with staggered (18.6 °) and eclipsed (3.1°) conformations between the mutual orientations of rings in the independent sandwiches of each ruthenocenyl molecule. In the crystal, there are intermolecular C—H...O hydrogen bonds between Cp carbon donor atoms and the cyclopropenone O atom of adjacent molecules, forming R22(14) and R66(38) motifs along the b and c axes. |
| first_indexed | 2024-12-11T22:00:35Z |
| format | Article |
| id | doaj.art-35976d6f00434fd89223d1783e1a4de7 |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-12-11T22:00:35Z |
| publishDate | 2017-09-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-35976d6f00434fd89223d1783e1a4de72022-12-22T00:49:07ZengInternational Union of CrystallographyIUCrData2414-31462017-09-0129x17135810.1107/S241431461701358Xbv40112,3-DiruthenocenylcyclopropenoneJessica J. Sánchez García0Marcos Flores-Alamo1Elena I. Klimova2Facultad de Química, Universidad Nacional Autónoma de México, Ciudad Universitaria, Ciudad de México, 04510, MexicoFacultad de Química, Universidad Nacional Autónoma de México, Ciudad Universitaria, Ciudad de México, 04510, MexicoFacultad de Química, Universidad Nacional Autónoma de México, Ciudad Universitaria, Ciudad de México, 04510, MexicoIn the title compound, [Ru2(C5H5)2(C13H8O)], the Ru—C bond lengths in the two ruthenocenyl moieties are in the range of 2.155 (4)–2.196 (3) Å. Both cyclopentadienyl (Cp) rings are planar and parallel with staggered (18.6 °) and eclipsed (3.1°) conformations between the mutual orientations of rings in the independent sandwiches of each ruthenocenyl molecule. In the crystal, there are intermolecular C—H...O hydrogen bonds between Cp carbon donor atoms and the cyclopropenone O atom of adjacent molecules, forming R22(14) and R66(38) motifs along the b and c axes.http://scripts.iucr.org/cgi-bin/paper?S241431461701358Xcrystal structurediruthenocenylcyclopropenone |
| spellingShingle | Jessica J. Sánchez García Marcos Flores-Alamo Elena I. Klimova 2,3-Diruthenocenylcyclopropenone IUCrData crystal structure diruthenocenylcyclopropenone |
| title | 2,3-Diruthenocenylcyclopropenone |
| title_full | 2,3-Diruthenocenylcyclopropenone |
| title_fullStr | 2,3-Diruthenocenylcyclopropenone |
| title_full_unstemmed | 2,3-Diruthenocenylcyclopropenone |
| title_short | 2,3-Diruthenocenylcyclopropenone |
| title_sort | 2 3 diruthenocenylcyclopropenone |
| topic | crystal structure diruthenocenylcyclopropenone |
| url | http://scripts.iucr.org/cgi-bin/paper?S241431461701358X |
| work_keys_str_mv | AT jessicajsanchezgarcia 23diruthenocenylcyclopropenone AT marcosfloresalamo 23diruthenocenylcyclopropenone AT elenaiklimova 23diruthenocenylcyclopropenone |