(Dimethylphosphoryl)methanaminium iodide–(dimethylphosphoryl)methanamine (1/1)
The asymmetric unit of the title structure, C3H11NOP+·I−·C3H10NOP, consists of one (dimethylphosphoryl)methanamine (dpma) molecule, one (dimethylphosphoryl)methanaminium (dpmaH) ion and one iodide counter-anion. In the crystal, medium–strong to weak N—...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2013-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813019004 |
| Summary: | The asymmetric unit of the title structure, C3H11NOP+·I−·C3H10NOP, consists of one (dimethylphosphoryl)methanamine (dpma) molecule, one (dimethylphosphoryl)methanaminium (dpmaH) ion and one iodide counter-anion. In the crystal, medium–strong to weak N—H...O and N—H...N hydrogen bonds connect dpmaH cations and dpma molecules into strands along [001]. The iodide counter-anions form only very weak hydrogen bonds. The crystal used for the diffraction study was found to be an inversion twin with a ratio of 0.83 (2):0.17 (2). The title structure is isotypic to that of dpmaH[ClO4]·dpma [Buhl et al. (2013). Crystals 3, 350–362]. |
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| ISSN: | 1600-5368 |