(Dimethylphosphoryl)methanaminium iodide–(dimethylphosphoryl)methanamine (1/1)
The asymmetric unit of the title structure, C3H11NOP+·I−·C3H10NOP, consists of one (dimethylphosphoryl)methanamine (dpma) molecule, one (dimethylphosphoryl)methanaminium (dpmaH) ion and one iodide counter-anion. In the crystal, medium–strong to weak N—...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2013-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813019004 |
| _version_ | 1818960599657218048 |
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| author | Guido J. Reiss |
| author_facet | Guido J. Reiss |
| author_sort | Guido J. Reiss |
| collection | DOAJ |
| description | The asymmetric unit of the title structure, C3H11NOP+·I−·C3H10NOP, consists of one (dimethylphosphoryl)methanamine (dpma) molecule, one (dimethylphosphoryl)methanaminium (dpmaH) ion and one iodide counter-anion. In the crystal, medium–strong to weak N—H...O and N—H...N hydrogen bonds connect dpmaH cations and dpma molecules into strands along [001]. The iodide counter-anions form only very weak hydrogen bonds. The crystal used for the diffraction study was found to be an inversion twin with a ratio of 0.83 (2):0.17 (2). The title structure is isotypic to that of dpmaH[ClO4]·dpma [Buhl et al. (2013). Crystals 3, 350–362]. |
| first_indexed | 2024-12-20T12:00:06Z |
| format | Article |
| id | doaj.art-35d33c27214f4f57b351986042ba1eec |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T12:00:06Z |
| publishDate | 2013-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-35d33c27214f4f57b351986042ba1eec2022-12-21T19:41:34ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-08-01698o1253o125410.1107/S1600536813019004(Dimethylphosphoryl)methanaminium iodide–(dimethylphosphoryl)methanamine (1/1)Guido J. ReissThe asymmetric unit of the title structure, C3H11NOP+·I−·C3H10NOP, consists of one (dimethylphosphoryl)methanamine (dpma) molecule, one (dimethylphosphoryl)methanaminium (dpmaH) ion and one iodide counter-anion. In the crystal, medium–strong to weak N—H...O and N—H...N hydrogen bonds connect dpmaH cations and dpma molecules into strands along [001]. The iodide counter-anions form only very weak hydrogen bonds. The crystal used for the diffraction study was found to be an inversion twin with a ratio of 0.83 (2):0.17 (2). The title structure is isotypic to that of dpmaH[ClO4]·dpma [Buhl et al. (2013). Crystals 3, 350–362].http://scripts.iucr.org/cgi-bin/paper?S1600536813019004 |
| spellingShingle | Guido J. Reiss (Dimethylphosphoryl)methanaminium iodide–(dimethylphosphoryl)methanamine (1/1) Acta Crystallographica Section E |
| title | (Dimethylphosphoryl)methanaminium iodide–(dimethylphosphoryl)methanamine (1/1) |
| title_full | (Dimethylphosphoryl)methanaminium iodide–(dimethylphosphoryl)methanamine (1/1) |
| title_fullStr | (Dimethylphosphoryl)methanaminium iodide–(dimethylphosphoryl)methanamine (1/1) |
| title_full_unstemmed | (Dimethylphosphoryl)methanaminium iodide–(dimethylphosphoryl)methanamine (1/1) |
| title_short | (Dimethylphosphoryl)methanaminium iodide–(dimethylphosphoryl)methanamine (1/1) |
| title_sort | dimethylphosphoryl methanaminium iodide 8211 dimethylphosphoryl methanamine 1 1 |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536813019004 |
| work_keys_str_mv | AT guidojreiss dimethylphosphorylmethanaminiumiodide8211dimethylphosphorylmethanamine11 |