Investigating the Effect of Modifier Chain Length on Insulation Properties of Polysulfide Modified Epoxy Resin

Polysulfide resins,with trade name of  G4 and G112, with short and long chain lengths respectively, were used as reactive modifiers to toughen epoxy resin. The effects of molecular weights of G4 and G112 on impact resistance, dielectric constant, thermal conductivity as well as decomposition  heat a...

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Main Authors: Tohid Farajpour, Yadollah Bayat, Mohammad Hossein Keshavarz, Ebrahim Zanjirian
Format: Article
Language:English
Published: Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR 2014-03-01
Series:Iranian Journal of Chemistry & Chemical Engineering
Subjects:
Online Access:http://www.ijcce.ac.ir/article_7192_cb56c490991dd750edea90d3cd2dceeb.pdf
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author Tohid Farajpour
Yadollah Bayat
Mohammad Hossein Keshavarz
Ebrahim Zanjirian
author_facet Tohid Farajpour
Yadollah Bayat
Mohammad Hossein Keshavarz
Ebrahim Zanjirian
author_sort Tohid Farajpour
collection DOAJ
description Polysulfide resins,with trade name of  G4 and G112, with short and long chain lengths respectively, were used as reactive modifiers to toughen epoxy resin. The effects of molecular weights of G4 and G112 on impact resistance, dielectric constant, thermal conductivity as well as decomposition  heat and adhesion properties of toughened epoxy were investigated. The impact strength and the dielectric constant of epoxy resin were enhanced by increasing of polysulfide so that the effect of the G112 is higher than the G4. For the same weight percent of G4 and G112, the G112 modified epoxy resin has lower Cure enthalpy than the G4 modified epoxy resin. Addition of modifier with long chain up to 10 weight percent was also leaded to higher bond strength with aluminum sheets. also, It is observed that the thermal conductivity of epoxy decreasing with incresing modifier chain length.
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spelling doaj.art-35f40cc74f0f4009951c6191813e2e882022-12-21T18:10:03ZengIranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECRIranian Journal of Chemistry & Chemical Engineering1021-99861021-99862014-03-0133137447192Investigating the Effect of Modifier Chain Length on Insulation Properties of Polysulfide Modified Epoxy ResinTohid Farajpour0Yadollah Bayat1Mohammad Hossein Keshavarz2Ebrahim Zanjirian3Department of Chemistry, Malek Ashtar University of Technology, Tehran, I.R. IRANDepartment of Chemistry, Malek Ashtar University of Technology, Tehran, I.R. IRANDepartment of Chemistry, Malek Ashtar University of Technology, Tehran, I.R. IRANSpace Transportation Research Institute, Iranian Space Research Center, Tehran, I.R. IRANPolysulfide resins,with trade name of  G4 and G112, with short and long chain lengths respectively, were used as reactive modifiers to toughen epoxy resin. The effects of molecular weights of G4 and G112 on impact resistance, dielectric constant, thermal conductivity as well as decomposition  heat and adhesion properties of toughened epoxy were investigated. The impact strength and the dielectric constant of epoxy resin were enhanced by increasing of polysulfide so that the effect of the G112 is higher than the G4. For the same weight percent of G4 and G112, the G112 modified epoxy resin has lower Cure enthalpy than the G4 modified epoxy resin. Addition of modifier with long chain up to 10 weight percent was also leaded to higher bond strength with aluminum sheets. also, It is observed that the thermal conductivity of epoxy decreasing with incresing modifier chain length.http://www.ijcce.ac.ir/article_7192_cb56c490991dd750edea90d3cd2dceeb.pdfepoxypolysulfideinsulation properties
spellingShingle Tohid Farajpour
Yadollah Bayat
Mohammad Hossein Keshavarz
Ebrahim Zanjirian
Investigating the Effect of Modifier Chain Length on Insulation Properties of Polysulfide Modified Epoxy Resin
Iranian Journal of Chemistry & Chemical Engineering
epoxy
polysulfide
insulation properties
title Investigating the Effect of Modifier Chain Length on Insulation Properties of Polysulfide Modified Epoxy Resin
title_full Investigating the Effect of Modifier Chain Length on Insulation Properties of Polysulfide Modified Epoxy Resin
title_fullStr Investigating the Effect of Modifier Chain Length on Insulation Properties of Polysulfide Modified Epoxy Resin
title_full_unstemmed Investigating the Effect of Modifier Chain Length on Insulation Properties of Polysulfide Modified Epoxy Resin
title_short Investigating the Effect of Modifier Chain Length on Insulation Properties of Polysulfide Modified Epoxy Resin
title_sort investigating the effect of modifier chain length on insulation properties of polysulfide modified epoxy resin
topic epoxy
polysulfide
insulation properties
url http://www.ijcce.ac.ir/article_7192_cb56c490991dd750edea90d3cd2dceeb.pdf
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AT mohammadhosseinkeshavarz investigatingtheeffectofmodifierchainlengthoninsulationpropertiesofpolysulfidemodifiedepoxyresin
AT ebrahimzanjirian investigatingtheeffectofmodifierchainlengthoninsulationpropertiesofpolysulfidemodifiedepoxyresin