Synthesis of Highly Functionalised Enantiopure Bicyclo[3.2.1]- octane Systems from Carvone
The commercially available monoterpene carvone has been efficiently convertedinto the tricyclo[3.2.1.02.7]octane and bicyclo[3.2.1]octane systems characteristic of somebiologically active compounds. The sequence used for this transformation involves as keyfeatures an intramolecular Diels-Alder react...
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| Format: | Article |
| Language: | English |
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MDPI AG
2004-04-01
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| Series: | Molecules |
| Subjects: | |
| Online Access: | http://www.mdpi.com/1420-3049/9/5/287/ |
| _version_ | 1818026559912542208 |
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| author | Noelia Vera Ismael Navarro Ignacio de Alfonso Ana C. Cuñat Consuelo Agulló Antonio Abad |
| author_facet | Noelia Vera Ismael Navarro Ignacio de Alfonso Ana C. Cuñat Consuelo Agulló Antonio Abad |
| author_sort | Noelia Vera |
| collection | DOAJ |
| description | The commercially available monoterpene carvone has been efficiently convertedinto the tricyclo[3.2.1.02.7]octane and bicyclo[3.2.1]octane systems characteristic of somebiologically active compounds. The sequence used for this transformation involves as keyfeatures an intramolecular Diels-Alder reaction of a 5-vinyl-1,3-cyclohexadiene and acyclopropane ring opening. |
| first_indexed | 2024-12-10T04:33:56Z |
| format | Article |
| id | doaj.art-360d1c95bd2543499ebee5fc57f40e3c |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-12-10T04:33:56Z |
| publishDate | 2004-04-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-360d1c95bd2543499ebee5fc57f40e3c2022-12-22T02:02:03ZengMDPI AGMolecules1420-30492004-04-019528729910.3390/90500287Synthesis of Highly Functionalised Enantiopure Bicyclo[3.2.1]- octane Systems from CarvoneNoelia VeraIsmael NavarroIgnacio de AlfonsoAna C. CuñatConsuelo AgullóAntonio AbadThe commercially available monoterpene carvone has been efficiently convertedinto the tricyclo[3.2.1.02.7]octane and bicyclo[3.2.1]octane systems characteristic of somebiologically active compounds. The sequence used for this transformation involves as keyfeatures an intramolecular Diels-Alder reaction of a 5-vinyl-1,3-cyclohexadiene and acyclopropane ring opening.http://www.mdpi.com/1420-3049/9/5/287/CarvoneDiels-Alder reactioncyclopropane cleavage5-vinyl-13- cyclohexadienesamarium diiodidebicyclo[3.2.1]octanetricyclo[3.2.1.02.7]octane |
| spellingShingle | Noelia Vera Ismael Navarro Ignacio de Alfonso Ana C. Cuñat Consuelo Agulló Antonio Abad Synthesis of Highly Functionalised Enantiopure Bicyclo[3.2.1]- octane Systems from Carvone Molecules Carvone Diels-Alder reaction cyclopropane cleavage 5-vinyl-1 3- cyclohexadiene samarium diiodide bicyclo[3.2.1]octane tricyclo[3.2.1.02.7]octane |
| title | Synthesis of Highly Functionalised Enantiopure Bicyclo[3.2.1]- octane Systems from Carvone |
| title_full | Synthesis of Highly Functionalised Enantiopure Bicyclo[3.2.1]- octane Systems from Carvone |
| title_fullStr | Synthesis of Highly Functionalised Enantiopure Bicyclo[3.2.1]- octane Systems from Carvone |
| title_full_unstemmed | Synthesis of Highly Functionalised Enantiopure Bicyclo[3.2.1]- octane Systems from Carvone |
| title_short | Synthesis of Highly Functionalised Enantiopure Bicyclo[3.2.1]- octane Systems from Carvone |
| title_sort | synthesis of highly functionalised enantiopure bicyclo 3 2 1 octane systems from carvone |
| topic | Carvone Diels-Alder reaction cyclopropane cleavage 5-vinyl-1 3- cyclohexadiene samarium diiodide bicyclo[3.2.1]octane tricyclo[3.2.1.02.7]octane |
| url | http://www.mdpi.com/1420-3049/9/5/287/ |
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