A green approach for the multicomponent synthesis of polyhydroquinolines and 6-unsubstituted dihydropyrimidinones using novel highly proficient acidic ionic liquid [CEMIM][MSA] as a reusable catalyst
Carboxylic acid functionalized imidazolium based novel acidic ionic liquid [CEMIM][MSA] was synthesized using economically feasible raw materials under very mild condition. The cost effective and sustainable synthesis of polyhydroquinoline and 6-unsustituted dihydropyrimidinone derivatives in green...
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Format: | Article |
Language: | English |
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Elsevier
2022-10-01
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Series: | Catalysis Communications |
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Online Access: | http://www.sciencedirect.com/science/article/pii/S1566736722001054 |
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author | Priyanka Patil Suresh Kadam Dayanand Patil Paresh More |
author_facet | Priyanka Patil Suresh Kadam Dayanand Patil Paresh More |
author_sort | Priyanka Patil |
collection | DOAJ |
description | Carboxylic acid functionalized imidazolium based novel acidic ionic liquid [CEMIM][MSA] was synthesized using economically feasible raw materials under very mild condition. The cost effective and sustainable synthesis of polyhydroquinoline and 6-unsustituted dihydropyrimidinone derivatives in green media was first time carried out very effectively using [CEMIM][MSA] catalyst. Acidic ionic liquid catalyst [CEMIM][MSA] with carboxylic acid group was easily separated and reused up to five cycles without much loss in its catalytic activity and stability. The introduced catalyst had showed a better catalytic performance in aqueous medium to obtain described compounds with excellent yields in shorter time. Purification free isolation of pure polyhydroquinolines and 6-unsustituted dihydropyrimidinones derivative makes the revealed protocol attractive and ecological. |
first_indexed | 2024-12-10T14:48:58Z |
format | Article |
id | doaj.art-360d7fc0e09b4785b889ba1ac0a5744e |
institution | Directory Open Access Journal |
issn | 1873-3905 |
language | English |
last_indexed | 2024-12-10T14:48:58Z |
publishDate | 2022-10-01 |
publisher | Elsevier |
record_format | Article |
series | Catalysis Communications |
spelling | doaj.art-360d7fc0e09b4785b889ba1ac0a5744e2022-12-22T01:44:29ZengElsevierCatalysis Communications1873-39052022-10-01170106500A green approach for the multicomponent synthesis of polyhydroquinolines and 6-unsubstituted dihydropyrimidinones using novel highly proficient acidic ionic liquid [CEMIM][MSA] as a reusable catalystPriyanka Patil0Suresh Kadam1Dayanand Patil2Paresh More3Department of Physics, K. E. T's V.G. Vaze College Autonomous, Maharashtra, IndiaDepartment of Physics, K. E. T's V.G. Vaze College Autonomous, Maharashtra, India; Corresponding authors at: Department of Physics, K. E. T's V.G. Vaze College Autonomous, Maharashtra, India.Department of Chemistry, K.E. T's V.G. Vaze College Autonomous, Maharashtra, IndiaDepartment of Physics, K. E. T's V.G. Vaze College Autonomous, Maharashtra, India; Department of Chemistry, K.E. T's V.G. Vaze College Autonomous, Maharashtra, India; Corresponding authors at: Department of Physics, K. E. T's V.G. Vaze College Autonomous, Maharashtra, India.Carboxylic acid functionalized imidazolium based novel acidic ionic liquid [CEMIM][MSA] was synthesized using economically feasible raw materials under very mild condition. The cost effective and sustainable synthesis of polyhydroquinoline and 6-unsustituted dihydropyrimidinone derivatives in green media was first time carried out very effectively using [CEMIM][MSA] catalyst. Acidic ionic liquid catalyst [CEMIM][MSA] with carboxylic acid group was easily separated and reused up to five cycles without much loss in its catalytic activity and stability. The introduced catalyst had showed a better catalytic performance in aqueous medium to obtain described compounds with excellent yields in shorter time. Purification free isolation of pure polyhydroquinolines and 6-unsustituted dihydropyrimidinones derivative makes the revealed protocol attractive and ecological.http://www.sciencedirect.com/science/article/pii/S1566736722001054PolyhydroquinolinesDihydropyrimidinonesGreen mediaMulticomponent reactionAcidic ionic liquid |
spellingShingle | Priyanka Patil Suresh Kadam Dayanand Patil Paresh More A green approach for the multicomponent synthesis of polyhydroquinolines and 6-unsubstituted dihydropyrimidinones using novel highly proficient acidic ionic liquid [CEMIM][MSA] as a reusable catalyst Catalysis Communications Polyhydroquinolines Dihydropyrimidinones Green media Multicomponent reaction Acidic ionic liquid |
title | A green approach for the multicomponent synthesis of polyhydroquinolines and 6-unsubstituted dihydropyrimidinones using novel highly proficient acidic ionic liquid [CEMIM][MSA] as a reusable catalyst |
title_full | A green approach for the multicomponent synthesis of polyhydroquinolines and 6-unsubstituted dihydropyrimidinones using novel highly proficient acidic ionic liquid [CEMIM][MSA] as a reusable catalyst |
title_fullStr | A green approach for the multicomponent synthesis of polyhydroquinolines and 6-unsubstituted dihydropyrimidinones using novel highly proficient acidic ionic liquid [CEMIM][MSA] as a reusable catalyst |
title_full_unstemmed | A green approach for the multicomponent synthesis of polyhydroquinolines and 6-unsubstituted dihydropyrimidinones using novel highly proficient acidic ionic liquid [CEMIM][MSA] as a reusable catalyst |
title_short | A green approach for the multicomponent synthesis of polyhydroquinolines and 6-unsubstituted dihydropyrimidinones using novel highly proficient acidic ionic liquid [CEMIM][MSA] as a reusable catalyst |
title_sort | green approach for the multicomponent synthesis of polyhydroquinolines and 6 unsubstituted dihydropyrimidinones using novel highly proficient acidic ionic liquid cemim msa as a reusable catalyst |
topic | Polyhydroquinolines Dihydropyrimidinones Green media Multicomponent reaction Acidic ionic liquid |
url | http://www.sciencedirect.com/science/article/pii/S1566736722001054 |
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