A green approach for the multicomponent synthesis of polyhydroquinolines and 6-unsubstituted dihydropyrimidinones using novel highly proficient acidic ionic liquid [CEMIM][MSA] as a reusable catalyst

Carboxylic acid functionalized imidazolium based novel acidic ionic liquid [CEMIM][MSA] was synthesized using economically feasible raw materials under very mild condition. The cost effective and sustainable synthesis of polyhydroquinoline and 6-unsustituted dihydropyrimidinone derivatives in green...

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Main Authors: Priyanka Patil, Suresh Kadam, Dayanand Patil, Paresh More
Format: Article
Language:English
Published: Elsevier 2022-10-01
Series:Catalysis Communications
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S1566736722001054
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author Priyanka Patil
Suresh Kadam
Dayanand Patil
Paresh More
author_facet Priyanka Patil
Suresh Kadam
Dayanand Patil
Paresh More
author_sort Priyanka Patil
collection DOAJ
description Carboxylic acid functionalized imidazolium based novel acidic ionic liquid [CEMIM][MSA] was synthesized using economically feasible raw materials under very mild condition. The cost effective and sustainable synthesis of polyhydroquinoline and 6-unsustituted dihydropyrimidinone derivatives in green media was first time carried out very effectively using [CEMIM][MSA] catalyst. Acidic ionic liquid catalyst [CEMIM][MSA] with carboxylic acid group was easily separated and reused up to five cycles without much loss in its catalytic activity and stability. The introduced catalyst had showed a better catalytic performance in aqueous medium to obtain described compounds with excellent yields in shorter time. Purification free isolation of pure polyhydroquinolines and 6-unsustituted dihydropyrimidinones derivative makes the revealed protocol attractive and ecological.
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spelling doaj.art-360d7fc0e09b4785b889ba1ac0a5744e2022-12-22T01:44:29ZengElsevierCatalysis Communications1873-39052022-10-01170106500A green approach for the multicomponent synthesis of polyhydroquinolines and 6-unsubstituted dihydropyrimidinones using novel highly proficient acidic ionic liquid [CEMIM][MSA] as a reusable catalystPriyanka Patil0Suresh Kadam1Dayanand Patil2Paresh More3Department of Physics, K. E. T's V.G. Vaze College Autonomous, Maharashtra, IndiaDepartment of Physics, K. E. T's V.G. Vaze College Autonomous, Maharashtra, India; Corresponding authors at: Department of Physics, K. E. T's V.G. Vaze College Autonomous, Maharashtra, India.Department of Chemistry, K.E. T's V.G. Vaze College Autonomous, Maharashtra, IndiaDepartment of Physics, K. E. T's V.G. Vaze College Autonomous, Maharashtra, India; Department of Chemistry, K.E. T's V.G. Vaze College Autonomous, Maharashtra, India; Corresponding authors at: Department of Physics, K. E. T's V.G. Vaze College Autonomous, Maharashtra, India.Carboxylic acid functionalized imidazolium based novel acidic ionic liquid [CEMIM][MSA] was synthesized using economically feasible raw materials under very mild condition. The cost effective and sustainable synthesis of polyhydroquinoline and 6-unsustituted dihydropyrimidinone derivatives in green media was first time carried out very effectively using [CEMIM][MSA] catalyst. Acidic ionic liquid catalyst [CEMIM][MSA] with carboxylic acid group was easily separated and reused up to five cycles without much loss in its catalytic activity and stability. The introduced catalyst had showed a better catalytic performance in aqueous medium to obtain described compounds with excellent yields in shorter time. Purification free isolation of pure polyhydroquinolines and 6-unsustituted dihydropyrimidinones derivative makes the revealed protocol attractive and ecological.http://www.sciencedirect.com/science/article/pii/S1566736722001054PolyhydroquinolinesDihydropyrimidinonesGreen mediaMulticomponent reactionAcidic ionic liquid
spellingShingle Priyanka Patil
Suresh Kadam
Dayanand Patil
Paresh More
A green approach for the multicomponent synthesis of polyhydroquinolines and 6-unsubstituted dihydropyrimidinones using novel highly proficient acidic ionic liquid [CEMIM][MSA] as a reusable catalyst
Catalysis Communications
Polyhydroquinolines
Dihydropyrimidinones
Green media
Multicomponent reaction
Acidic ionic liquid
title A green approach for the multicomponent synthesis of polyhydroquinolines and 6-unsubstituted dihydropyrimidinones using novel highly proficient acidic ionic liquid [CEMIM][MSA] as a reusable catalyst
title_full A green approach for the multicomponent synthesis of polyhydroquinolines and 6-unsubstituted dihydropyrimidinones using novel highly proficient acidic ionic liquid [CEMIM][MSA] as a reusable catalyst
title_fullStr A green approach for the multicomponent synthesis of polyhydroquinolines and 6-unsubstituted dihydropyrimidinones using novel highly proficient acidic ionic liquid [CEMIM][MSA] as a reusable catalyst
title_full_unstemmed A green approach for the multicomponent synthesis of polyhydroquinolines and 6-unsubstituted dihydropyrimidinones using novel highly proficient acidic ionic liquid [CEMIM][MSA] as a reusable catalyst
title_short A green approach for the multicomponent synthesis of polyhydroquinolines and 6-unsubstituted dihydropyrimidinones using novel highly proficient acidic ionic liquid [CEMIM][MSA] as a reusable catalyst
title_sort green approach for the multicomponent synthesis of polyhydroquinolines and 6 unsubstituted dihydropyrimidinones using novel highly proficient acidic ionic liquid cemim msa as a reusable catalyst
topic Polyhydroquinolines
Dihydropyrimidinones
Green media
Multicomponent reaction
Acidic ionic liquid
url http://www.sciencedirect.com/science/article/pii/S1566736722001054
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