Green Composites Based on Mater-Bi<sup>®</sup> and <i>Solanum lycopersicum</i> Plant Waste for 3D Printing Applications

3D printability of green composites is currently experiencing a boost in importance and interest, envisaging a way to valorise agricultural waste, in order to obtain affordable fillers for the preparation of biodegradable polymer-based composites with reduced cost and environmental impact, without u...

Full description

Bibliographic Details
Main Authors: Roberto Scaffaro, Maria Clara Citarrella, Marco Morreale
Format: Article
Language:English
Published: MDPI AG 2023-01-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/15/2/325
_version_ 1797437557527543808
author Roberto Scaffaro
Maria Clara Citarrella
Marco Morreale
author_facet Roberto Scaffaro
Maria Clara Citarrella
Marco Morreale
author_sort Roberto Scaffaro
collection DOAJ
description 3D printability of green composites is currently experiencing a boost in importance and interest, envisaging a way to valorise agricultural waste, in order to obtain affordable fillers for the preparation of biodegradable polymer-based composites with reduced cost and environmental impact, without undermining processability and mechanical performance. In this work, an innovative green composite was prepared by combining a starch-based biodegradable polymer (Mater-Bi<sup>®</sup>, MB) and a filler obtained from the lignocellulosic waste coming from <i>Solanum lycopersicum</i> (i.e., tomato plant) harvesting. Different processing parameters and different filler amounts were investigated, and the obtained samples were subjected to rheological, morphological, and mechanical characterizations. Regarding the adopted filler amounts, processability was found to be good, with adequate dispersion of the filler in the matrix. Mechanical performance was satisfactory, and it was found that this is significantly affected by specific process parameters such as the raster angle. The mechanical properties were compared to those predictable from the Halpin–Tsai model, finding that the prepared systems exceed the expected values.
first_indexed 2024-03-09T11:24:10Z
format Article
id doaj.art-36100bc183734c7f957f1db14a4b6f99
institution Directory Open Access Journal
issn 2073-4360
language English
last_indexed 2024-03-09T11:24:10Z
publishDate 2023-01-01
publisher MDPI AG
record_format Article
series Polymers
spelling doaj.art-36100bc183734c7f957f1db14a4b6f992023-12-01T00:08:08ZengMDPI AGPolymers2073-43602023-01-0115232510.3390/polym15020325Green Composites Based on Mater-Bi<sup>®</sup> and <i>Solanum lycopersicum</i> Plant Waste for 3D Printing ApplicationsRoberto Scaffaro0Maria Clara Citarrella1Marco Morreale2Department of Engineering, University of Palermo, Viale delle Scienze, 90128 Palermo, ItalyDepartment of Engineering, University of Palermo, Viale delle Scienze, 90128 Palermo, ItalyFaculty of Engineering and Architecture, Kore University of Enna, Cittadella Universitaria, 94100 Enna, Italy3D printability of green composites is currently experiencing a boost in importance and interest, envisaging a way to valorise agricultural waste, in order to obtain affordable fillers for the preparation of biodegradable polymer-based composites with reduced cost and environmental impact, without undermining processability and mechanical performance. In this work, an innovative green composite was prepared by combining a starch-based biodegradable polymer (Mater-Bi<sup>®</sup>, MB) and a filler obtained from the lignocellulosic waste coming from <i>Solanum lycopersicum</i> (i.e., tomato plant) harvesting. Different processing parameters and different filler amounts were investigated, and the obtained samples were subjected to rheological, morphological, and mechanical characterizations. Regarding the adopted filler amounts, processability was found to be good, with adequate dispersion of the filler in the matrix. Mechanical performance was satisfactory, and it was found that this is significantly affected by specific process parameters such as the raster angle. The mechanical properties were compared to those predictable from the Halpin–Tsai model, finding that the prepared systems exceed the expected values.https://www.mdpi.com/2073-4360/15/2/325green composites3D printingFDMbiopolymerssolanum lycopersicum
spellingShingle Roberto Scaffaro
Maria Clara Citarrella
Marco Morreale
Green Composites Based on Mater-Bi<sup>®</sup> and <i>Solanum lycopersicum</i> Plant Waste for 3D Printing Applications
Polymers
green composites
3D printing
FDM
biopolymers
solanum lycopersicum
title Green Composites Based on Mater-Bi<sup>®</sup> and <i>Solanum lycopersicum</i> Plant Waste for 3D Printing Applications
title_full Green Composites Based on Mater-Bi<sup>®</sup> and <i>Solanum lycopersicum</i> Plant Waste for 3D Printing Applications
title_fullStr Green Composites Based on Mater-Bi<sup>®</sup> and <i>Solanum lycopersicum</i> Plant Waste for 3D Printing Applications
title_full_unstemmed Green Composites Based on Mater-Bi<sup>®</sup> and <i>Solanum lycopersicum</i> Plant Waste for 3D Printing Applications
title_short Green Composites Based on Mater-Bi<sup>®</sup> and <i>Solanum lycopersicum</i> Plant Waste for 3D Printing Applications
title_sort green composites based on mater bi sup r sup and i solanum lycopersicum i plant waste for 3d printing applications
topic green composites
3D printing
FDM
biopolymers
solanum lycopersicum
url https://www.mdpi.com/2073-4360/15/2/325
work_keys_str_mv AT robertoscaffaro greencompositesbasedonmaterbisupsupandisolanumlycopersicumiplantwastefor3dprintingapplications
AT mariaclaracitarrella greencompositesbasedonmaterbisupsupandisolanumlycopersicumiplantwastefor3dprintingapplications
AT marcomorreale greencompositesbasedonmaterbisupsupandisolanumlycopersicumiplantwastefor3dprintingapplications