Anionic Water Cluster Polymers [(H2O)18(OH)2]n2n− Is Stabilized by Bis(2,2′-bipyridine) Cupric Chloride [Cu(bipy)2Cl]−
Anionic water clusters have long been studied to infer properties of the bulk hydrated electron. In particular, the question of whether the excess electron is on the surface of the cluster or in the interior of the clusters has been the subject of much speculation. The successes of solid-state physi...
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| Format: | Article |
| Language: | English |
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MDPI AG
2018-01-01
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| Series: | Molecules |
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| Online Access: | http://www.mdpi.com/1420-3049/23/1/195 |
| _version_ | 1818550062735687680 |
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| author | E Liu Fangfang Jian |
| author_facet | E Liu Fangfang Jian |
| author_sort | E Liu |
| collection | DOAJ |
| description | Anionic water clusters have long been studied to infer properties of the bulk hydrated electron. In particular, the question of whether the excess electron is on the surface of the cluster or in the interior of the clusters has been the subject of much speculation. The successes of solid-state physics are built on exploiting the regularity of atomic arrangements in crystal. Describing the crystalline order of solids is relatively straightforward. Here we report the crystal structure of an anionic water cluster polymer [(H2O)18(OH)2]n2n− moiety that is stabilized by bis(2,2′-bipyridine) cupric chloride [Cu(bipy)2Cl]− host. |
| first_indexed | 2024-12-12T08:41:26Z |
| format | Article |
| id | doaj.art-3618cc5247a64ff2acf9b44483b99b9c |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-12-12T08:41:26Z |
| publishDate | 2018-01-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-3618cc5247a64ff2acf9b44483b99b9c2022-12-22T00:30:46ZengMDPI AGMolecules1420-30492018-01-0123119510.3390/molecules23010195molecules23010195Anionic Water Cluster Polymers [(H2O)18(OH)2]n2n− Is Stabilized by Bis(2,2′-bipyridine) Cupric Chloride [Cu(bipy)2Cl]−E Liu0Fangfang Jian1School of Chemical Engineering and Pharmaceutics, Henan University of Science and Technology, Luoyang 471023, ChinaSchool of Chemical Engineering and Pharmaceutics, Henan University of Science and Technology, Luoyang 471023, ChinaAnionic water clusters have long been studied to infer properties of the bulk hydrated electron. In particular, the question of whether the excess electron is on the surface of the cluster or in the interior of the clusters has been the subject of much speculation. The successes of solid-state physics are built on exploiting the regularity of atomic arrangements in crystal. Describing the crystalline order of solids is relatively straightforward. Here we report the crystal structure of an anionic water cluster polymer [(H2O)18(OH)2]n2n− moiety that is stabilized by bis(2,2′-bipyridine) cupric chloride [Cu(bipy)2Cl]− host.http://www.mdpi.com/1420-3049/23/1/195water clustercrystalhydrogen-bondpolymerCu compound |
| spellingShingle | E Liu Fangfang Jian Anionic Water Cluster Polymers [(H2O)18(OH)2]n2n− Is Stabilized by Bis(2,2′-bipyridine) Cupric Chloride [Cu(bipy)2Cl]− Molecules water cluster crystal hydrogen-bond polymer Cu compound |
| title | Anionic Water Cluster Polymers [(H2O)18(OH)2]n2n− Is Stabilized by Bis(2,2′-bipyridine) Cupric Chloride [Cu(bipy)2Cl]− |
| title_full | Anionic Water Cluster Polymers [(H2O)18(OH)2]n2n− Is Stabilized by Bis(2,2′-bipyridine) Cupric Chloride [Cu(bipy)2Cl]− |
| title_fullStr | Anionic Water Cluster Polymers [(H2O)18(OH)2]n2n− Is Stabilized by Bis(2,2′-bipyridine) Cupric Chloride [Cu(bipy)2Cl]− |
| title_full_unstemmed | Anionic Water Cluster Polymers [(H2O)18(OH)2]n2n− Is Stabilized by Bis(2,2′-bipyridine) Cupric Chloride [Cu(bipy)2Cl]− |
| title_short | Anionic Water Cluster Polymers [(H2O)18(OH)2]n2n− Is Stabilized by Bis(2,2′-bipyridine) Cupric Chloride [Cu(bipy)2Cl]− |
| title_sort | anionic water cluster polymers h2o 18 oh 2 n2n is stabilized by bis 2 2 bipyridine cupric chloride cu bipy 2cl |
| topic | water cluster crystal hydrogen-bond polymer Cu compound |
| url | http://www.mdpi.com/1420-3049/23/1/195 |
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