Methylammonium Chloride Additive in Lead Iodide Optimizing the Crystallization Process for Efficient Perovskite Solar Cells
Perovskite solar cells (PSCs) were fabricated using a two-step spin-coating method with MACl added to the inorganic layer. The properties of the perovskite films were characterized by SEM, XRD, PL, UV-vis spectra, etc. The morphology of the PbI2 film was significantly changed, and the formation of M...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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Hindawi Limited
2022-01-01
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| Series: | International Journal of Photoenergy |
| Online Access: | http://dx.doi.org/10.1155/2022/5288400 |
| _version_ | 1798020925765976064 |
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| author | Hongqiao Wang Jingquan Zhang |
| author_facet | Hongqiao Wang Jingquan Zhang |
| author_sort | Hongqiao Wang |
| collection | DOAJ |
| description | Perovskite solar cells (PSCs) were fabricated using a two-step spin-coating method with MACl added to the inorganic layer. The properties of the perovskite films were characterized by SEM, XRD, PL, UV-vis spectra, etc. The morphology of the PbI2 film was significantly changed, and the formation of MACl-related intermediate phase was observed at the grain boundaries. The grain size and crystallinity of the perovskite film increased, and the morphology at grain boundaries was optimized, while the composition of perovskite remained unchanged. The introduction of MACl improved the open circuit voltage (VOC) and fill factor (FF) of PSCs, and the optimal device efficiency reached 21.59%. This paper presents a new approach using additives in inorganic layers to optimize the crystallization process for efficient PSCs. |
| first_indexed | 2024-04-11T17:05:37Z |
| format | Article |
| id | doaj.art-36457987f54e436a8a3bcc06baf96577 |
| institution | Directory Open Access Journal |
| issn | 1687-529X |
| language | English |
| last_indexed | 2024-04-11T17:05:37Z |
| publishDate | 2022-01-01 |
| publisher | Hindawi Limited |
| record_format | Article |
| series | International Journal of Photoenergy |
| spelling | doaj.art-36457987f54e436a8a3bcc06baf965772022-12-22T04:13:02ZengHindawi LimitedInternational Journal of Photoenergy1687-529X2022-01-01202210.1155/2022/5288400Methylammonium Chloride Additive in Lead Iodide Optimizing the Crystallization Process for Efficient Perovskite Solar CellsHongqiao Wang0Jingquan Zhang1College of Materials Science and Engineering & Institute of New Energy and Low-Carbon TechnologyCollege of Materials Science and Engineering & Institute of New Energy and Low-Carbon TechnologyPerovskite solar cells (PSCs) were fabricated using a two-step spin-coating method with MACl added to the inorganic layer. The properties of the perovskite films were characterized by SEM, XRD, PL, UV-vis spectra, etc. The morphology of the PbI2 film was significantly changed, and the formation of MACl-related intermediate phase was observed at the grain boundaries. The grain size and crystallinity of the perovskite film increased, and the morphology at grain boundaries was optimized, while the composition of perovskite remained unchanged. The introduction of MACl improved the open circuit voltage (VOC) and fill factor (FF) of PSCs, and the optimal device efficiency reached 21.59%. This paper presents a new approach using additives in inorganic layers to optimize the crystallization process for efficient PSCs.http://dx.doi.org/10.1155/2022/5288400 |
| spellingShingle | Hongqiao Wang Jingquan Zhang Methylammonium Chloride Additive in Lead Iodide Optimizing the Crystallization Process for Efficient Perovskite Solar Cells International Journal of Photoenergy |
| title | Methylammonium Chloride Additive in Lead Iodide Optimizing the Crystallization Process for Efficient Perovskite Solar Cells |
| title_full | Methylammonium Chloride Additive in Lead Iodide Optimizing the Crystallization Process for Efficient Perovskite Solar Cells |
| title_fullStr | Methylammonium Chloride Additive in Lead Iodide Optimizing the Crystallization Process for Efficient Perovskite Solar Cells |
| title_full_unstemmed | Methylammonium Chloride Additive in Lead Iodide Optimizing the Crystallization Process for Efficient Perovskite Solar Cells |
| title_short | Methylammonium Chloride Additive in Lead Iodide Optimizing the Crystallization Process for Efficient Perovskite Solar Cells |
| title_sort | methylammonium chloride additive in lead iodide optimizing the crystallization process for efficient perovskite solar cells |
| url | http://dx.doi.org/10.1155/2022/5288400 |
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