Polylactide (PLA) Filaments a Biobased Solution for Additive Manufacturing: Correlating Rheology and Thermomechanical Properties with Printing Quality

Three commercial filaments for Fused Deposition Modeling (FDM) were selected to study the influence of polymer formulation on the printing quality and mechanical properties of FDM specimens. The three filaments were all based on polylactic acid (PLA) as the matrix, and they are sold as PLA filaments...

Full description

Bibliographic Details
Main Authors: Gianluca Cicala, Davide Giordano, Claudio Tosto, Giovanni Filippone, Antonino Recca, Ignazio Blanco
Format: Article
Language:English
Published: MDPI AG 2018-07-01
Series:Materials
Subjects:
Online Access:http://www.mdpi.com/1996-1944/11/7/1191
_version_ 1811328253470703616
author Gianluca Cicala
Davide Giordano
Claudio Tosto
Giovanni Filippone
Antonino Recca
Ignazio Blanco
author_facet Gianluca Cicala
Davide Giordano
Claudio Tosto
Giovanni Filippone
Antonino Recca
Ignazio Blanco
author_sort Gianluca Cicala
collection DOAJ
description Three commercial filaments for Fused Deposition Modeling (FDM) were selected to study the influence of polymer formulation on the printing quality and mechanical properties of FDM specimens. The three filaments were all based on polylactic acid (PLA) as the matrix, and they are sold as PLA filaments. The printing quality was tested by printing one complex shape with overhang features. The marked shear thinning behavior for two filaments was observed by rheology. The filaments were also studied by scanning electron microscopy and thermogravimetric analysis (TGA) to unveil their composition. The filaments with the best printing quality showed the presence of mineral fillers, which explained the melt behavior observed by rheology. The tensile testing confirmed that the filled PLA was the best-performing filament both in terms of printing quality and thermomechanical performance, with a p-value = 0.106 for the tensile modulus, and a p-value = 0.615 for the ultimate tensile strength.
first_indexed 2024-04-13T15:22:00Z
format Article
id doaj.art-36617e5b49e74d078e48f2eef6bf2ce3
institution Directory Open Access Journal
issn 1996-1944
language English
last_indexed 2024-04-13T15:22:00Z
publishDate 2018-07-01
publisher MDPI AG
record_format Article
series Materials
spelling doaj.art-36617e5b49e74d078e48f2eef6bf2ce32022-12-22T02:41:38ZengMDPI AGMaterials1996-19442018-07-01117119110.3390/ma11071191ma11071191Polylactide (PLA) Filaments a Biobased Solution for Additive Manufacturing: Correlating Rheology and Thermomechanical Properties with Printing QualityGianluca Cicala0Davide Giordano1Claudio Tosto2Giovanni Filippone3Antonino Recca4Ignazio Blanco5Dipartimento DICAR (Department of Civil Engineering and Architecture), Università di Catania, Viale Andrea Doria 6, 95125 Catania, ItalyDipartimento DICAR (Department of Civil Engineering and Architecture), Università di Catania, Viale Andrea Doria 6, 95125 Catania, ItalyDipartimento DICAR (Department of Civil Engineering and Architecture), Università di Catania, Viale Andrea Doria 6, 95125 Catania, ItalyDipartimento di Ingegneria Chimica, dei Materiali e Della Produzione Industriale, Università degli Studi di Napoli Federico II, Piazzale Tecchio 80, 80125 Napoli, ItalyDipartimento DICAR (Department of Civil Engineering and Architecture), Università di Catania, Viale Andrea Doria 6, 95125 Catania, ItalyDipartimento DICAR (Department of Civil Engineering and Architecture), Università di Catania, Viale Andrea Doria 6, 95125 Catania, ItalyThree commercial filaments for Fused Deposition Modeling (FDM) were selected to study the influence of polymer formulation on the printing quality and mechanical properties of FDM specimens. The three filaments were all based on polylactic acid (PLA) as the matrix, and they are sold as PLA filaments. The printing quality was tested by printing one complex shape with overhang features. The marked shear thinning behavior for two filaments was observed by rheology. The filaments were also studied by scanning electron microscopy and thermogravimetric analysis (TGA) to unveil their composition. The filaments with the best printing quality showed the presence of mineral fillers, which explained the melt behavior observed by rheology. The tensile testing confirmed that the filled PLA was the best-performing filament both in terms of printing quality and thermomechanical performance, with a p-value = 0.106 for the tensile modulus, and a p-value = 0.615 for the ultimate tensile strength.http://www.mdpi.com/1996-1944/11/7/1191additive manufacturingfused deposition modelingrheologymechanical propertiesPLA3D printingthermal properties
spellingShingle Gianluca Cicala
Davide Giordano
Claudio Tosto
Giovanni Filippone
Antonino Recca
Ignazio Blanco
Polylactide (PLA) Filaments a Biobased Solution for Additive Manufacturing: Correlating Rheology and Thermomechanical Properties with Printing Quality
Materials
additive manufacturing
fused deposition modeling
rheology
mechanical properties
PLA
3D printing
thermal properties
title Polylactide (PLA) Filaments a Biobased Solution for Additive Manufacturing: Correlating Rheology and Thermomechanical Properties with Printing Quality
title_full Polylactide (PLA) Filaments a Biobased Solution for Additive Manufacturing: Correlating Rheology and Thermomechanical Properties with Printing Quality
title_fullStr Polylactide (PLA) Filaments a Biobased Solution for Additive Manufacturing: Correlating Rheology and Thermomechanical Properties with Printing Quality
title_full_unstemmed Polylactide (PLA) Filaments a Biobased Solution for Additive Manufacturing: Correlating Rheology and Thermomechanical Properties with Printing Quality
title_short Polylactide (PLA) Filaments a Biobased Solution for Additive Manufacturing: Correlating Rheology and Thermomechanical Properties with Printing Quality
title_sort polylactide pla filaments a biobased solution for additive manufacturing correlating rheology and thermomechanical properties with printing quality
topic additive manufacturing
fused deposition modeling
rheology
mechanical properties
PLA
3D printing
thermal properties
url http://www.mdpi.com/1996-1944/11/7/1191
work_keys_str_mv AT gianlucacicala polylactideplafilamentsabiobasedsolutionforadditivemanufacturingcorrelatingrheologyandthermomechanicalpropertieswithprintingquality
AT davidegiordano polylactideplafilamentsabiobasedsolutionforadditivemanufacturingcorrelatingrheologyandthermomechanicalpropertieswithprintingquality
AT claudiotosto polylactideplafilamentsabiobasedsolutionforadditivemanufacturingcorrelatingrheologyandthermomechanicalpropertieswithprintingquality
AT giovannifilippone polylactideplafilamentsabiobasedsolutionforadditivemanufacturingcorrelatingrheologyandthermomechanicalpropertieswithprintingquality
AT antoninorecca polylactideplafilamentsabiobasedsolutionforadditivemanufacturingcorrelatingrheologyandthermomechanicalpropertieswithprintingquality
AT ignazioblanco polylactideplafilamentsabiobasedsolutionforadditivemanufacturingcorrelatingrheologyandthermomechanicalpropertieswithprintingquality