The crystal structures of two novel polymorphs of bis(oxonium) ethane-1,2-disulfonate
Two novel crystal forms of bis(oxonium) ethane-1,2-disulfonate, 2H3O−·C2H4O6S22−, are reported. Polymorph II has monoclinic (P21/n) symmetry, while the symmetry of form III is triclinic (P\overline{1}). Both structures display extensive networks of O—H...O hydrogen bonds. While this network in Form...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2019-11-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989019013367 |
| _version_ | 1818961009340055552 |
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| author | Jaroslaw Mazurek Ana Fernandez-Casares |
| author_facet | Jaroslaw Mazurek Ana Fernandez-Casares |
| author_sort | Jaroslaw Mazurek |
| collection | DOAJ |
| description | Two novel crystal forms of bis(oxonium) ethane-1,2-disulfonate, 2H3O−·C2H4O6S22−, are reported. Polymorph II has monoclinic (P21/n) symmetry, while the symmetry of form III is triclinic (P\overline{1}). Both structures display extensive networks of O—H...O hydrogen bonds. While this network in Form II is similar to that observed for the previously reported Form I [Mootz & Wunderlich (1970). Acta Cryst. B26, 1820–1825; Sartori et al. (1994). Z. Naturforsch. 49, 1467–1472] and extends in all directions, in Form III it differs significantly, forming layers parallel to the ab plane. The sulfonate molecule in all three forms adopts a nearly identical geometry. The other observed differences between the forms, apart from the hydrogen-bonding network, are observed in the crystal density and packing index. |
| first_indexed | 2024-12-20T12:06:37Z |
| format | Article |
| id | doaj.art-366a2018cb7643d7b6d2c620f678087c |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-12-20T12:06:37Z |
| publishDate | 2019-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-366a2018cb7643d7b6d2c620f678087c2022-12-21T19:41:22ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902019-11-0175111586158910.1107/S2056989019013367lh5920The crystal structures of two novel polymorphs of bis(oxonium) ethane-1,2-disulfonateJaroslaw Mazurek0Ana Fernandez-Casares1Ardena, Solid State Research Services, Meibergdreef 31, 1105 AZ Amsterdam, The NetherlandsArdena, Solid State Research Services, Meibergdreef 31, 1105 AZ Amsterdam, The NetherlandsTwo novel crystal forms of bis(oxonium) ethane-1,2-disulfonate, 2H3O−·C2H4O6S22−, are reported. Polymorph II has monoclinic (P21/n) symmetry, while the symmetry of form III is triclinic (P\overline{1}). Both structures display extensive networks of O—H...O hydrogen bonds. While this network in Form II is similar to that observed for the previously reported Form I [Mootz & Wunderlich (1970). Acta Cryst. B26, 1820–1825; Sartori et al. (1994). Z. Naturforsch. 49, 1467–1472] and extends in all directions, in Form III it differs significantly, forming layers parallel to the ab plane. The sulfonate molecule in all three forms adopts a nearly identical geometry. The other observed differences between the forms, apart from the hydrogen-bonding network, are observed in the crystal density and packing index.http://scripts.iucr.org/cgi-bin/paper?S2056989019013367crystal structurepolymorphismoxonium cationsulfonate anions |
| spellingShingle | Jaroslaw Mazurek Ana Fernandez-Casares The crystal structures of two novel polymorphs of bis(oxonium) ethane-1,2-disulfonate Acta Crystallographica Section E: Crystallographic Communications crystal structure polymorphism oxonium cation sulfonate anions |
| title | The crystal structures of two novel polymorphs of bis(oxonium) ethane-1,2-disulfonate |
| title_full | The crystal structures of two novel polymorphs of bis(oxonium) ethane-1,2-disulfonate |
| title_fullStr | The crystal structures of two novel polymorphs of bis(oxonium) ethane-1,2-disulfonate |
| title_full_unstemmed | The crystal structures of two novel polymorphs of bis(oxonium) ethane-1,2-disulfonate |
| title_short | The crystal structures of two novel polymorphs of bis(oxonium) ethane-1,2-disulfonate |
| title_sort | crystal structures of two novel polymorphs of bis oxonium ethane 1 2 disulfonate |
| topic | crystal structure polymorphism oxonium cation sulfonate anions |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989019013367 |
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