Bis{tris[3-(2-pyridyl)-1H-pyrazole]manganese(II)} dodecamolybdo(V,VI)phosphate hexahydrate
The asymmetric unit of the title compound, [Mn(C8H7N3)3]2[PMo12O40]·6H2O, consists of a complex [Mn(C8H7N3)3]2+ cation, half of a mixed-valent MoV,VI α-Keggin-type [PMo12O40]4− heteropolyanion, and three uncoordinated water molecules. The Mn2+ cation is surrou...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053681000320X |
| _version_ | 1818284479182012416 |
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| author | Lujiang Hao Chunling Ma Jianghui Chen Xiaofei Zhang Xiutang Zhang |
| author_facet | Lujiang Hao Chunling Ma Jianghui Chen Xiaofei Zhang Xiutang Zhang |
| author_sort | Lujiang Hao |
| collection | DOAJ |
| description | The asymmetric unit of the title compound, [Mn(C8H7N3)3]2[PMo12O40]·6H2O, consists of a complex [Mn(C8H7N3)3]2+ cation, half of a mixed-valent MoV,VI α-Keggin-type [PMo12O40]4− heteropolyanion, and three uncoordinated water molecules. The Mn2+ cation is surrounded by six N atoms from three chelating 3-(2-pyridyl)-1H-pyrazole ligands in a distorted octahedral coordination. In the heteropolyanion, two O atoms of the central PO4 group (overline{1} symmetry) are equally disordered about an inversion centre. N—H...O and O—H...O hydrogen bonding between the cations, anions and the uncoordinated water molecules leads to a consolidation of the structure. |
| first_indexed | 2024-12-13T00:53:27Z |
| format | Article |
| id | doaj.art-36724ac9a460427096b7f02a9a3c2aec |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T00:53:27Z |
| publishDate | 2010-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-36724ac9a460427096b7f02a9a3c2aec2022-12-22T00:04:51ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-02-01662m231m23210.1107/S160053681000320XBis{tris[3-(2-pyridyl)-1H-pyrazole]manganese(II)} dodecamolybdo(V,VI)phosphate hexahydrateLujiang HaoChunling MaJianghui ChenXiaofei ZhangXiutang ZhangThe asymmetric unit of the title compound, [Mn(C8H7N3)3]2[PMo12O40]·6H2O, consists of a complex [Mn(C8H7N3)3]2+ cation, half of a mixed-valent MoV,VI α-Keggin-type [PMo12O40]4− heteropolyanion, and three uncoordinated water molecules. The Mn2+ cation is surrounded by six N atoms from three chelating 3-(2-pyridyl)-1H-pyrazole ligands in a distorted octahedral coordination. In the heteropolyanion, two O atoms of the central PO4 group (overline{1} symmetry) are equally disordered about an inversion centre. N—H...O and O—H...O hydrogen bonding between the cations, anions and the uncoordinated water molecules leads to a consolidation of the structure.http://scripts.iucr.org/cgi-bin/paper?S160053681000320X |
| spellingShingle | Lujiang Hao Chunling Ma Jianghui Chen Xiaofei Zhang Xiutang Zhang Bis{tris[3-(2-pyridyl)-1H-pyrazole]manganese(II)} dodecamolybdo(V,VI)phosphate hexahydrate Acta Crystallographica Section E |
| title | Bis{tris[3-(2-pyridyl)-1H-pyrazole]manganese(II)} dodecamolybdo(V,VI)phosphate hexahydrate |
| title_full | Bis{tris[3-(2-pyridyl)-1H-pyrazole]manganese(II)} dodecamolybdo(V,VI)phosphate hexahydrate |
| title_fullStr | Bis{tris[3-(2-pyridyl)-1H-pyrazole]manganese(II)} dodecamolybdo(V,VI)phosphate hexahydrate |
| title_full_unstemmed | Bis{tris[3-(2-pyridyl)-1H-pyrazole]manganese(II)} dodecamolybdo(V,VI)phosphate hexahydrate |
| title_short | Bis{tris[3-(2-pyridyl)-1H-pyrazole]manganese(II)} dodecamolybdo(V,VI)phosphate hexahydrate |
| title_sort | bis tris 3 2 pyridyl 1h pyrazole manganese ii dodecamolybdo v vi phosphate hexahydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S160053681000320X |
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