Unusual local electric field concentration in multilayer ceramic capacitors

Local electric-field around multitype pores (dielectric pore, interface pore, electrode pore) in multilayer ceramic capacitors (MLCCs) was investigated using Kelvin probe force microscopy combined with the finite element simulation to understand the effect of pores on the electric reliability of MLC...

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Main Authors: Wentong Du, Huarong Zeng, Weiwei Yang, Kunyu Zhao, Faqiang Zhang, Guorong Li, Yongxiang Li, Zhifu Liu
Format: Article
Language:English
Published: Elsevier 2023-03-01
Series:Journal of Materiomics
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2352847822001277
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author Wentong Du
Huarong Zeng
Weiwei Yang
Kunyu Zhao
Faqiang Zhang
Guorong Li
Yongxiang Li
Zhifu Liu
author_facet Wentong Du
Huarong Zeng
Weiwei Yang
Kunyu Zhao
Faqiang Zhang
Guorong Li
Yongxiang Li
Zhifu Liu
author_sort Wentong Du
collection DOAJ
description Local electric-field around multitype pores (dielectric pore, interface pore, electrode pore) in multilayer ceramic capacitors (MLCCs) was investigated using Kelvin probe force microscopy combined with the finite element simulation to understand the effect of pores on the electric reliability of MLCCs. Electric-field is found to be concentrated significantly in the vicinity of these pores and the strength of the local electric-field is 1.5–5.0 times of the nominal strength. Unexpectedly, the concentration degree of the pores in the inner electrode is much higher than that in the dielectrics and dielectric-electrode interfaces. Meanwhile, geometry orientations are found to have a remarkable influence on the local electric field strength. The pores act as an insulation degradation precursor via local electric, thermal center, and oxygen vacancies accumulation center. Such unusual local electric field concentration of multitype pores can provide new insights into the understanding of insulation degradation evolution, processing tailoring and design optimization for MLCCs.
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spelling doaj.art-36793f8ef9dd42bf9d873b3baaaa8d9b2023-09-03T09:09:50ZengElsevierJournal of Materiomics2352-84782023-03-0192403409Unusual local electric field concentration in multilayer ceramic capacitorsWentong Du0Huarong Zeng1Weiwei Yang2Kunyu Zhao3Faqiang Zhang4Guorong Li5Yongxiang Li6Zhifu Liu7CAS Key Laboratory of Inorganic Functional Materials and Devices, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, 201899, China; Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing, 100049, ChinaCAS Key Laboratory of Inorganic Functional Materials and Devices, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, 201899, China; Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing, 100049, China; Corresponding author. CAS Key Laboratory of Inorganic Functional Materials and Devices, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, 201899, China.CAS Key Laboratory of Inorganic Functional Materials and Devices, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, 201899, China; Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing, 100049, ChinaCAS Key Laboratory of Inorganic Functional Materials and Devices, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, 201899, China; Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing, 100049, China; Corresponding author. CAS Key Laboratory of Inorganic Functional Materials and Devices, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, 201899, China.CAS Key Laboratory of Inorganic Functional Materials and Devices, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, 201899, China; Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing, 100049, ChinaCAS Key Laboratory of Inorganic Functional Materials and Devices, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, 201899, China; Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing, 100049, ChinaSchool of Engineering, RMIT University, Melbourne, VIC, 3000, AustraliaCAS Key Laboratory of Inorganic Functional Materials and Devices, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, 201899, China; Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing, 100049, China; Corresponding author. CAS Key Laboratory of Inorganic Functional Materials and Devices, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, 201899, China.Local electric-field around multitype pores (dielectric pore, interface pore, electrode pore) in multilayer ceramic capacitors (MLCCs) was investigated using Kelvin probe force microscopy combined with the finite element simulation to understand the effect of pores on the electric reliability of MLCCs. Electric-field is found to be concentrated significantly in the vicinity of these pores and the strength of the local electric-field is 1.5–5.0 times of the nominal strength. Unexpectedly, the concentration degree of the pores in the inner electrode is much higher than that in the dielectrics and dielectric-electrode interfaces. Meanwhile, geometry orientations are found to have a remarkable influence on the local electric field strength. The pores act as an insulation degradation precursor via local electric, thermal center, and oxygen vacancies accumulation center. Such unusual local electric field concentration of multitype pores can provide new insights into the understanding of insulation degradation evolution, processing tailoring and design optimization for MLCCs.http://www.sciencedirect.com/science/article/pii/S2352847822001277Multilayer ceramic capacitors (MLCCs)Kelvin probe force microscopyPoreLocal electric field concentration
spellingShingle Wentong Du
Huarong Zeng
Weiwei Yang
Kunyu Zhao
Faqiang Zhang
Guorong Li
Yongxiang Li
Zhifu Liu
Unusual local electric field concentration in multilayer ceramic capacitors
Journal of Materiomics
Multilayer ceramic capacitors (MLCCs)
Kelvin probe force microscopy
Pore
Local electric field concentration
title Unusual local electric field concentration in multilayer ceramic capacitors
title_full Unusual local electric field concentration in multilayer ceramic capacitors
title_fullStr Unusual local electric field concentration in multilayer ceramic capacitors
title_full_unstemmed Unusual local electric field concentration in multilayer ceramic capacitors
title_short Unusual local electric field concentration in multilayer ceramic capacitors
title_sort unusual local electric field concentration in multilayer ceramic capacitors
topic Multilayer ceramic capacitors (MLCCs)
Kelvin probe force microscopy
Pore
Local electric field concentration
url http://www.sciencedirect.com/science/article/pii/S2352847822001277
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