The calculation of the optical gap energy of ZnXO (X = Bi, Sn and Fe)

In this paper, a new mathematical model has been developed to calculate the optical properties of nano materials a function of their size and structure. ZnO has good characterizatics in optical, electrical, and structural crystallisation; We will demonstrate that the direct optical gap energy of ZnO...

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Main Authors: Benramache Said, Benhaoua Boubaker
Format: Article
Language:English
Published: De Gruyter 2016-01-01
Series:Open Physics
Subjects:
Online Access:https://doi.org/10.1515/phys-2016-0080
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author Benramache Said
Benhaoua Boubaker
author_facet Benramache Said
Benhaoua Boubaker
author_sort Benramache Said
collection DOAJ
description In this paper, a new mathematical model has been developed to calculate the optical properties of nano materials a function of their size and structure. ZnO has good characterizatics in optical, electrical, and structural crystallisation; We will demonstrate that the direct optical gap energy of ZnO films grown by US and SP spray deposition can be calculated by investigating the correlation between solution molarity, doping levels of doped films and their Urbache energy. A simulation model has been developed to calculate the optical band gap energy of undoped and Bi, Sn and Fe doped ZnO thin films. The measurements by thus proposed models are in agreement with experimental data, with high correlation coefficients in the range 0.94-0.99. The maximum calculated enhancement of the optical gap energy of Sn doped ZnO thin films is always higher than the enhancement attainable with an Fe doped film, where the minimum error was found for Bi and Sn doped ZnO thin films to be 2,345 and 3,072%, respectively. The decrease in the relative errors from undoped to doped films can be explained by the good optical properties which can be observed in the fewer number of defects as well as less disorder.
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spelling doaj.art-367e14db4b384b2bbb31f4342d9ec3932022-12-21T22:39:03ZengDe GruyterOpen Physics2391-54712016-01-0114171472010.1515/phys-2016-0080phys-2016-0080The calculation of the optical gap energy of ZnXO (X = Bi, Sn and Fe)Benramache Said0Benhaoua Boubaker1Material Sciences Department, Faculty of Science, University of Biskra, Biskra 07000, Algeria, B.P. 145 University of Biskra, Biskra 07000, AlgeriaVTRS Laboratory, Institute of Technology, University of El-Oued, El-Oued 39000; AlgeriaIn this paper, a new mathematical model has been developed to calculate the optical properties of nano materials a function of their size and structure. ZnO has good characterizatics in optical, electrical, and structural crystallisation; We will demonstrate that the direct optical gap energy of ZnO films grown by US and SP spray deposition can be calculated by investigating the correlation between solution molarity, doping levels of doped films and their Urbache energy. A simulation model has been developed to calculate the optical band gap energy of undoped and Bi, Sn and Fe doped ZnO thin films. The measurements by thus proposed models are in agreement with experimental data, with high correlation coefficients in the range 0.94-0.99. The maximum calculated enhancement of the optical gap energy of Sn doped ZnO thin films is always higher than the enhancement attainable with an Fe doped film, where the minimum error was found for Bi and Sn doped ZnO thin films to be 2,345 and 3,072%, respectively. The decrease in the relative errors from undoped to doped films can be explained by the good optical properties which can be observed in the fewer number of defects as well as less disorder.https://doi.org/10.1515/phys-2016-0080znothin filmsemiconductor dopingcorrelation02.30.vv68.55.ag78.20.bh81.40.tv
spellingShingle Benramache Said
Benhaoua Boubaker
The calculation of the optical gap energy of ZnXO (X = Bi, Sn and Fe)
Open Physics
zno
thin film
semiconductor doping
correlation
02.30.vv
68.55.ag
78.20.bh
81.40.tv
title The calculation of the optical gap energy of ZnXO (X = Bi, Sn and Fe)
title_full The calculation of the optical gap energy of ZnXO (X = Bi, Sn and Fe)
title_fullStr The calculation of the optical gap energy of ZnXO (X = Bi, Sn and Fe)
title_full_unstemmed The calculation of the optical gap energy of ZnXO (X = Bi, Sn and Fe)
title_short The calculation of the optical gap energy of ZnXO (X = Bi, Sn and Fe)
title_sort calculation of the optical gap energy of znxo x bi sn and fe
topic zno
thin film
semiconductor doping
correlation
02.30.vv
68.55.ag
78.20.bh
81.40.tv
url https://doi.org/10.1515/phys-2016-0080
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