Irradiation Damage Independent Deuterium Retention in WMoTaNbV

High entropy alloys are a promising new class of metal alloys with outstanding radiation resistance and thermal stability. The interaction with hydrogen might, however, have desired (H storage) or undesired effects, such as hydrogen-induced embrittlement or tritium retention in the fusion reactor wa...

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Main Authors: Anna Liski, Tomi Vuoriheimo, Pasi Jalkanen, Kenichiro Mizohata, Eryang Lu, Jari Likonen, Jouni Heino, Kalle Heinola, Yevhen Zayachuk, Anna Widdowson, Ko-Kai Tseng, Che-Wei Tsai, Jien-Wei Yeh, Filip Tuomisto, Tommy Ahlgren
Format: Article
Language:English
Published: MDPI AG 2022-10-01
Series:Materials
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Online Access:https://www.mdpi.com/1996-1944/15/20/7296
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Summary:High entropy alloys are a promising new class of metal alloys with outstanding radiation resistance and thermal stability. The interaction with hydrogen might, however, have desired (H storage) or undesired effects, such as hydrogen-induced embrittlement or tritium retention in the fusion reactor wall. High entropy alloy WMoTaNbV and bulk W samples were used to study the quantity of irradiation-induced trapping sites and properties of D retention by employing thermal desorption spectrometry, secondary ion mass spectrometry, and elastic recoil detection analysis. The D implantation was not found to create additional hydrogen traps in WMoTaNbV as it does in W, while 90 at% of implanted D is retained in WMoTaNbV, in contrast to 35 at% in W. Implantation created damage predicted by SRIM is 0.24 dpa in WMoTaNbV, calculated with a density of <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><mn>6.044</mn><mo>×</mo><msup><mn>10</mn><mn>22</mn></msup></mrow></semantics></math></inline-formula> atoms/cm<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msup><mrow></mrow><mn>3</mn></msup></semantics></math></inline-formula>. The depth of the maximum damage was 90 nm. An effective trapping energy for D in WMoTaNbV was found to be about 1.7 eV, and the D emission temperature was close to 700 °C.
ISSN:1996-1944