Enzyme-triggered Radical Reactions: Another Approach For Tin-free Radical Chemistry

Enzyme-triggered Radical Reactions: Another Approach For Tin-free Radical Chemistry

The system laccase/mediator/dioxygen is able to trigger radical reactions with radical precursors which are not natural substrates of this enzyme. The radical generation has been accomplished by single electron transfer oxidation of a 1,3-dicarbonyl precursor. The process is exemplified wi...

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Bibliographic Details
Main Authors: Ibrahima Cissokho, Anne-Marie Farnet, Elisée Ferré, Michèle P. Bertrand, Gérard Gil, Stéphane Gastaldi
Format: Article
Language:deu
Published: Swiss Chemical Society 2012-06-01
Series:CHIMIA
Subjects:
1,3-dicarbonyl compounds
Laccase
Oxidoreductase
Radical mediator
Radical reaction
Online Access:https://www.chimia.ch/chimia/article/view/5241

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