Enantioselective PCCP Brønsted acid-catalyzed aza-Piancatelli rearrangement

Enantioselective PCCP Brønsted acid-catalyzed aza-Piancatelli rearrangement

An enantioselective aza-Piancatelli rearrangement has been developed using a chiral Brønsted acid based on pentacarboxycyclopentadiene (PCCP). This reaction provides rapid access to valuable chiral 4-amino-2-cyclopentenone building blocks from readily available starting material and is operationally...

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Bibliographic Details
Main Authors: Gabrielle R. Hammersley, Meghan F. Nichol, Helena C. Steffens, Jose M. Delgado, Gesine K. Veits, Javier Read de Alaniz
Format: Article
Language:English
Published: Beilstein-Institut 2019-07-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
aza-Piancatelli
Brønsted acid
cyclopentane
furylcarbinols
PCCP
Online Access:https://doi.org/10.3762/bjoc.15.160

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