Chlorido[1-diphenylphosphanyl-3-(phenylsulfanyl)propane-κ2P,S](η5-pentamethylcyclopentadienyl)iridium(III) chloride monohydrate

Chlorido[1-diphenylphosphanyl-3-(phenylsulfanyl)propane-κ2P,S](η5-pentamethylcyclopentadienyl)iridium(III) chloride monohydrate

The crystal structure of the title compound, [Ir(C10H15)Cl(C21H21PS)]Cl·H2O, consists of discrete [Ir(η5-C5Me5)Cl{Ph2P(CH2)3SPh-κP,κS}]+ cations, chloride anions and water molecules. The IrIII atom is coordinated by an η5-C5Me5 ligand,...

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Bibliographic Details
Main Authors: Gerd Ludwig, Marcus Korb, Tobias Rüffer, Heinrich Lang, Dirk Steinborn
Format: Article
Language:English
Published: International Union of Crystallography 2012-06-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812021964
Description
Summary:The crystal structure of the title compound, [Ir(C10H15)Cl(C21H21PS)]Cl·H2O, consists of discrete [Ir(η5-C5Me5)Cl{Ph2P(CH2)3SPh-κP,κS}]+ cations, chloride anions and water molecules. The IrIII atom is coordinated by an η5-C5Me5 ligand, a chloride and a Ph2P(CH2)3SPh-κP,κS ligand, leading to a three-legged piano-stool geometry. In the crystal, two water molecules and two chloride anions are linked by weak O—H...Cl hydrogen bonding into tetramers that are located on centers of inversion. The H atoms of one of the methyl groups are disordered and were refined using a split model.
ISSN:1600-5368

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